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Fluxes of dissolved forms of iron and manganese across the sediment–water interface were studied in situ in the Gulf of Finland and the Vistula Lagoon (Baltic Sea), and in the Golubaya Bay (Black Sea) from 2001 to 2005. Fluxes were measured using chamber incubations, and sediment cores were collected and sliced to assess the porewater and solid phase metal distribution at different depths. Measured and calculated benthic fluxes of manganese and iron were directed out of sediment for all sites and were found to vary between 70–4450 and 5–1000 µmole m− 2 day− 1 for manganese and iron, respectively. The behavior of the studied metals at various redox conditions in the near-bottom water and in the sediment was the main focus in this study. Our results show the importance of bottom water redox conditions for iron fluxes. We measured no fluxes at oxic conditions, intermediate fluxes at anoxic conditions (up to 200 μmole m− 2 day− 1) and high fluxes at suboxic conditions (up to 1000 μmole m− 2 day− 1). Total dissolved iron fluxes were generally dominated by iron(II). Contribution of iron(III) to the total iron flux did not exceed 20%. Obtained fluxes of manganese at all studied regions showed a linear correlation (r2 = 0.97) to its concentration in the porewater of the top sediment layer (0–5 mm) and did not depend on dissolved oxygen concentrations of bottom water. Organically complexed iron and manganese were in most cases not involved in the benthic exchange processes.  相似文献   
104.
A method for collection of surface films on the sea has been developed and tested at various places along the Swedish West Coast. Considerable amounts of lipids on the sea surface were found even when no seaslicks were observed. Triglycerides, free fatty acids, and wax esters are the dominating constituents, and there are characteristic deviations in the fatty-acid patterns compared to the corresponding lipids dissolved in the sub-surface water. Organochlorine residues, phthalic acid esters and heavy metals also occur in considerable amounts.  相似文献   
105.
Two different methods of estimating the water exchange through the Baltic coastal region of Laxemar have been used, consisting of particle trajectories and passive tracers. Water is traced from and to a small discharge region near the coast. The discharge material in this region is treated as zero-dimensional particles or tracers with neutral buoyancy. The real discharge material could be a leakage of radio-nuclides through the sea floor from an underground repository of nuclear waste.Water exchange rates between the discharge region and the model domain are estimated using both forward and backward trajectories as well as passive tracers. The Lagrangian trajectories can account for the time evolution of the water exchange while the tracers give one average age per model grid box. Water exchange times such as residence time, age and transient times have been calculated with trajectories but only the average age (AvA) for tracers. The trajectory calculations provide a more detailed time evolution than the tracers.On the other hand the tracers are integrated “on-line” simultaneously in the sea circulation model with the same time step while the Lagrangian trajectories are integrated “off-line” from the stored model velocities with its inherent temporal resolution, presently 1 h. The sub-grid turbulence is parameterised as the Laplacian diffusion for the passive tracers and with an extra stochastic velocity for trajectories. The importance of the parameterised sub-grid turbulence for the trajectories is estimated to give an extra diffusion of the same order as the Laplacian diffusion by comparing the Lagrangian dispersions with and without parameterisation. The results of the different methods are similar but depend on the chosen diffusivity coefficient with a slightly higher correlation between trajectories and tracers when integrated with a lower diffusivity coefficient.  相似文献   
106.
Rates of transformation, recycling and burial of nitrogen and their temporal and spatial variability were investigated in deep-sea sediments of the Porcupine Abyssal Plain (PAP), NE Atlantic during eight cruises from 1996 to 2000. Benthic fluxes of ammonium (NH4) and nitrate (NO3) were measured in situ using a benthic lander. Fluxes of dissolved organic nitrogen (DON) and denitrification rates were calculated from pore water profiles of DON and NO3, respectively. Burial of nitrogen was calculated from down core profiles of nitrogen in the solid phase together with 14C-based sediment accumulation rates and dry bulk density. Average NH4 and NO3-effluxes were 7.4 ± 19 μmol m−2 d−1 (n = 7) and 52 ± 30 μmol m−2 d−1 (n = 14), respectively, during the period 1996–2000. During the same period, the DON-flux was 11 ± 5.6 μmol m−2 d−1 (n = 5) and the denitrification rate was 5.1 ± 3.0 μmol m−2 d−1 (n = 22). Temporal and spatial variations were only found in the benthic NO3 fluxes. The average burial rate was 4.6 ± 0.9 μmol m−2 d−1. On average over the sampling period, the recycling efficiency of the PON input to the sediment was 94% and the burial efficiency hence 6%. The DON flux constituted 14% of the nitrogen recycled, and it was of similar magnitude as the sum of burial and denitrification. By assuming the PAP is representative of all deep-sea areas, rates of denitrification, burial and DON efflux were extrapolated to the total area of the deep-sea floor (>2000 m) and integrated values of denitrification and burial of 8 ± 5 and 7 ± 1 Tg N year−1, respectively, were obtained. This value of total deep-sea sediment denitrification corresponds to 3–12% of the global ocean benthic denitrification. Burial in deep-sea sediments makes up at least 25% of the global ocean nitrogen burial. The integrated DON flux from the deep-sea floor is comparable in magnitude to a reported global riverine input of DON suggesting that deep-sea sediments constitute an important source of DON to the world ocean.  相似文献   
107.
The Stockholm archipelago spans roughly a semicircular area with a radius of approximately 60 km, traditionally partitioned into three parts: the inner, the middle and the outer archipelago. This subdivision coincides with differing water exchange regimes. The inner and middle archipelagos are characterised by comparatively larger basins which are interconnected by a limited number of straits. This configuration is well suited for a discrete basin (DB-) model approach by partitioning the area into a set of sub-basins that are only resolved vertically. The advantage of this approach over 3D-models is the possibility for enhanced vertical resolution and improved strait exchange formulation, outweighing the disadvantage of neglected horizontal gradients within the basins. In the inner archipelago the dominating exchange process is estuarine circulation, induced by the marked freshwater discharge and the vertical mixing. In the outer and middle archipelagos the density fluctuations due to Ekman pumping along the Baltic boundary interface produce another type of baroclinic process that clearly dominates. Measurements to adequately resolve these density variations do not exist. Missing forcing data are provided by linking the middle archipelago's boundary straits to a 3D-model of the Baltic with a grid resolution of 0.5 nautical miles (n.m.). This fine resolution model (FR-domain) is in turn driven by the atmospheric forcing and the density variation at the rectangular boundary of the FR-domain which acceptably resolves both the interfacial straits and the outer archipelago's complex hypsography. Massive computing resources would be demanded if the FR-domain were extended to comprise the entire Baltic. The FR-domain is thus interfaced with an existing coarse resolution model of the entire Baltic (CR-domain) with a grid size of 5 n.m., the open boundary of which is located in the Kattegat. This 3-fold model set-up has been run for one whole year (1992) with a one-year spin-up time to make up for the lack of initial data. The model concept is at this stage to be regarded as a framework for further development in anticipation of improved formulations, particularly for the strait exchange formulation. Therefore only primary validation experiments and a few sensitivity analyses have been performed.  相似文献   
108.
A TKE-dissipation model for the atmospheric boundary layer   总被引:1,自引:0,他引:1  
The dissipation, , of turbulent kinetic energy (TKE) is a key parameter in atmospheric boundary-layer (ABL) models. Besides being a sink for momentum, it is often used together with the TKE to define an internal turbulence time scale for closure relations. A prognostic formulation for the dissipation of TKE is formulated, based on isotropic tensor modeling methods. The formulation is coupled to a level 2.5 second-order closure model and evaluated against measurements taken in horizontally homogeneous conditions, as well as against a tailored length-scale formulation. A formulation suitable for convective as well as neutral and stable ABLs is suggested.On leave from Department of Meteorology, Uppsala University, P.O. Box 516, S-751 20 Uppsala, Sweden.The National Center for Atmospheric Research is sponsored by the National Science Foundation.  相似文献   
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110.
Leaf area index (LAI) and canopy coverage are important parameters when modelling snow process in coniferous forests, controlling interception and transmitting radiation. Estimates of LAI and sky view factor show large variability depending on the estimation method used, and it is not clear how this is reflected in the calculated snow processes beneath the canopy. In this study, the winter LAI and sky view fraction were estimated using different optical and biomass‐based approximations in several boreal coniferous forest stands in Fennoscandia with different stand density, age and site latitude. The biomass‐based estimate of LAI derived from forest inventory data was close to the values derived from the optical measurements at most sites, suggesting that forest inventory data can be used as input to snow hydrological modelling. Heterogeneity of tree species and site fertility, as well as edge effects between different forest compartments, caused differences in the LAI estimates at some sites. A snow energy and mass balance model (SNOWPACK) was applied to detect how the differences in the estimated values of the winter LAI and sky view fraction were reflected in simulated snow processes. In the simulations, an increase in LAI and a decrease in sky view fraction changed the snow surface energy balance by decreasing shortwave radiation input and increasing longwave radiation input. Changes in LAI and sky view fraction affected directly snow accumulation through altered throughfall fraction and indirectly snowmelt through the changed surface energy balance. Changes in LAI and sky view fraction had a greater impact on mean incoming radiation beneath the canopy than on other energy fluxes. Snowmelt was affected more than snow accumulation. The effect of canopy parameters on evaporation loss from intercepted snow was comparable with the effect of variation in governing meteorological variables such as precipitation intensity and air temperature. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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