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We performed laboratory experiments on the bidirectional reflectance of powdered surfaces of dunite, graphite, and Allende (CV3) and Gao (H5) meteorites. The particle size of each sample varied from tens to hundreds of micrometers. The absolute bidirectional reflectance was determined for two ranges of phase angle: from 2° to 80° at 0° angle of incidence and from 2° to 155° at 75° angle of incidence. The phase angle was incremented every 1° in between 2° and 5° and every 10° between 10° and 150°. We determined the Hapke parameters and found that the values of the asymmetry parameter retrieved for most of the samples were positive when the coverage of the phase angle was wide, 2° to 155°, although the values derived from remote sensing instruments on asteroid flyby missions have been negative or nearly zero. Among our sample surfaces, only those of graphite, Allende, and Gao with particle sizes of hundreds micrometers show negative or nearly zero values. The single-scattering albedos determined for the Gao samples are comparable to the values of S-class asteroids, while those for the Allende samples are much larger than those of C-class asteroids. 相似文献
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Mineralogical and isotopic studies were carried out on the natural nuclear reaction zone 2 from the Oklo deposit to evaluate the mobility of several nuclear reaction products in response to the alteration of the reaction zone and to identify the mechanisms which could retard the transport of released radionuclides. To address these issues, in situ isotopic analyses by SHRIMP and a selective extraction procedure were performed to constrain the structural location of nuclear reaction products (exchangeable and non exchangeable) and their association with mineral phases. The distribution patterns of U, REE, Zr and Mo isotopes reveal that substantial amounts were released from the core and migrated through the hydrothermal alteration halo over metric distances, owing to uraninite dissolution and advective transport by hydrothermal solutions during and soon after criticality. The results emphasize the mobility of Zr at Oklo, this element being often considered as “immobile” during water–rock interactions. The main output is the demonstration of the net effects of sorption and coprecipitation processes. Chlorite and to a lesser extent illite were found to have adsorbed significant amounts of U, REE, Zr (and probably Th) and less sorbing elements such as Mo. Coprecipitation of secondary UO2 and P-rich coffinite within the alteration halo is also an important means of retardation. The concentration of radionuclides released from the reactor were probably high and they display solubility limited transport behaviour. No retention effect was found for Se in the immediate vicinity of the reactor and this element may have moved farther from its source of production. These results have interesting implications for the evaluation of long-term containment of radionuclides. They provide a simple illustration of the performance of a clay barrier in the uptake of radionuclides by sorption onto clays and reincorporation in secondary U-minerals. This study also demonstrates the robustness of these retention processes over extremely long periods of time. 相似文献
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Cretaceous granitic rocks are widely distributed in the northern to central parts of Kyushu Island, southwest Japan arc, and are divided into two types, granite and tonalite-granodiorite. These rocks are clearly defined by their mineral assemblage, that is, the granite contains mostly muscovite and/or garnet and does not have hornblende, whereas the tonalite-granodiorite is always observed with hornblende. Many workers suggest that most of the granite has low initial Sr isotopic ratios (SrI90 Ma: 0.7052-0.7059) whose values are similar to those of tonalite-granodiorite (SrI90 Ma: 0.7050-0.7056).
The SiO2 contents of the granite (67.9 to 78.0 wt.%) are higher than that of tonalite-granodiorite (54.2 to 68.2 wt.%). The granite is characterized by peraluminous compositions, while the tonalite-granodiorite shows metaluminous to peraluminous compositions. The petrogenetic relation between granite and tonalite-granodiorite is examined by a modal batch melting model, which referred to results of already published experiments. The result of the model suggests that the petrogenesis of the peraluminous granitic magma can be explained by an anatexis of metaluminous tonalite in the tonalite-granodiorite under lower to middle crustal conditions and variable fH2O.
Rocks of tonalite to granodiorite in a subduction system generally have low initial Sr isotopic ratios (<0.705), which imply that the magma derived from a highly metaluminous origin such as mafic magma, mafic lower crust and/or subducting slab. In this study, it is regarded that the peraluminous granitic magma can be directly produced by an anatexis of metaluminous tonalite. Therefore, peraluminous granite with low initial Sr isotopic ratios may imply to a first step of recycling of the granitic layer in an active plate margin. 相似文献
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H. M. Zakir Hossain Quazi Hasna Hossain Atsushi Kamei Daisuke Araoka 《Arabian Journal of Geosciences》2018,11(23):749
The modal and chemical composition of sands from Cox’s Bazar beach (CBB) and Kuakata beach (KB) areas of Bangladesh has been investigated to infer their maturity, chemical weathering, and provenance signatures. The CBB and KB sands are typically high quartz, low feldspar, and lithic fragments, representing a recycled orogen source. Major element compositions of CBB sands are characterized by high SiO2 (83.52–89.84 wt%) and low Al2O3 (4.39–6.39 wt%), whereas KB sands contained relatively low SiO2 (63.28–79.14 wt%) and high Al2O3 (9.00–11.33 wt%) contents. The major, trace and rare earth element (REE) compositions of beach sands display comparable distribution patterns with enriched Th and SiO2 for both sands relative to upper continental crust (UCC). Pb, Rb, Y, and Fe for KB sands are little higher than UCC and the rest of the elements are marked depleted for both suites reflecting destruction of plagioclase and K-feldspar during fluvial transportation. The CBB and KB sands are compositionally low mature to immature in nature subsequently classified as subarkose and litharenite, respectively. Chondrite-normalized REE patterns for CBB and KB sands show LREE enrichment and nearly flat HREE (LaN/YbN, 7.64–9.38 and 5.48–8.82, respectively) coupled with prominent Eu anomalies (Eu/Eu*, 0.51–0.72 and 0.52–0.76, respectively), suggesting felsic source provenance. The provenance discrimination diagrams, immobile trace element ratios (Th/Sc, Zr/Sc, Ce/Sc, and Ti/Zr), and REE (∑LREE/HREE, Eu/Eu* and GdN/YbN) parameters indicate that CBB and KB sands were largely derived from felsic source rocks, with compositions close to average rhyolite, granodiorite, granite, and UCC. 相似文献
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Quantitative determination of the degree of chemical weathering of rocks is a fundamental task in environmental and engineering geology, and many weathering indices based on whole-rock chemistry have been proposed. However, most classical indices are of limited application to granitoids in a wide area, because these lithotypes generally exhibit wide chemical variation arising from their petrogenesis. The chemical evolution produced during rock weathering, therefore, overprints pre-existing magmatic chemical variation. This problem can cause many classical weathering indices to yield misleading results. This study proposes a method that compensates for the influence of petrogenesis on calculation of the weathering index. The method is based on a bivariate plot of the magmatic chemical variation (MCV) in granitoids, and the degree of chemical weathering (DCW). The MCV axis must be based on an element that reflects magmatic processes and is also relatively immobile during rock weathering. In this study TiO2 contents are utilized for the MCV. The DCW axis is fundamentally defined by the ratios of more-mobile to less-mobile elements during weathering, and hence many classical indices can be applied. The improved value of the degree of chemical weathering (DCWi) for a weathered rock is derived by:where MCV1 is the measured composition (e.g. TiO2 content) of the weathered rock. DCW1 denotes the ratios of more-mobile to less-mobile elements of the weathered rock. The “s” parameter is the slope of the least square linear regression for fresh granitoids in the MCV–DCW relationship. MCVCV is a correction factor which is given by the average point on the MCV axis (e.g. average TiO2) of the fresh rocks. This method is useful for evaluating the degree of weathering of various granitoids, and enhances the practical application of many weathering indices. 相似文献
DCWi=s×(MCVCV-MCV1)+DCW1
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In seismic waveform inversion, non‐linearity and non‐uniqueness require appropriate strategies. We formulate four types of L2 normed misfit functionals for Laplace‐Fourier domain waveform inversion: i) subtraction of complex‐valued observed data from complex‐valued predicted data (the ‘conventional phase‐amplitude’ residual), ii) a ‘conventional phase‐only’ residual in which amplitude variations are normalized, iii) a ‘logarithmic phase‐amplitude’ residual and finally iv) a ‘logarithmic phase‐only’ residual in which the only imaginary part of the logarithmic residual is used. We evaluate these misfit functionals by using a wide‐angle field Ocean Bottom Seismograph (OBS) data set with a maximum offset of 55 km. The conventional phase‐amplitude approach is restricted in illumination and delineates only shallow velocity structures. In contrast, the other three misfit functionals retrieve detailed velocity structures with clear lithological boundaries down to the deeper part of the model. We also test the performance of additional phase‐amplitude inversions starting from the logarithmic phase‐only inversion result. The resulting velocity updates are prominent only in the high‐wavenumber components, sharpening the lithological boundaries. We argue that the discrepancies in the behaviours of the misfit functionals are primarily caused by the sensitivities of the model gradient to strong amplitude variations in the data. As the observed data amplitudes are dominated by the near‐offset traces, the conventional phase‐amplitude inversion primarily updates the shallow structures as a result. In contrast, the other three misfit functionals eliminate the strong dependence on amplitude variation naturally and enhance the depth of illumination. We further suggest that the phase‐only inversions are sufficient to obtain robust and reliable velocity structures and the amplitude information is of secondary importance in constraining subsurface velocity models. 相似文献
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Ocean Dynamics - Residual mercury dynamic has been the research emphasis since mercury contamination was publicly recognized in Minamata Bay. Simulation of mercury distribution and transport... 相似文献
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