Nephelines from the Somma-Vesuvius volcanic complex (Southern Italy): crystal-chemical,structural and genetic investigations     

Giuseppina Balassone  Volker Kahlenberg  Angela Altomare  Angela Mormone  Rosanna Rizzi  Michele Saviano  Nicola Mondillo 《Mineralogy and Petrology》2014,108(1):71-90

Sixteen nephelines from different geological occurrences were sampled at the type-locality, the Somma-Vesuvius volcanic complex (southern Italy), and investigated for their chemistry and crystal structure obtained by both single-crystal and powder X-ray diffraction. Nepheline-bearing samples are metamorphic or from magmatic ejecta and pumice deposits. The lower K contents characterize the pumice- and some metamorphic-derived nephelines, whereas the higher ones are found in some samples from magmatic nodules. The amount of the anorthite molecule, quite low on average, can be more variable in the metamorphic nephelines. The crystal-structure investigations on Somma-Vesuvius samples compare well with previous studies of natural nephelines. All 16 nepheline samples adopt space group P6₃. The observed lattice parameters vary between 9.9768–9.9946 Å (for a) and 8.3614–8.3777 Å (for c), respectively. Furthermore, chemical analysis revealed that all specimens exhibit an excess of Si relative the ideal Si:Al ratio of 1:1. The analysis of the T-O distances in our samples clearly indicates a distinct ordering process of aluminium and silicon on the tetrahedral sites which is an agreement with Loewenstein’s rule. A linear correlation between the distance of symmetry equivalent split atoms O(1)-O(1)’ and the T(1)-O(1)-T(2) tilt angle was observed. The average <B-O> (B = Na) distances of all crystals are very similar which is consistent with the outcome of the site population refinement indicating full occupancy with sodium. Oriented precession-type sections of reciprocal space indicated the presence of at least the most intense family of satellite peaks, demonstrating that this group of satellite reflections can occur not only in nephelines from pegmatites and ijolites but also in rocks from completely different petrological settings.  相似文献   

A depositional model for offshore deposits of the lower Blue Gate Member,Mancos Shale,Uinta Basin,Utah, USA          下载免费PDF全文

Lauren P. Birgenheier  Brendan Horton  Andrew D. McCauley  Cari L. Johnson  Angela Kennedy 《Sedimentology》2017,64(5):1402-1438

Depositional models that use heterogeneity in mud‐dominated successions to distinguish and diagnose environments within the offshore realm are still in their infancy, despite significant recent advances in understanding the complex and dynamic processes of mud deposition. Six cored intervals of the main body of the Mancos Shale, the lower Blue Gate Member, Uinta Basin, were examined sedimentologically, stratigraphically and geochemically in order to evaluate facies heterogeneity and depositional mechanisms. Unique sedimentological and geochemical features are used to identify three offshore environments of deposition: the prodelta, the mudbelt and the sediment‐starved shelf. Prodelta deposits consist of interlaminated siltstone and sandstone and exhibit variable and stressed trace fossil assemblages, and indicators of high sedimentation rates. The prodelta was dominated by river‐fed hyperpycnal flow. Mudbelt deposits consist of interlaminated siltstone and sandstone and are characterized by higher bioturbation indices and more diverse trace fossil assemblages. Ripples, scours, truncations and normally graded laminations are abundant in prodelta and mudbelt deposits indicating dynamic current conditions. Mudbelt sediment dispersal was achieved by both combined flow above storm wave base and current‐enhanced and wave‐enhanced sediment gravity flows below storm wave base. Sediment‐starved shelf deposits are dominantly siltstone to claystone with the highest calcite and organic content. Bioturbation is limited to absent. Sediment‐starved shelf deposits were the result of a combination of shelfal currents and hypopycnal settling of sediment. Despite representing the smallest volume, sediment‐starved shelf deposits are the most prospective for shale hydrocarbon resource development, due to elevated organic and carbonate content. Sediment‐starved shelf deposits are found in either retrogradational to aggradational parasequence sets or early distal aggradational to progradational parasequence sets, bounding the maximum flooding surface. An improved framework classification of offshore mudstone depositional processes based on diagnostic sedimentary criteria advances our predictive ability in complex and dynamic mud‐dominated environments and informs resource prospectivity.  相似文献   

Chadian faunas and flora from dyserth: Depositional environments and palaeogeographic setting of Viséan strata in northeast wales     

Ian D. Somerville  Angela R. E. Strank  Anthony Welsh 《Geological Journal》1989,24(1):49-66

New floral and faunal data from the oldest Dinantian limestones (Foel Formation) in the Dyserth area, suggest that these sediments are of Chadian age, rather than the Asbian age concluded by earlier workers. The basal late Chadian limestones rest conformably on Dinantian Basement Beds of ?Chadian age or older. The initial inundation of St. George's Land occurred during Chadian times, when shallow-water marine limestones accumulated in the Dyserth area and further to the south, together with terrestrially derived siliciclastics, containing drifted plant fragments. Periodically, a restricted hypersaline lagoonal environment was established but an open marine, neritic environment with abundant stenohaline fauna prevailed in this area. These Chadian sediments accumulated on the proximal part of a carbonate ramp and are presumed to have passed laterally downslope into deeper water basinal facies with Waulsortian buildups of the Irish Sea Basin. In the later Arundian, a carbonate ramp–to–platform transition occurred, with widespread deposition of shallow-water carbonates. In the Asbian this platform developed a rimmed margin, with buildups forming a linear belt between platform and basin. An almost complete Chadian to Brigantian Lower Carboniferous sequence can now be recognized in North Wales. This succession is comparable with the shelf succession in south Cumbria on the northern margin of the Irish Sea Basin.  相似文献