Can we improve the spatial predictions of seabed sediments? A case study of spatial interpolation of mud content across the southwest Australian margin     

Jin Li  Andrew D. HeapAnna Potter  Zhi HuangJames J. Daniell 《Continental Shelf Research》2011,31(13):1365-1376

Spatially continuous data of environmental variables is often required for marine conservation and management. However, information for environmental variables is usually collected by point sampling, particularly for the marine region. Thus, methods generating such spatially continuous data by using point samples to estimate values for unknown locations become essential tools. Such methods are, however, often data- or even variable-specific and it is difficult to select an appropriate method for any given dataset. In this study, 14 methods (37 sub-methods) are compared using samples of mud content with five levels of sample density across the southwest Australian margin. Bathymetry, distance-to-coast, slope and geomorphic province were used as secondary variables. Ten-fold cross validation with relative mean absolute error (RMAE) and visual examination were used to assess the performance of these methods. A total of 1850 prediction datasets are produced and used to assess the performance of the methods and the effects of other factors considered. Considering both the accuracy and the visual examination, we found that a combined method (i.e., random forest and ordinary kriging: RKrf) is the most robust method. This method is novel, with a RMAE up to 17% less than that of the control. No threshold in sample density was detected in relation to prediction accuracy. No consistent patterns are observed between the performance of the methods and data variation. The RMAE of three most accurate methods is about 30% lower than that of the best methods in previous publications, highlighting the robustness of the methods selected in this study. The implications and limitations of this study are discussed and a number of suggestions are provided for further studies.  相似文献   

A multivariate study of Forbush decrease simultaneity     

O. Okike  A.B. Collier 《Journal of Atmospheric and Solar》2011,73(7-8):796-804

The distribution of the cosmic ray flux over the Earth is not uniform, but the result of complex phenomena within the Sun–Earth environment. A Forbush decrease (Fd) is a rapid decrease in the intensity of cosmic rays. A given Fd can appear in different forms at different locations of the Earth. An investigation of simultaneous observations of Fd events by a selection of cosmic ray stations remains a subject of interest among researchers and numerous methods of analysis can be found in literature. Although these studies have contributed significantly to our knowledge, the variability in the manifestations of Fds demonstrates that there are still open questions in this field. The present work suggests that multivariate analysis is a simple method that can be used to discriminate between globally simultaneous and non-simultaneous Fds.  相似文献   

The settling dynamics of flocculating mud-sand mixtures: Part 1��Empirical algorithm development     

Andrew James Manning  John V. Baugh  Jeremy R. Spearman  Emma L. Pidduck  Richard J. S. Whitehouse 《Ocean Dynamics》2011,61(2-3):311-350

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Epifaunal worm tubes on Lower Jurassic (Lower Lias) ammonites from Dorset     

Chris Andrew  Christopher R.C. Paul  Stephen K. Donovan 《Proceedings of the Geologists' Association. Geologists' Association》2011,122(1):34-46

Over 40 ammonites, mostly Promicroceras, with epifaunal worm tubes are described from the Lower Jurassic, Charmouth Mudstone Formation (Lias Group) of Dorset. Serpulids that were overgrown by the ammonites or responded to the ammonites’ growth attached to juvenile, living ammonites. Some epifaunal serpulids attached post-mortem, indicating oxygenated bottom water, which was rare in the lower Charmouth Mudstone Formation. Other serpulids do not conform to either pre- or post-mortem growth predictions and require individual assessment. The commonest pattern of growth for serpulids on live juvenile ammonites was attachment in the umbilical seam, with later growth onto, and finally around, the venter. Reconstructing this pattern shows that serpulids kept their aperture at 6 o’clock with respect to the orientation of the living ammonite (105-115° behind the ammonite aperture) throughout life. Reorientation of growth lines in serpulid worms just before the aperture suggests some worm tubes were fully grown. The 6 o’clock position of the aperture enabled feeding currents generated by the worms to parallel currents generated by swimming ammonites, thus maximizing food gathering and confirming that ammonites swam backwards. The mid-ventral position enabled the worm to deploy its branchia on both sides of the ammonite. Growth on ammonites was beneficial to the worms, but parasitic to the ammonites. Promicroceras with epifaunal worm tubes died at smaller sizes than unencumbered examples and size at death correlates inversely to extra weight of worm tubes. Uniformitarian comparisons suggest fossil serpulid worms grew in one season and that Promicroceras reached full size in two or three years.  相似文献   

Pleistocene recycling of copper at a porphyry system,Atacama Desert,Chile: Cu isotope evidence   总被引：2，自引：1，他引：1  

Carlos Palacios  Olivier Rouxel  Martin Reich  Eion M. Cameron  Matthew I. Leybourne 《Mineralium Deposita》2011,46(1):1-7

We present Cu isotope data of hypogene and supergene minerals from the Late Paleocene Spence Cu-Mo porphyry in the Atacama Desert of northern Chile. Chalcopyrite displays a restricted range of δ⁶⁵Cu values within the values reported for primary porphyry Cu sulfides (+ 0.28‰ to + 0.34‰, n = 6). Supergene chalcocite samples show heavier and remarkably homogeneous δ⁶⁵Cu values, between + 3.91‰ and + 3.95‰ (n = 6), consistent with previous models of Cu leaching and enrichment in porphyry systems. Secondary Cu minerals from the oxide zone show a wider range of composition, varying from + 1.28‰ and + 1.37‰ for chrysocolla (n = 6) to very light Cu isotope signatures reported for atacamite between -5.72‰ to -6.77‰ (n = 17). These data suggest redox cycling of Cu during supergene enrichment of the Spence Cu deposit, characterized by a first stage of supergene chalcocite formation from acidic, isotopically-heavy leach fluids of meteoric origin down-flowing in a semi-arid climate (44 to ~ 15-9 Ma). Reworking of the initial supergene copper assemblage, during the Pleistocene, by rising neutral and chlorine-rich deep formation waters under well-established hyper-arid climate conditions lead to the formation of atacamite with extremely fractionated Cu compositions. Essentially coeval chrysocolla formed by dissolution of atacamite during short episodes of wetter climatic conditions occurring in the latest Pleistocene.  相似文献   

Mercury in the Southern Ocean     

Daniel Cossa  Lars-Eric Heimbürger  Stephen R. Rintoul  Edward C.V. Butler  Andrew R. Bowie  Roslyn J. Watson 《Geochimica et cosmochimica acta》2011,75(14):4037-4052

We present here the first mercury speciation study in the water column of the Southern Ocean, using a high-resolution south-to-north section (27 stations from 65.50°S to 44.00°S) with up to 15 depths (0-4440 m) between Antarctica and Tasmania (Australia) along the 140°E meridian. In addition, in order to explore the role of sea ice in Hg cycling, a study of mercury speciation in the “snow-sea ice-seawater” continuum was conducted at a coastal site, near the Australian Casey station (66.40°S; 101.14°E). In the open ocean waters, total Hg (Hg_T) concentrations varied from 0.63 to 2.76 pmol L⁻¹ with “transient-type” vertical profiles and a latitudinal distribution suggesting an atmospheric mercury source south of the Southern Polar Front (SPF) and a surface removal north of the Subantartic Front (SAF). Slightly higher mean Hg_T concentrations (1.35 ± 0.39 pmol L⁻¹) were measured in Antarctic Bottom Water (AABW) compared to Antarctic Intermediate water (AAIW) (1.15 ± 0.22 pmol L⁻¹). Labile Hg (Hg_R) concentrations varied from 0.01 to 2.28 pmol L⁻¹, with a distribution showing that the Hg_T enrichment south of the SPF consisted mainly of Hg_R (67 ± 23%), whereas, in contrast, the percentage was half that in surface waters north of PFZ (33 ± 23%). Methylated mercury species (MeHg_T) concentrations ranged from 0.02 to 0.86 pmol L⁻¹. All vertical MeHg_T profiles exhibited roughly the same pattern, with low concentrations observed in the surface layer and increasing concentrations with depth up to an intermediate depth maximum. As for Hg_T, low mean MeHg_T concentrations were associated with AAIW, and higher ones with AABW. The maximum of MeHg_T concentration at each station was systematically observed within the oxygen minimum zone, with a statistically significant MeHg_Tvs Apparent Oxygen Utilization (AOU) relationship (p < 0.001). The proportion of Hg_T as methylated species was lower than 5% in the surface waters, around 50% in deep waters below 1000 m, reaching a maximum of 78% south of the SPF. At Casey coastal station Hg_T and Hg_R concentrations found in the “snow-sea ice-seawater” continuum were one order of magnitude higher than those measured in open ocean waters. The distribution of Hg_T there suggests an atmospheric Hg deposition with snow and a fractionation process during sea ice formation, which excludes Hg from the ice with a parallel Hg enrichment of brine, probably concurring with the Hg enrichment of AABW observed in the open ocean waters. Contrastingly, MeHg_T concentrations in the sea ice environment were in the same range as in the open ocean waters, remaining below 0.45 pmol L⁻¹. The MeHg_T vertical profile through the continuum suggests different sources, including atmosphere, seawater and methylation in basal ice. Whereas Hg_T concentrations in the water samples collected between the Antarctic continent and Tasmania are comparable to recent measurements made in the other parts of the World Ocean (e.g., Soerensen et al., 2010), the Hg species distribution suggests distinct features in the Southern Ocean Hg cycle: (i) a net atmospheric Hg deposition on surface water near the ice edge, (ii) the Hg enrichment in brine during sea ice formation, and (iii) a net methylation of Hg south of the SPF.  相似文献   

Is the Palea Kavala Bi–Te–Pb–Sb ± Au district, northeastern Greece, an intrusion-related system?     

Andrew P. Fornadel  Paul G. Spry  Vasilios Melfos  Michael Vavelidis  Panagiotis Ch. Voudouris 《Ore Geology Reviews》2011,39(3):119-133

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Preface: Insights from environmental tracers in groundwater systems   总被引：2，自引：2，他引：0  

Ward E. Sanford  Werner Aeschbach-Hertig  Andrew L. Herczeg 《Hydrogeology Journal》2011,19(1):1-3

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Impacts of the ‘<Emphasis Type="Italic">Pacific Adventurer</Emphasis>’ Oil Spill on the Macrobenthos of Subtropical Sandy Beaches     

Thomas Alfred Schlacher  Andrew Holzheimer  Tim Stevens  David Rissik 《Estuaries and Coasts》2011,34(5):937-949

Biological impacts of oil on sandy shore ecosystems remain incompletely understood, especially following smaller spills on subtropical beaches. Here we quantified changes to benthic assemblages on a sandy beach following the 270-t spill of heavy fuel oil from the Pacific Adventurer that occurred in March 2009 off Moreton Island in Eastern Australia. Assessments of ecological impacts are based on spatial contrasts between multiple reference and impact sites sampled 1 week and 3 months after the spill. Benthic invertebrate assemblages exposed to oil had significantly fewer individuals of fewer species 1 week after the spill, markedly changing their ecological structure. Biological differences consistent with oil-related mortality were significant on the lower shore and in the swash and remained so 3 months after the spill. This signals a lack of recovery of these communities in the short term, despite the fairly rapid removal of oil. Results show that, despite the relatively small size of the spill, heavy fuel oil contamination can cause substantial impacts on sandy beach ecosystems, and that recovery may be prolonged.  相似文献   

Identification of alluvial fans susceptible to debris-flow hazards   总被引：3，自引：1，他引：2  

Andrew Welsh  Tim Davies 《Landslides》2011,8(2):183-194

We describe and test a method for identifying alluvial fans likely to be affected by debris flows. It is based on identifying catchment parameters by geographical information system interrogation of a digital elevation model, using the Melton ratio as the discriminating parameter. The method was calibrated using data from debris-flow-generating catchments in Coromandel and the adjacent Kaimai Ranges, North Island, NZ, and tested against data from the rest of New Zealand. The procedure is remarkably (but not completely) reliable for identifying debris-flow-capable catchments, and thus fans, across the wide range of climates and lithologies in New Zealand mountains. A case study illustrates the potential of the method for avoiding future hazards and emphasises the need for a precautionary approach when field investigations do not detect evidence for past debris flows.  相似文献