Simultaneous Determination of Cd,In, Tl and Bi by Isotope Dilution‐Internal Standardisation ICP‐QMS with Corrections Using Externally Measured MoO+/Mo+ Ratios     

Akio Makishima  Hiroshi Kitagawa  Eizo Nakamura 《Geostandards and Geoanalytical Research》2011,35(1):57-67

A method for the simultaneous determination of Cd with In, Tl and Bi by isotope dilution‐internal standardisation (ID‐IS) ICP‐QMS using the same aliquot for rare earth element and other trace element determinations was developed. Samples mixed with an enriched ¹⁴⁹Sm spike were decomposed using a HF‐HClO₄ mixture, which was evaporated and then diluted with HNO₃. After determination of Sm by ID‐ICP‐QMS and Cd, In, Tl and Bi concentrations were determined using the ¹⁴⁹Sm intensity as an internal standard. The interference of MoO⁺ on Cd⁺ was corrected using the MoO⁺/Mo⁺ ratio separately measured using a Mo standard solution, and the validity of the externally determined oxide‐forming ratio correction was evaluated. The MoO⁺/Mo⁺ ratios measured using the standard solution and samples were ～ 0.0002 and < 0.002, respectively. Detection limits for Cd, In, Tl and Bi in silicate samples were at levels of < 1 ng g^?1 with a total uncertainty of < 7%. Cadmium in the carbonaceous chondrites, Orgueil (CI1), Murchison (CM2) and Allende (CV3) as well as Cd, In, Tl and Bi in the reference materials, JB‐2, JB‐3, JA‐1, JA‐2, JA‐3, JP‐1 (GSJ), BHVO‐1, AGV‐1, PCC‐1 and DTS‐1 (USGS) and NIST SRM 610, 612, 614 and 616 were determined to show the applicability of this method.  相似文献   

Effects of dust scattering albedo and 2175-Å bump on ultraviolet colours of normal disc galaxies     

Akio K. Inoue  Veronique Buat  Denis Burgarella  Pasquale Panuzzo  Tsutomu T. Takeuchi †  Jorge Iglesias-Páramo 《Monthly notices of the Royal Astronomical Society》2006,370(1):380-398

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Bacterial growth rate and the relative abundance of bacteria to heterotrophic nanoflagellates in the euphotic and disphotic layers in temperate coastal waters of Sagami Bay,Japan     

Youta?SugaiEmail author  Kenji?Tsuchiya  Victor?S.?Kuwahara  Shinji?Shimode  Kazuhiro?Komatsu  Akio?Imai  Tatsuki?Toda 《Journal of Oceanography》2016,72(4):577-587

This study aimed to clarify the vertical differences in bacterial growth and grazing pressure on bacteria by heterotrophic nanoflagellates (HNF) and to identify the controlling factors of bacterial growth in temperate coastal waters of Sagami Bay, Japan. In addition to environmental factors, the annual monthly variations in bacterial growth rate (BGR) and the relative abundance of bacteria to HNF (BA/HNFA) were investigated in the euphotic and disphotic layers between May 2012 and May 2013. Significant vertical differences in BGR and BA/HNFA were evident between the two layers during the thermal stratification times of May to October 2012 and April to May 2013. BGR indicated significantly stronger limitation of bacterial growth in the euphotic layer compared to the disphotic layer. In contrast, significantly lower BA/HNFA was observed in the euphotic layer, suggesting significantly higher grazing pressure on bacteria by HNF. However, significant differences in BGR and BA/HNFA were not observed between the two layers from November 2012 to Match 2013, when the water column was well-mixed vertically due to the cooling and wind-induced mixing of surface water. This study indicates that bacteria in the euphotic layer grow less actively and are more vulnerable to predatory grazing by HNF relative to the disphotic layer during the stratification period. Further, multiple regression analyses indicate that bacterial growth was most controlled by the concentrations of chlorophyll a and dissolved organic carbon in the euphotic and disphotic layers, respectively.  相似文献   

High-pressure X-ray diffraction study of ε-FeOOH     

Akio Suzuki 《Physics and Chemistry of Minerals》2010,37(3):153-157

An in situ synchrotron X-ray diffraction study was carried out on ε-FeOOH at room temperature up to a pressure of 8.6 GPa using the energy-dispersive method. The linear compressibility was determined to be β _a  = 1.69(3) × 10⁻³ GPa⁻¹, β _b  = 2.86(6) × 10⁻³ GPa⁻¹, and β _c  = 1.73(5) × 10⁻³ GPa⁻¹. The b-axis of the unit cell is more compressible than the a and c axes. The pressure–volume data were fitted to a third-order Birch–Murnaghan equation of state. The best fit was found using a room temperature isothermal bulk modulus of K ₀ = 126(3) GPa and its pressure derivative K′ = 10(1).  相似文献   

Fluctuation in volume transport distribution accompanied by the Kuroshio front migration in the Tokara Strait   总被引：1，自引：0，他引：1  

Akio Maeda  Toru Yamashiro  Masahito Sakurai 《Journal of Oceanography》1993,49(2):231-245

A relation between migration of the Kuroshio front and fluctuation of distribution of volume transport in the Tokara Strait was described, using sea level records at five tide gauge stations around the strait and data which were composed of sea surface temperature, XBT casts, sea surface salinity and velocities at 20 m, 75 m and 150 m depths taken en route a ferryboat. The Kuroshio front extends to about 150 m depth. The sea surface salinity and the horizontal velocities abruptly change at the front. There is a good correlation in a period range from half a month to two months between the migration of the front, which is not only at the surface but also in the subsurface, and the sea level fluctuation at Nakano-shima. A northward migration of the front with a period range from 17 to 50 days decreases the transport in the southern strait between Naze and Nakano-shima but increases in the northern strait between Nakano-shima and Sata-misaki. The northward migration intensifies inflow into Kagoshima Bay and the Ohsumi Branch Current. Correlation between the transport in the northern strait and the Ohsumi Branch Current is significant in the period range from 30 to 50 days. In this significant period range, the former leads the latter by about 3 days.  相似文献   

Seismic activity in the northeastern Japan arc     

Akio Takagi  Akira Hasegawa  Norihito Umino  Ziro Suzuki 《Physics of the Earth and Planetary Interiors》1979,18(4):351-354

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日本内陆地震活动的迁移与扩散          下载免费PDF全文

吉田明夫  细野耕司 《地震工程学报》1989,11(4):105-116

本文研究了日本内陆及其外围海域发生大地震后的地震活动迁移现象。在所研究的6个震例中,一个共同的特点是,地震活动的迁移总是沿着地壳内的活动地质构造带发生。有时可以根据地震活动的迁移来进一步确定活动构造带的存在。把板块边缘地区的地震活动类比为沿着力学偶合平面迁移和扩散,我们可以认为,岛上的活动构造带对应着地壳块体的力学相互作用边界。地震迁移的形式可能不只一种。在我们所研究的震例中发现了以下特征:地震迁移速度约为几km/年;大地震震源区之间存在着地震空区;在每一条地震带上有一定的地震活动周期。地震迁移的一种可能机制是:由于地壳块体的相对运动,在其边界上的凹凸不平区造成了构造应力集中,这些凹凸不平区相继地发生破裂,形成了地震迁移。  相似文献   

Short-term temporal variations in iron concentration and speciation in a canal during a summer algal bloom     

Takashi Nagai  Akio Imai  Kazuo Matsushige  Kunihiko Yokoi  Takehiko Fukushima 《Aquatic Sciences - Research Across Boundaries》2008,70(4):388-396

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Double-planed deep seismic zone and upper-mantle structure in the Northeastern Japan Arc   总被引：6，自引：0，他引：6  

Akira Hasegawa  Norihito Umino  Akio Takagi 《Geophysical Journal International》1978,54(2):281-296

Summary. The ScSp wave converted from the ScS wave at the boundary between the descending lithospheric slab and the mantle above it was clearly observed from a nearby deep earthquake with magnitude 7.7 at some stations of the seismic network of Tohoku University which covers the Tohoku District, the northeastern part of Honshu, Japan. By applying the three-dimensional seismic-ray tracing method, the location of this boundary was determined from the difference in arrival time between the ScS and ScSp waves. The result shows that the upper boundary of the descending slab lies exactly on the upper plane of the double-planed deep seismic zone found in the Northeastern Japan Arc.
There is an additional evidence that the boundary is located on the upper plane of the double-planed deep seismic zone. The hypocentre distribution of intermediate-depth earthquakes located by the small-scale seismic-array observation is extremely different from that obtained by the relatively large-scale seismic network. The discrepancy in the distribution of hypocentres of the same earthquake independently located is well explained by the inclined lithospheric slab model derived from the difference in arrival time between the ScS and ScSp waves.
The earthquakes with reverse faulting or with down-dip compressional stresses occur at the upper boundary of the descending slab. Within the descending slab, the earthquakes with down-dip extensional stresses also occur in a very narrow zone from 30 to 40 km below the dipping boundary in the depth range from 50 to about 200 km, and these shocks form the lower plane of the double-planed deep seismic zone.  相似文献   

Viscosity of silicate melts in CaMgSi2O6–NaAlSi2O6 system at high pressure     

Akio Suzuki  Eiji Ohtani  Hidenori Terasaki  Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2005,32(2):140-145

In situ X-ray viscometry of the silicate melts was carried out at high pressure and at high temperature. The viscosity of the silicate melts in the diopside(Di)–jadeite(Jd) system was determined in the pressure range from 1.88 GPa to 7.9 GPa and in the temperature range from 2,003 K to 2,173 K. The viscosity of the Di 25%–Jd 75% melt decreases continuously to 5.0 GPa, whereas the viscosity of the Di 50%–Jd 50% melt increases over 3.5 GPa. The viscosity of the Di50%–Jd 50% melt reaches a minimum around 3.5 GPa. Since the amounts of silicon in the two melts are the same, the difference in the pressure dependence of the viscosity may be controlled by another network-forming element, i.e., aluminum. The difference in the pressure dependence of the viscosities in the melts with two intermediate compositions in the Di–Jd system is estimated to be due to the difference in the melt structures at high pressures and high temperatures.  相似文献