Variations in the δ15N and δ18O values of nitrate in drainage water of two fertilized fields in Mecklenburg-Vorpommern (Germany)     

Barbara Deutsch  Iris Liskow  Petra Kahle  Maren Voss 《Aquatic Sciences - Research Across Boundaries》2005,67(2):156-165

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A multi‐step model for the origin of E3 (enstatite) chondrites     

Melinda HUTSON  Alex RUZICKA 《Meteoritics & planetary science》2000,35(3):601-608

Abstract— It appears that the mineralogy and chemical properties of type 3 enstatite chondrites could have been established by fractionation processes (removal of a refractory component, and depletion of water) in the solar nebula, and by equilibration with nebular gas at low‐to‐intermediate temperatures (approximately 700–950 K). We describe a model for the origin of type 3 enstatite chondrites that for the first time can simultaneously account for the mineral abundances, bulk‐chemistry, and phase compositions of these chondrites by the operation of plausible processes in the solar nebula. This model, which assumes a representative nebular gas pressure of 10^?5 bar, entails three steps: (1) initial removal of 56% of the equilibrium condensed phases in a system of solar composition at 1270 K; (2) an average loss of 80–85% water vapor in the remaining gas; and (3) two different closure temperatures for the condensed phases. The first step involves a “refractory element fractionation” and is needed to account for the overall major element composition of enstatite chondrites, assuming an initial system with a solar composition. The second step, water‐vapor depletion, is needed to stabilize Si‐bearing metal, oldhamite, and niningerite, which are characteristic minerals of the enstatite chondrites. Variations in closure temperatures are suggested by the way in which the bulk chemistry and mineral assemblages of predicted condensates change with temperature, and how these parameters correlate with the observations of enstatite chondrites. In general, most phases in type 3 enstatite chondrites appear to have ceased equilibrating with nebular gas at approximately 900–950 K, except for Fe‐metal, which continued to partially react with nebular gas to temperatures as low as ～700 K.  相似文献   

Crystal‐bearing lunar spherules: Impact melting of the Moon's crust and implications for the origin of meteoritic chondrules     

Alex RUZICKA  Gregory A. SNYDER  Lawrence A. TAYLOR 《Meteoritics & planetary science》2000,35(1):173-192

Abstract— Crystal‐bearing lunar spherules (CLSs) in lunar breccia (14313, 14315, 14318), soil (68001, 24105), and impact‐melt rock (62295) samples can be classified into two types: feldspathic and olivine‐rich. Feldspathic CLSs contain equant, tabular, or acicular plagioclase grains set in glass or a pyroxene‐olivine mesostasis; the less common olivine‐rich CLSs contain euhedral or skeletal olivine set in glass, or possess a barred‐olivine texture. Bulk‐chemical and mineral‐chemical data strongly suggest that feldspathic CLSs formed by impact melting of mixtures of ferroan anorthosite and Mg‐suite rocks that compose the feldspathic crust of the Moon. It is probable that olivine‐rich CLSs also formed by impact melting, but some appear to have been derived from distinctively magnesian lunar materials, atypical of the Moon's crust. Some CLSs contain reversely‐zoned “relic” plagioclase grains that were not entirely melted during CLS formation, thin (≤5 μm thick) rims of troilite or phosphate, and chemical gradients in glassy mesostases attributed to metasomatism in a volatile‐rich (Na‐K‐P‐rich) environment. Crystal‐bearing lunar spherules were rimmed and metasomatized prior to brecciation. Compound CLS objects are also present; these formed by low‐velocity collisions in an environment, probably an ejecta plume, that contained numerous melt droplets. Factors other than composition were responsible for producing the crystallinity of the CLSs. We agree with previous workers that relatively slow cooling rates and long ballistic travel times were critical features that enabled these impact‐melt droplets to partially or completely crystallize in free‐flight. Moreover, incomplete melting of precursor materials formed nucleation sites that aided subsequent crystallization. Clearly, CLSs do not resemble meteoritic chondrules in all ways. The two types of objects had different precursors and did not experience identical rimming processes, and vapor fractionation appears to have played a less important role in establishing the compositions of CLSs than of chondrules. However, the many detailed similarities between CLSs and chondrules indicate that it is more difficult to rule out an origin for some chondrules by impact melting than some have previously argued. Differences between CLSs, chondrules, and their host rocks possibly can be reconciled with an impact‐melt origin for some chondrules when different precursors, the higher gravity of the Moon compared to chondrite parent bodies, and the likely presence of nebular gas during chondrule formation are taken into account.  相似文献   

Relative role and extent of marine and groundwater inundation on a dune‐dominated barrier island under sea‐level rise scenarios          下载免费PDF全文

Alex K. Manda  Michael S. Sisco  David J. Mallinson  Michael T. Griffin 《水文研究》2015,29(8):1894-1904

Climate change and sea‐level rise will have severe impacts on coastal water resources around the world. However, whereas the influence of marine inundation is well documented in the literature, the impact of groundwater inundation on coastal communities is not well known. Here, core analysis, groundwater monitoring, and ground penetrating radar are utilized to assess the groundwater regime of the surficial aquifer on Bogue Banks Barrier Island (USA). Then, geospatial techniques are used to assess the relative roles and extents of groundwater and marine inundation on the dune‐dominated barrier island under sea‐level rise scenarios of 0.2, 0.5, and 1.0 m above current conditions by 2100. Additionally, the effects of rising water tables on onsite wastewater treatment systems (OWTS) are modelled using the projected sea‐level rise scenarios. The results indicate that the surficial aquifer comprising fine to medium sands responds quickly to precipitation. Water‐level measurements reveal varying thicknesses of the vadose zone (>3 to 0 m) and several groundwater mounds with radial flow patterns. Results from projected sea‐level rise scenarios suggest that owing to aquifer properties and morphology of the island, groundwater inundation may occur at the same rate as marine inundation. Furthermore, the area inundated by groundwater may be as significant as that affected by marine inundation. The results also show that the proportion of land in the study area where OWTS may be perpetually compromised by rising water tables under worst case scenarios may range from ~43 to ~54% over an 86‐year‐period. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Exploring climate change impacts and adaptation options for maize production in the Central Rift Valley of Ethiopia using different climate change scenarios and crop models   总被引：1，自引：0，他引：1  

Belay T. Kassie  Senthold Asseng  Reimund P. Rotter  Huib Hengsdijk  Alex C. Ruane  Martin K. Van Ittersum 《Climatic change》2015,129(1-2):145-158

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Diagnosis of East African climate and the circulation mechanisms associated with extreme wet and dry events: a study based on RegCM4     

Bob Alex Ogwang  Haishan Chen  Guirong Tan  Victor Ongoma  Didier Ntwali 《Arabian Journal of Geosciences》2015,8(12):10255-10265

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The Ecological Impact of Conquest and Colonization on a Medieval Frontier Landscape: Combined Palynological and Geochemical Analysis of Lake Sediments from Radzyń Chełminski,Northern Poland     

Alex Brown  Rowena Banerjea  Amanda Dawn Wynne  Normunds Stivrins  Marc Jarzebowski  Lisa‐Marie Shillito  Aleks Pluskowski 《Geoarchaeology》2015,30(6):511-527

Slavic and German colonization of the southern Baltic between the 8th and 15th centuries A.D. is well‐documented archaeologically and historically. Despite the large number of pollen profiles from Poland, few palaeoecological studies have examined the ecological impact of a process that was central to the expansion of European, Christian, societies. This study aims to redress this balance through multiproxy analysis of lake sediments from Radzyń Chełminski, Northern Poland, using pollen, element geochemistry (Inductively Coupled‐Optical Emission Spectroscopy [ICP‐OES]), organic content, and magnetic susceptibility. The close association between lake and medieval settlements presents the ideal opportunity to reconstruct past vegetation and land‐use dynamics within a well‐documented archaeological, historical, and cultural context. Three broad phases of increasing landscape impact are visible in the pollen and geochemical data dating from the 8th/9th, 10th/11th, and 13th centuries, reflecting successive phases of Slavic and German colonization. This involved the progressive clearance of oak‐hornbeam dominated woodland and the development of an increasingly open agricultural landscape. Although the castles and towns of the Teutonic Order remain the most visible signs of medieval colonization, the palynological and geochemical data demonstrate that the major phase of woodland impact occurred during the preceding phase of Slavic expansion; Germans colonists were entering a landscape already significantly altered.  相似文献   

Remote sensing mapping of the regeneration of coastal natural habitats in Singapore: Implications for marine conservation in tropical cities     

Y. H. Jonathan Tan  Jacqueline K. Q. Tham  Aayush Paul  Umair Rana  Hui Ping Ang  Nhung T. H. Nguyen  Alex T. K. Yee  Bryan P. I. Leong  Simon Drummond  Karenne P. P. Tun 《Singapore journal of tropical geography》2023,44(1):130-148

Rapid urbanization has resulted in the loss of coastal and marine habitats in cities worldwide. The effective conservation of urban coastal ecosystems requires detailed knowledge of their spatial distribution, necessitating high-resolution mapping. Our study produces a high-resolution coastal and marine habitat map and shoreline map for the tropical city-state of Singapore created through pixel-based supervised classification of satellite imagery, bathymetry data and expert ground knowledge. These maps can be used as a base reference for multiple applications including ecological research, conservation and urban planning. They also help identifiy trends in the extent of key coastal habitats, providing insight into their differing levels of vulnerability to loss and potential for restoration to ensure long-term resilience. The method used for mapping shoreline typologies and resulting insights gained, can guide other rapidly urbanizing coastal cities on strategies to assemble useful spatial knowledge for effective conservation of their urban coastal ecosystems.  相似文献   

Carbon and water flux responses to physiology by environment interactions: a sensitivity analysis of variation in climate on photosynthetic and stomatal parameters     

William L. Bauerle  Alex B. Daniels  David M. Barnard 《Climate Dynamics》2014,42(9-10):2539-2554

Sensitivity of carbon uptake and water use estimates to changes in physiology was determined with a coupled photosynthesis and stomatal conductance (g _s) model, linked to canopy microclimate with a spatially explicit scheme (MAESTRA). The sensitivity analyses were conducted over the range of intraspecific physiology parameter variation observed for Acer rubrum L. and temperate hardwood C₃ (C₃) vegetation across the following climate conditions: carbon dioxide concentration 200–700 ppm, photosynthetically active radiation 50–2,000 μmol m^?2 s^?1, air temperature 5–40 °C, relative humidity 5–95 %, and wind speed at the top of the canopy 1–10 m s^?1. Five key physiological inputs [quantum yield of electron transport (α), minimum stomatal conductance (g ₀), stomatal sensitivity to the marginal water cost of carbon gain (g ₁), maximum rate of electron transport (J _max), and maximum carboxylation rate of Rubisco (V _cmax)] changed carbon and water flux estimates ≥15 % in response to climate gradients; variation in α, J _max, and V _cmax input resulted in up to ~50 and 82 % intraspecific and C₃ photosynthesis estimate output differences respectively. Transpiration estimates were affected up to ~46 and 147 % by differences in intraspecific and C₃ g ₁ and g ₀ values—two parameters previously overlooked in modeling land–atmosphere carbon and water exchange. We show that a variable environment, within a canopy or along a climate gradient, changes the spatial parameter effects of g ₀, g ₁, α, J _max, and V _cmax in photosynthesis-g _s models. Since variation in physiology parameter input effects are dependent on climate, this approach can be used to assess the geographical importance of key physiology model inputs when estimating large scale carbon and water exchange.  相似文献   

Silicon isotope fractionation during magmatic differentiation   总被引：3，自引：0，他引：3  

Paul S. Savage  R. Bastian Georg  Kevin W. Burton  Alex N. Halliday 《Geochimica et cosmochimica acta》2011,75(20):6124-6139

The Si isotopic composition of Earth’s mantle is thought to be homogeneous (δ³⁰Si = −0.29 ± 0.08‰, 2 s.d.) and not greatly affected by partial melting and recycling. Previous analyses of evolved igneous material indicate that such rocks are isotopically heavy relative to the mantle. To understand this variation, it is necessary to investigate the degree of Si isotopic fractionation that takes place during magmatic differentiation. Here we report Si isotopic compositions of lavas from Hekla volcano, Iceland, which has formed in a region devoid of old, geochemically diverse crust. We show that Si isotopic composition varies linearly as a function of silica content, with more differentiated rocks possessing heavier isotopic compositions. Data for samples from the Afar Rift Zone, as well as various igneous USGS standards are collinear with the Hekla trend, providing evidence of a fundamental relationship between magmatic differentiation and Si isotopes. The effect of fractionation has been tested by studying cumulates from the Skaergaard Complex, which show that olivine and pyroxene are isotopically light, and plagioclase heavy, relative to the Si isotopic composition of the Earth’s mantle. Therefore, Si isotopes can be utilised to model the competing effects of mafic and felsic mineral fractionation in evolving silicate liquids and cumulates.At an average SiO₂ content of ∼60 wt.%, the predicted δ³⁰Si value of the continental crust that should result from magmatic fractionation alone is −0.23 ± 0.05‰ (2 s.e.), barely heavier than the mantle. This is, at most, a maximum estimate, as this does not take into account weathered material whose formation drives the products toward lighter δ³⁰Si values. Mass balance calculations suggest that removal of continental crust of this composition from the upper mantle will not affect the Si isotopic composition of the mantle.  相似文献