Asbestos and other fibrous minerals contained in the serpentinites of the Gimigliano-Mount Reventino Unit (Calabria,S-Italy)   总被引：1，自引：1，他引：0  

Andrea Bloise  Teresa Critelli  Manuela Catalano  Carmine Apollaro  Domenico Miriello  Alessandro Croce  Eugenio Barrese  Francesca Liberi  Eugenio Piluso  Caterina Rinaudo  Elena Belluso 《Environmental Earth Sciences》2014,71(8):3773-3786

Serpentinites are metamorphic rocks with good technological properties and valuable ornamental characteristics, which have been exploited since ancient times. Actually, their use is limited and monitored in several countries worldwide because they can contain fibrous asbestos minerals that may be carcinogenic. Furthermore, certain types of fibrous minerals can be confused with asbestos, and must therefore be carefully investigated. We have investigated the possible presence of the asbestos and non-asbestos fibrous phases contained in serpentinitic rocks in a meta-ophiolitic sequence from the Gimigliano-Mount Reventino Unit (Southern Italy), which had not been previously assessed. The detection and quantification of asbestos and the correct distinction of the fibrous non-asbestos minerals are very important not only from a scientific point of view, but also from a legislative one. This is especially the case for the administrative agencies that have to take decisions with regards to the implementation of public and occupational health protection measures (e.g., in road yards and quarry excavations). As a consequence of this, serpentinitic rock samples have been characterized in detail through X-ray powder diffraction, scanning and transmission electron microscopy combined with energy-dispersive spectrometry, analytical electron microscopy (SEM–EDS and TEM–AEM), differential scanning calorimetry, thermogravimetry and micro-Raman spectroscopy. Two kinds of asbestos and four kinds of non-asbestos fibrous silicates have been detected in the examined samples. In order of decreasing abundance these are polygonal serpentine, chrysotile, fibrous antigorite, tremolite, gedrite and magnesiohornblende. The size, morphology, crystallinity and chemical composition of the fibres were also discussed, in the light of the possible role these properties could play in the carcinogenic effect on human health.  相似文献   

A one-dimensional viscoelastic and viscoplastic constitutive approach to modeling the delayed behavior of clay and organic soils     

Aldo Madaschi  Alessandro Gajo 《Acta Geotechnica》2017,12(4):827-847

Accurate modeling of the time-dependent behavior of geomaterials is of great importance in a number of engineering structures interacting with soft, highly compressible clay layers or with organic clays and peats. In this work, a uniaxial constitutive model, based on Perzyna’s overstress theory and directly extendible to multiaxial stress conditions, is formulated and validated. The proposed constitutive approach essentially has three innovative aspects. The first concerns the implementation of two viscoplastic mechanisms within Perzyna’s theory in order to distinguish between short-term (quasi-instantaneous) and long-term plastic responses. Similarly, elastic response is simulated by combining an instantaneous and a long-term viscous deformation mechanism. The second innovative aspect concerns the use of a bespoke logarithmic law for viscous effects, which has never been used before to simulate delayed soil behavior (as far as the authors are aware). The third concerns the model’s extensive validation by simulating a number of different laboratory test results, including conventional and unconventional oedometer tests with small and large load increments/decrements and wide and narrow loading/unloading cycles, constant rates of stress and strain tests, and oedometer tests performed in a Rowe consolidation cell with measurement of pore pressure dissipation.  相似文献   

A quantitative approach to the influence of pyrite separation on Cu-processing tailings: a case study at Reps,Mirdita district,Albania     

Irene Fantone  Giovanni Grieco  Agim Sinojmeri  Alessandro Cavallo 《Environmental Earth Sciences》2017,76(22):774

Sulfide-rich tailings are a well-known environmental threat due to their production of acid drainage (AD) and release of potential toxic elements (PTE) to the local environment. The presence of heterogeneous materials produces complex environmental signatures and complicates the quantitative prediction of contamination. The present work provides a method of quantifying such heterogeneities, starting from mineral processing data of the Reps, Mirdita (Albania) site. A quantitative flow sheet (QF) method was applied to a selected dump site of the Mirdita copper mining district where secondary pyrite separation had been used in the past. The site is subject to long-lasting (10³ years) AD processes with significant release of PTE into the local environment. The tailings at the Reps site are divided into two classes based on the sulfide S content, respectively, represented by high-sulfide-content (S > 10 wt%) materials (hS) and low-sulfide-content (S < 3 wt%) material (lS). The reconstruction of the QF allowed us to identify the hS tailings as the discharge of single-flotation processing lines. This material accounts for about 82% of the total potential H₂SO₄ production, even though it represents < 20% of the entire tailing discard. The QF is a useful tool for the evaluation of heterogeneity and consequently for the modeling of waste management within abandoned sites and in working plants. Given a good quantification, heterogeneity can in fact support the setting of pyrite separation lines or the separate management of pyrite-rich tailing dumps.  相似文献   

ASPHAA: A GIS‐Based Algorithm to Calculate Cell Area on a Latitude‐Longitude (Geographic) Regular Grid     

Monia Santini  Andrea Taramelli  Alessandro Sorichetta 《Transactions in GIS》2010,14(3):351-377

One characteristic of a Geographic Information System (GIS) is that it addresses the necessity to handle a large amount of data at multiple scales. Lands span over an area greater than 15 million km² all over the globe and information types are highly variable. In addition, multi‐scale analyses involve both spatial and temporal integration of datasets deriving from different sources. The currently worldwide used system of latitude and longitude coordinates could avoid limitations in data use due to biases and approximations. In this article a fast and reliable algorithm implemented in Arc Macro Language (AML) is presented to provide an automatic computation of the surface area of the cells in a regularly spaced longitude‐latitude (geographic) grid at different resolutions. The approach is based on the well‐known approximation of the spheroidal Earth's surface to the authalic (i.e. equal‐area) sphere. After verifying the algorithm's strength by comparison with a numerical solution for the reference spheroidal model, specific case studies are introduced to evaluate the differences when switching from geographic to projected coordinate systems. This is done at different resolutions and using different formulations to calculate cell areas. Even if the percentage differences are low, they become relevant when reported in absolute terms (hectares).  相似文献   

The role of structural inheritance in continental break-up and exhumation of Alpine Tethyan mantle(Canavese Zone,Western Alps)     

Andrea Festa  Gianni Balestro  Alessandro Borghi  Sara De Caroli  Andrea Succo 《地学前缘(英文版)》2020,11(1):167-188

The Canavese Zone(CZ)in the Western Alps represents the remnant of the distal passive margin of the Adria microplate,which was stretched and thinned during the Jurassic opening of the Alpine Tethys.Through detailed geological mapping,stratigraphic and structural analyses,we document that the continental break-up of Pangea and tectonic dismemberment of the Adria distal margin,up to mantle rocks exhumation and oceanization,did not simply result from the syn-rift Jurassic extension but was strongly favored by older structu ral inheritances(the Proto-Canavese Shear Zone),which controlled earlier lithospheric weakness.Our findings allowed to redefine in detail(i)the tectono-stratigraphic setting of the Variscan metamorphic basement and the Late Carbonife rous to Early Cretaceous CZ succession,(ii)the role played by inherited Late Carboniferous to Early Triassic structures and(iii)the significance of the CZ in the geodynamic evolution of the Alpine Tethys.The large amount of extensional displacement and crustal thinning occurred during different pulses of Late Carbonife rous-Early Triassic strike-slip tectonics is wellconsistent with the role played by long-lived regional-scale wrench faults(e.g.,the East-Variscan Shear Zone),suggesting a re-discussion of models of mantle exhumation driven by low-angle detachment faults as unique efficient mechanism in stretching and thinning continental crust.  相似文献   

Real-time assimilation of streamflow observations into a hydrological routing model: effects of model structures and updating methods   总被引：1，自引：1，他引：0  

Maurizio Mazzoleni  Haksu Lee  Yuqiong Liu  Dong-Jun Seo  Alessandro Amaranto 《水文科学杂志》2018,63(3):386-407

This paper comparatively assesses the performance of five data assimilation techniques for three-parameter Muskingum routing with a spatially lumped or distributed model structure. The assimilation techniques used include direct insertion (DI), nudging scheme (NS), Kalman filter (KF), ensemble Kalman filter (EnKF) and asynchronous ensemble Kalman filter (AEnKF), which are applied to river reaches in Texas and Louisiana, USA. For both lumped and distributed routing, results from KF, EnKF and AEnKF are sensitive to the error specification. As expected, DI outperformed the other models in the case of lumped modelling, while in distributed routing, KF approaches, particularly AEnKF and EnKF, performed better than DI or nudging, reflecting the benefit of updating distributed states through error covariance modelling in KF approaches. The results of this work would be useful in setting up data assimilation systems that employ increasingly abundant real-time observations using distributed hydrological routing models.  相似文献   

Spatial pattern analysis using hybrid models: an application to the Hellenic seismicity     

Marianna?SiinoEmail author  Giada?Adelfio  Jorge?Mateu  Marcello?Chiodi  Antonino?D’Alessandro 《Stochastic Environmental Research and Risk Assessment (SERRA)》2017,31(7):1633-1648

Earthquakes are one of the most destructive natural disasters and the spatial distribution of their epicentres generally shows diverse interaction structures at different spatial scales. In this paper, we use a multi-scale point pattern model to describe the main seismicity in the Hellenic area over the last 10 years. We analyze the interaction between events and the relationship with geological information of the study area, using hybrid models as proposed by Baddeley et al. (2013). In our analysis, we find two competing suitable hybrid models, one with a full parametric structure and the other one based on nonparametric kernel estimators for the spatial inhomogeneity.  相似文献   

Integrated Electrical Resistivity Tomography and Ground Penetrating Radar Measurements Applied to Tomb Detection     

Rita Deiana  Jacopo Bonetto  Alessandro Mazzariol 《Surveys in Geophysics》2018,39(6):1081-1105

The integrated use of electrical resistivity tomography (ERT) and ground penetrating radar (GPR) measurements, and in particular the joint analysis of 2D and 3D data, can represent a valid solution for target identification at complex archaeological sites. A good example, in this respect, is given by the case study of a Phoenician–Punic necropolis in the archaeological site of Nora, in southern Sardinia (Italy), where GPR and ERT measurements were collected before site excavation. In this specific case, the mix of soil and air in the buried chambers, as well as the orientation and the complex spatial distribution of these structures into the sandstone bedrock, generated a number of anomalies difficult to interpret only using 2D results. Only the integration of all GPR and ERT data in a 3D view, and the comparison with archaeological evidence after the excavation, allowed a solid interpretation of geophysical anomalies visible in the 2D sections. Overall, this case study demonstrates the efficiency of the combined use of GPR and ERT acquisitions and shows how, in general, only the joint analysis of 2D data and in a 3D view can help the interpretation of the real distribution of the buried archaeological remains at similar archaeological complex sites.  相似文献   

Channel mobility drives a diverse stratigraphic architecture in the dryland Mojave River (California,USA)     

Alessandro Ielpi  Mathieu G.A. Lapôtre  Alvise Finotello  Massimiliano Ghinassi  Andrea D'Alpaos 《地球表面变化过程与地形》2020,45(8):1717-1731

The links between flood frequency and rates of channel migration are poorly defined in the ephemeral rivers typical of arid regions. Exploring these links in desert fluvial landscapes would augment our understanding of watershed biogeochemistry and river morphogenesis on early Earth (i.e. prior to the greening of landmasses). Accordingly, we analyse the Mojave River (California), one of the largest watercourses in the Great Basin of the western United States. We integrate discharge records with channel-migration rates derived from dynamic time-warping analysis and chronologically calibrated subsidence rates, thereby constraining the river's formative conditions. Our results reveal a slight downstream decrease in bankfull discharge on the Mojave River, rather than the downstream increase typically exhibited by perennial streams. Yet, the number of days per year during which the channel experiences bankfull or higher stages is roughly maintained along the river's length. Analysis of historical peak flood records suggests that the incidence of channel-formative events responds to modulation in watershed runoff due to the precipitation in the river's headwaters over decades to centuries. Our integrated analysis finally suggests that, while maintaining hydraulic geometries that are fully comparable with many other rivers worldwide, ephemeral desert rivers akin to the Mojave are capable of generating a surprisingly wide range of depositional geometries in the stratigraphic record. © 2020 John Wiley & Sons, Ltd.  相似文献   

A novel insight into vertical ground motion modelling in earthquake engineering     

Luca Prakash Argani  Alessandro Gajo 《国际地质力学数值与分析法杂志》2022,46(1):164-186

Recent observations of failure and damage of buildings and structures under seismic action has led to an increasing interest for an in-depth analysis of the vertical component of site ground motion. In particular, when dealing with saturated soils, the current engineering practice does not usually go beyond the simplified $u$–$p$ formulation of the Biot's equations describing the coupled hydro-mechanical behaviour, thus neglecting some terms of fluid inertial forces, despite the presence of more refined formulations, for example, the $u$–$U$ formulation. Therefore, a theoretical and numerical validation of the $u$–$p$ formulation as compared with the $u$–$U$ formulation is proposed in this work, where the numerical simulations are compared with the analytical solution for the $u$–$p$ formulation, which is also derived and illustrated in this text. The comparison between the two formulations and the analytical solution is provided for different levels of permeability and dynamic actions, which are representative of a wide scenario of site ground properties and seismic hazard in the vertical direction. In particular, the soil response is analysed in terms of acceleration and pore pressure time history, frequency content, acceleration response spectrum, and amplification ratio of acceleration. This study extends the discussion of the limits of applicability of the $u$–$p$ formulation with respect to the rigorous solution of Biot's equations (obtained here with $u$–$U$ formulation) to the context of a complex dynamic regime provided by the vertical components of real earthquake records, and paves the way for further investigations.  相似文献