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11.
Sarah Lentfort Addi Bischoff Samuel Ebert Markus Patzek 《Meteoritics & planetary science》2021,56(1):127-147
CM chondrites are complex impact (mostly regolith) breccias, in which lithic clasts show various degrees of aqueous alteration. Here, we investigated the degree of alteration of individual clasts within 19 different CM chondrites and CM‐like clasts in three achondrites by chemical analysis of the tochilinite‐cronstedtite‐intergrowths (TCIs; formerly named “poorly characterized phases”). To identify TCIs in various chondritic lithologies, we used backscattered electron (BSE) overview images of polished thin sections, after which appropriate samples underwent electron microprobe measurements. Thus, 75 lithic clasts were classified. In general, the excellent work and specific criteria of Rubin et al. (2007) were used and considered to classify CM breccias in a similar way as ordinary chondrite breccias (e.g., CM2.2‐2.7). In BSE images, TCIs in strongly altered fragments in CM chondrites (CM2.0‐CM2.2) appear dark grayish and show a low contrast to the surrounding material (typically clastic matrix), and can be distinguished from TCIs in moderately (CM2.4‐CM2.6) or less altered fragments (CM2.7‐CM2.9); the latter are bright and have high contrast to the surroundings. We found that an accurate subclassification can be obtained by considering only the “FeO”/SiO2 ratio of the TCI chemistry. One could also consider the TCIs’ S/SiO2 ratio and the metal abundance, but these were not used for classification due to several disadvantages. Most of the CM chondrites are finds that have suffered terrestrial weathering in hot and cold deserts. Thus, the observed abundance of metal is susceptible to weathering and may not be a reliable indicator of subtype classification. This study proposes an extended classification scheme based on Rubin’s scale from subtypes CM2.0‐CM2.9 that takes the brecciation into account and includes the minimum to maximum degree of alteration of individual clasts. The range of aqueous alteration in CM chondrites and small spatial scale of mixing of clasts with different alteration histories will be important for interpreting returned samples from the OSIRIS‐REx and Hayabusa 2 missions in the future. 相似文献
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R chondrites are a distinct group of chondritic meteorites with unique mineralogical and chemical compositions. They contain various types of Al-rich objects [Ca,Al-rich inclusions (CAIs), Al-rich chondrules and fragments], whose mineralogical compositions and classifications were previously determined by Rout and Bischoff (2008). Here, we report on the bulk compositions of 126 such Al-rich objects determined by broad-beam electron probe microanalysis.Most of the CAIs, except a few, are significantly altered by complex nebular and/or parent body processes and the determination of their pristine composition is difficult. We found that the simple concentric spinel-rich inclusions have high Al2O3 (21–72 wt%) correlated with their high modal spinel. The subgroup of simple concentric spinel-rich CAIs have a high Al2O3 (21–57 wt%) and also sometimes high FeO (up to 36 wt%), due to a high hercynitic component in the spinel. One simple concentric spinel- and hibonite-rich CAI H030/L, identified as a HAL-type CAI by isotopic studies reported elsewhere, has a highly refractory composition (Al2O3～72 wt%). Most of the simple concentric spinel- and fassaite-rich CAIs have consistently high CaO (～2.5–17 wt%) compared to other simple concentric spinel-rich inclusions group, where only some inclusions have high CaO (up to 15 wt%). Simple concentric spinel- and Na,Al-alteration product-rich CAIs are heavily altered and have high Na2O (up to ～12.5 wt%).The three analyzed fassaite-rich spherules have high CaO and Al2O3, and complex spinel- and fassaite-rich CAIs have high CaO (up to 23 wt%) and SiO2 (up to 41 wt%). Most of the complex spinel- and plagioclase-rich CAIs are altered and contain high amounts of secondary oligoclase. However, a few are less affected by secondary alteration and these are characterized by relatively high CaO (up to 24 wt%) and Al2O3 (18–33 wt%); complex spinel and Na,Al-alteration product-rich CAIs are similar to the concentric spinel- and Na,Al-alteration product-rich CAIs. Due to Fe- and alkali-metasomatism, the vast majority of the inclusions in this subgroup were heavily altered, either in a nebular or parent body environment. As a result of this alteration, they contain high FeO and Na2O+K2O+Cl.Almost all inclusions have a Ca/Al-ratio below the solar ratio. This suggests that significant Ca/Al fractionation occurred during the formation of most CAIs, most probably due to disequilibrium condensation of spinel prior to melilite. However, a distillation process cannot be ruled out for some CAIs in producing the spinel enrichment. Some porous and fine grained CAIs may have been produced by agglomeration of refractory dust rich in spinel and fassaite. The HAL-type CAI, H030/L, most likely formed by distillation, similar to most of the HAL-type inclusions. Phase equilibrium analysis, in the CMAS system, shows that the fassaite-bearing spherules most likely formed by metastable crystallization and disequilibrium processes. Al-rich chondrules are characterized by >10 wt% Al2O3, and most of these also have high FeO and Na2O. Considering their bulk compositions, their precursors seem to have been a mixture of a ferromagnesian chondrule component rich in olivine and an anorthite–spinel–pyroxene–nepheline-rich CAI component. The mineral assemblages of some of the less altered Al-rich chondrules conform to those predicted by phase equilibrium studies. 相似文献
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14.
S. V. S. MURTY V. K. RAI A. D. SHUKLA G. SRINIVASAN P. N. SHUKLA K. M. SUTHAR N. BHANDARI A. BISCHOFF 《Meteoritics & planetary science》2004,39(3):387-399
Abstract— The Devgaon meteorite fell in India on February 12, 2001 and was immediately collected. It is an ordinary chondrite having a number of SiO2‐rich objects and some Ca, Al‐rich inclusions. Olivines (Fa17–19) are fairly equilibrated, while pyroxenes (Fs4–20) are unequilibrated. Occasionally, shock veins are visible, but the bulk rock sample is very weakly shocked (S2). Chondrules and chondrule fragments are abundant. Based on chemical and petrological features, Devgaon is classified as an H3.8 group chondrite. Several cosmogenic radionuclides ranging in half‐lives from 5.6 d (52Mn) to 7.3 times 105 yr (26Al), noble gases (He, Ne, Ar, Kr, and Xe), and particle track density have been measured. The track density in olivines from five spot samples varies between (4.6 to 9) × 106 cm?2 showing a small gradient within the meteorite. The light noble gases are dominated by cosmogenic and radiogenic components. Large amounts of trapped gases (Ar, Kr, and Xe) are present. In addition, (n, γ) products from Br and I are found in Kr and Xe, respectively. The average cosmic ray exposure age of 101 ± 8 Ma is derived based on cosmogenic 38Ar, 83Kr, and 126Xe. The track production rates correspond to shielding depths of about 4.9 to 7.8 cm, indicating that the stone suffered type IV ablation. Low 60Co, high (22Ne/21Ne)c, and large neutron produced excesses at 80Kr, 82Kr, and 128Xe indicate a complex exposure history of the meteoroid. In the first stage, a meter‐sized body was exposed for nearly 108 yr in the interplanetary space that broke up in ?50 cm‐sized fragments about a million years ago (stage 2), before it was captured by the Earth. 相似文献
15.
V. P. SEMENENKO A. BISCHOFF I. WEBER C. PERRON A. L. GIRICH 《Meteoritics & planetary science》2001,36(8):1067-1085
Abstract— Two dark lithic fragments and matrix of the Krymka LL3.1 chondrite were mineralogically and chemically studied in detail. These objects are characterised by the following chemical and mineralogical characteristics, which distinguish them from the host chondrite Krymka: (1) bulk chemical analyses revealed low totals (systematically lower than 94 wt%) due to high porosity; (2) enrichment in FeO and depletion in S, MgO and SiO2 due to a high abundance of Fe‐rich silicates and low sulfide abundance; (3) fine‐grained, almost chondrule‐free texture with predominance of a porous, cryptocrystalline groundmass and fine grains; (4) occurrence of a small amount of once‐molten material (microchondrules) enclosed in fine‐grained materials; (5) occurrence of accretionary features, especially unique accretionary spherules; (6) high abundance of small calcium‐ aluminium‐rich inclusions (CAIs) in one of the fine‐grained fragments. It is suggested that the abundance of CAIs in this fragment is one of the highest ever found in an ordinary chondrite. Accretionary, fine‐grained spherules within one of the fragments bear fundamental information about the initial stages of accretion as well as on the evolution of the clast, its incorporation, and history within the bulk rock of Krymka. The differences in porosity, bulk composition, and mineralogy of cores and rims of the fine‐grained spherulitic objects allow us to speculate on the following processes: (1) Low velocity accretion of tiny silicate grains onto the surface of coarse metal or silicate grains in a dusty region of the nebula is the beginning of the formation of accretionary, porous (fluffy) silicate spherules. (2) Within a dusty environment with decreasing silicate/(metal + sulfide) ratio the porous spherules collected abundant metal and sulfide particles together with silicate dust, which formed an accretionary rim. Variations of the silicate/(sulfide + metal) ratio in the dusty nebular environment result in the formation of multi‐layered rims on the surface of the silicate‐rich spherules. (3) Soft accretion and lithification of rimmed, fluffy spherules, fine‐grained, silicate‐rich dust, metal‐sulfide particles, CAIs, silicate‐rich microchondrules, and coarse silicate grains and fragments followed. (4) After low‐temperature processing of the primary, accretionary rock collisional fragmentation occurred, the fragments were subsequently coated by fine‐grained material, which was highly oxidized and depleted in sulfides. (5) In a final stage this accretionary “dusty” rock was incorporated as a fragment within the Krymka host. 相似文献
16.
Addi BISCHOFF Miha JERSEK Thomas GRAU Breda MIRTIC Ulrich OTT Jan KUČERA Marian HORSTMANN Matthias LAUBENSTEIN Siegfried HERRMANN Zdeněk ŘANDA Marc WEBER Gerd HEUSSER 《Meteoritics & planetary science》2011,46(6):793-804
Abstract– On April 9, 2009, at 3:00 CEST, a very bright fireball appeared over Carinthia and the Karavanke Mountains. The meteoroid entered the atmosphere at a very steep angle and disintegrated into a large number of objects. Two main objects were seen as separate fireballs up to an altitude of approximately 5 km, and witnesses reported loud explosions. Three stones were found with a total weight of approximately 3.611 kg. The measured activity of short‐lived cosmogenic radionuclides clearly indicates that two specimens result from a very recent meteorite fall. All cosmogenic radionuclide concentrations suggest a rather small preatmospheric radius of <20 cm; a nominal cosmic‐ray exposure age based on 21Ne is approximately 4 Ma, but the noble gas and radionuclide results in combination indicate a complex irradiation. Jesenice is a highly recrystallized rock with only a few relic chondrules visible in hand specimen and thin section. The texture, the large grain size of plagioclase, and the homogeneous compositions of olivines and pyroxenes clearly indicate that Jesenice is a L6 chondrite. The bulk composition of Jesenice is very close to the published average element concentration for L ordinary chondrites. The chondrite is weakly shocked (S3) as indicated by the undulatory extinction in olivine and plagioclase and the presence of planar fractures in olivine. Being weakly shocked and with gas retention ages of >1.7 Ga (4He) and approximately 4.3 Ga (40Ar), Jesenice seems not to have been strongly affected by the catastrophic disruption of the L‐chondrite parent body approximately 500 Ma ago. 相似文献
17.
Abstract— NWA 2526 is a coarse‐grained, achondritic rock dominated by equigranular grains of polysynthetically twinned enstatite (?85 vol%) with frequent 120° triple junctions and ?10–15 vol% of kamacite + terrestrial weathering products. All other phases including troilite, daubreelite, schreibersite, and silica‐normative melt areas make up 相似文献
18.
Abstract— The Portales Valley meteorite provides an opportunity to investigate and compare the microstructure in Fe‐Ni metal of the metallic particles in the chondritic portion and in the metal veins. The low‐temperature phase decomposition of Fe‐Ni metal was investigated using scanning electron microscopy, transmission electron microscopy, and atomic force microscopy. The microstructure is formed as the Portales Valley meteorite cooled from high temperatures and includes the outer taenite rim, the cloudy zone, clear taenite, and martensite. Martensite in turn decomposes into a fine admixture of fcc rods in a bcc matrix. The width of the island phase of the cloudy zone in the metal particles of the chondritic portion and the metal veins can be used to estimate a low‐temperature cooling rate. The microstructural evidence indicates that the chondritic portions and the metal veins in the Portales Valley meteorite cooled together as a mixture with a cooling rate of roughly 6.5 K/Ma. 相似文献
19.
Josep M. Trigo‐Rodríguez Jordi Llorca Mona Weyrauch Addi Bischoff Carles E. Moyano‐Cambero Klaus Keil Matthias Laubenstein Andreas Pack José María Madiedo Jacinto Alonso‐Azcárate My Riebe Rainer Wieler Uli Ott Mar Tapia Narcís Mestres 《Meteoritics & planetary science》2014,49(8):1475-1484
We report and describe an L6 ordinary chondrite fall that occurred in Ardón, León province, Spain (longitude 5.5605°W, latitude 42.4364°N) on July 9th, 1931. The 5.5 g single stone was kept hidden for 83 yr by Rosa González Pérez, at the time an 11 yr old who had observed the fall and had recovered the meteorite. According to various newspaper reports, the event was widely observed in Northern Spain. Ardón is a very well‐preserved, fresh, strongly metamorphosed (petrologic type 6), and weakly shocked (S3) ordinary chondrite with well‐equilibrated and recrystallized minerals. The mineral compositions (olivine Fa23.7±0.3, low‐Ca pyroxene Fs20.4±0.2Wo1.5±0.2, plagioclase An10.3±0.5Ab84.3±1.2), magnetic susceptibility (log χ = 4.95 ± 0.05 × 10?9 m3 kg?1), bulk density (3.49 ± 0.05 g cm?3), grain density (3.58 ± 0.05 g cm?3), and porosity (2.5 vol%) are typical for L6 chondrites. Short‐lived radionuclides confirm that the meteorite constitutes a recent fall. The 21Ne and 38Ar cosmic ray exposure ages are both about 20–30 Ma, similar to values for many other L chondrites. The cosmogenic 22Ne/21Ne ratio indicates that preatmospheric Ardón was a relatively large body. The fact that the meteorite was hidden in private hands for 83 yr makes one wonder if other meteorite falls may have experienced the same fate, thus possibly explaining the anomalously low number of falls reported in continental Spain in the 20th century. 相似文献
20.
A. BISCHOFF 《Meteoritics & planetary science》1996,31(6):849-855
Abstract— Lunar meteorite QUE 93069 found in Antarctica is a mature, anorthitic regolith breccia with highland affinities that was ejected from the Moon <0.3 Ma ago. The frequency distribution of mineral and lithic clasts gives information about the nature of the regolith and subregolith basement near the ejection site as well as about the abundances of rock types shocked to different degrees prior to the breccia formation. Thin section QUE 93069,37 consists of 67.5 vol% fine-grained (<～130 μm) constituents and 32.5 vol% mineral and lithic clasts and an impact melt vein. The most abundant types of these clasts are intragranularly recrystallized anorthosites and plagioclases (together 26.3 vol%) and feldspathic fine-grained to microporphyritic crystalline melt breccias (21.9 vol%). Mafic crystalline melt breccias are extremely rare (1.3 vol%). Granulitic lithologies are 10.4 vol%, recrystallized feldspathic melt breccias are 15.0 vol%, and glasses are 3.5 vol%. The impact melt vein cutting across the entire thin section was probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Lunar meteorite QUE 93069 has a higher abundance of clear glass, occurring within melt spherules, glassy fragments, and an impact melt vein than lunar meteorites ALHA81005, Y-791197, Y-82192/3, Y-86032, or MAC 88104/5. The high abundance of melt spherules indicates that this lunar meteorite contains the highest content of typical regolith components. Mafic crystalline melt breccias are much rarer in QUE 93069 than in all other lunar highland regolith breccias. The extremely low abundance of mafic components may constrain possible areas of the Moon, from which the breccia was derived. The source area of QUE 93069 must be a highland terrain lacking significant mafic impact melts or mare components. 相似文献