9000 years of changes in peat organic matter composition in Store Mosse (Sweden) traced using FTIR-ATR     

Antonio Martínez Cortizas  Jenny K. Sjöström  Eleonor E. Ryberg  Malin E. Kylander  Joeri Kaal  Olalla López-Costas  Noemi Álvarez Fernández  Richard Bindler 《Boreas: An International Journal of Quaternary Research》2021,50(4):1161-1178

Store Mosse (the ‘Great Bog’ in Swedish) is one of the most extensive bog complexes in southern Sweden (~77 km²), where pioneering palaeoenvironmental research has been carried out since the early 20th century. This includes, for example, vegetation changes, carbon and nitrogen dynamics, peat decomposition, atmospheric metal pollution, mineral dust deposition, dendrochronology, and tephrochronology. Even though organic matter (OM) represents the bulk of the peat mass and its compositional change has the potential to provide crucial ecological information on bog responses to environmental factors, peat OM molecular composition has not been addressed in detail. Here, a 568-cm-deep peat sequence was studied at high resolution, by attenuated reflectance Fourier-transform infrared spectroscopy (FTIR-ATR) in the mid-infrared region (4000–400 cm^–1). Principal components analysis was performed on selected absorbances and change-point modelling was applied to the records to determine the timing of changes. Four components accounted for peat composition: (i) depletion/accumulation of labile (i.e. carbohydrates) and recalcitrant (i.e. lignin and other aromatics, aliphatics, organic acids and some N compounds) compounds, due to peat decomposition; (ii) variations in N compounds and carbohydrates; (iii) residual variation of lignin and organic acids; and (iv) residual variation of aliphatic structures. Peat decomposition showed two main patterns: a long-term trend highly correlated to peat age (r = 0.87), and a short-term trend, which showed five main phases of increased decomposition (at ~8.4–8.1, ~7.0–5.6, ~3.5–3.1, ~2.7–2.1 and ~1.6–1.3 ka) – mostly corresponding to drier climate and its effect on bog hydrology. The high peat accumulation event (~5.6–3.9 ka), described in earlier studies, is characterized by the lowest degree of peat decomposition of the whole record. Given that FTIR-ATR is a quick, non-destructive, cost-effective technique, our results indicate that it can be applied in a systematic way (including multicore studies) to peat research and provide relevant information on the evolution of peatlands.  相似文献   

The Colider and Roosevelt Volcanic rocks (sw amazonian craton): geochemistry and sm-nd isotope characteristics of a silicic large igneous province     

Saar de Almeida  Bruna  Geraldes  Mauro César  Sommer  Carlos Augusto  Corrales  Felipe  de Barros  Antonio João Paes 《中国地球化学学报》2021,40(6):1023-1049

The volcanic rocks of the Colíder and Roosevelt formations are extensively exposed in the south-central portion of the Amazonian Craton where effusive and pyroclastic rocks have been mapped. Both units, topped by chemical sediments and oceanic facies as rhyolite and andesite lavas, rhyodacite, and porphyritic dacite, with frequent intercalations of pyroclastic and epiclastic deposits. Whole-rock geochemistry for 55 samples of rhyolitic to andesitic composition suggests the involvement of fertile mantle-derived components with E-MORB to OIB compositions. The analyzed rocks display calc-alkaline to shoshonitic affinity consistent with generation related to an active continental margin. The whole-rock Sm-Nd isotope data from selected felsic volcanic rocks of the Colíder and Roosevelt formations yield negative initial ε_Nd values between –3 and –9, indicating the predominantly crustal nature of the parental magmas with early Archean to late Paleoproterozoic (ca. 2.5–2.0 Ga) depleted mantle model ages.

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Transfer of fishing effort between areas and fishery units in Spanish fisheries as side effects of the prestige oil spill management measures     

Esther Abad  Jose M. Bellido  Antonio Punzón 《Ocean & Coastal Management》2010,53(3):107-113

This paper shows how post-oil spill management measures can affect the general pattern of fishing effort exerted on two particular species of great commercial value in northern Spanish fisheries: anglerfish (Lophius piscatorius and Lophius budegassa) and mackerel (Scomber scombrus). Data time series of catches and fishing efforts were analysed corresponding to the area and time period affected by the oil spill fishing restrictions (December 2002–June 2003) and similar previous and post-spill periods. This was done to detect shifts that could be due to either the oil spill per se or the management measures taken to minimise pollution effects. Then, analyses and simulations with Arcview GIS module FAST (Fishing Activity Simulation Tool v. 1.1) were carried out with the aim of studying the fishing effort spatial distribution. Changes were observed in the Catch Per Unit Effort (CPUE) of anglerfish and mackerel by area or fishery unit. Results show a spatial displacement of fishing effort to other fishing areas in the case of anglerfish, and the transfer of fishing effort between different fishery units in the case of mackerel. Although both effects were caused primarily by the management measures in force after the oil spill, they are considered side or collateral effects. The management measures that have to be taken after any disaster should also consider these kinds of ancillary effects as well as evaluating the likely positive or negative impact of these side effects.  相似文献   

Preface—Dedication to Keith Bell     

Antonio Simonetti 《Mineralogy and Petrology》2010,98(1-4):1-3

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Re‐establishment of soil water repellency after destruction by intense burning in a Mediterranean heathland (SW Spain)     

Antonio Jordán  Félix A. González  Lorena M. Zavala 《水文研究》2010,24(6):736-748

Soil water repellency has been conventionally considered as a fire‐induced effect, but an increasing number of studies have suggested that natural background repellency occurs in many soil types, and many of them have suggested that water repellency can be re‐established over time after being destroyed. An experimental fire was conducted to study changes of the soil surface during the first 18 months following intense burning. The main objectives of this paper are as follows: (1) to investigate in situ water repellency changes at three soil depths (0, 2 and 4 cm) immediately after burning; (2) to evaluate the medium‐term evolution of water repellency under field conditions; and (3) to outline the main hydrological consequences of these changes. Also, different water repellency tests (water drop penetration time, ethanol percentage test (EPT) and contact angle (CA) between water drops and the soil surface) were carried out for comparison purposes. Field experiments showed that soil water repellency was partly destroyed after intense burning. Changes were relatively strong at the soil surface, but diminished progressively with depth. Levels of water repellency were practically re‐established 18 months after burning. This suggests that water repellency in the studied area is not necessarily a consequence of fire, but can instead be a natural attribute. Finally, although limited in time, destruction of soil water repellency has important consequences for runoff flow generation and soil loss rates, and, indirectly, for water quality. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Quantum mechanical potential surfaces and calculations on minerals and molecular clusters     

Antonio C. Lasaga  G. V. Gibbs 《Physics and Chemistry of Minerals》1988,16(1):29-41

Recently, ab-initio quantum mechanical potential surfaces calculated for silicate hydroxyacid molecules were used to extract covalent potentials for use in mineral physics calculations (Lasaga and Gibbs 1987). The calculations showed that these potentials are capable of generating the structure and physical properties of silicate minerals. In this paper we explore in more detail the suitability of various covalent potentials in mimicking the topography of the ab-initio potential surfaces. We also extend the use of such quantum-derived potentials in generating the structures of hydroxyacid dimers, trimers, and pentamers of silicate tetrahedra and in studying the structure and the dynamical properties of minerals and glasses.  相似文献   

The objective determination of the instantaneous predominant frequency of seismic signals and inferences onQ of coda waves     

Antonio Rovelli  Sandro Marcucci  Giuliano Milana 《Pure and Applied Geophysics》1988,128(1-2):281-293

A technique to detect spectrum variations versus time along seismic signals is applied to coda waves of local earthquakes (Friuli, Northern Italy). The technique consists of an autoregressive modeling and utilizes nonlinear spectral analysis where the spectrum of stochastic processes is estimated as the transfer function of the filter that whitens the process under analysis. This approach appears to be particularly well suited to those investigations where automatic measurements of the instantaneous frequency have to be carried out on digital data. The detection of variations of the instantaneous frequency along the coda allows computation of seismic-Q in the lithosphere and its frequency dependence: the result obtained is $$Q = 100f^{0.4} $$ which appears to be strongly consistent with that, based on the estimate of the coda amplitude decay in the band including the most significant frequencies of the signals under analysis.  相似文献   

Geobal post-seismic deformation     

Antonio Piersanti  Giorgio Spada  Roberto Sabadini  Maurizio Bonafede 《Geophysical Journal International》1995,120(3):544-566

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Association of subsurface radon changes in Alaska and the northeastern United States with earthquakes     

Robert L. Fleischer  Antonio Mogro-Campero 《Geochimica et cosmochimica acta》1985,49(4):1061-1071

Changes of radon concentration in the ground have been reported to correlate with seismic activity in many places over widely varying distances from the earthquake epicenters, sometimes over 100's and occasionally over 1000's of km depending on the magnitude M of the earthquakes. For proper use of such correlations in forecasting the location and size of impending earthquakes, it would be useful to establish a relation between M and the maximum distance x_M at which radon can be significantly altered by preseismic effects.We have monitored radon in the ground continuously at Blue Mountain Lake, NY starting Dec. 3. 1975 and at three locations in Alaska—Icy Bay, Yakataga, and Sand Point (starting Nov. 12, 1979; March 5, 1980; and June 29, 1980 respectively). Sample correlations from visual examination of the recent radon record and tentative use of a proposed scaling relation show a number of possible earthquake-related signals at these locations. The data are compatible with scaling relations that were derived from two separate models of premonitory elastic strains. In this work x_M = 10^0.48M, where x_M is in units of km and M ≥ 3. Since tilt and strain signals correlate similarly with magnitude and distance, it is likely that most earthquake-related radon signals are mechanically induced.  相似文献   

Seismic Q for the lithosphere of the Montenegro region (Yugoslavia): frequency,depth and time windowing effects     

Antonio Rovelli 《Physics of the Earth and Planetary Interiors》1984,34(3):159-172

The availability of accelerometric data for the Montenegro earthquake of 15th April 1979 makes it possible to investigate seismic Q of the lithosphere in that region, in particular, its dependence on frequency, on the depth reached by seismic waves, and on the length of time windows in which signals are processed. Two different spectral methods, S phase energy ratio and coda envelope decay, are applied, respectively, to direct and scattered shear waves. Similar results are obtained using different portions of the recordings, i.e., coda waves for the envelope decay fit and the S wave train, with a significant duration of ～ 10 s, for the energy ratios. The same apparent Q (Q ～ 40 f, where f is the frequency expressed in Hz) that is found for other neighbouring central Mediterranean regions (e.g., Ancona, on the central Italian Adriatic coast; Valnerina, in the central Apennines; Irpinia, in the southern Apennines) is also found for the southern Yugoslavian coast, in the band 1–25 Hz up to a maximum range of ～ 120 km from the focus. This strong frequency dependence is probably connected with the type of small-scale heterogeneity and the same geological age and level of tectonic activity peculiar to all these seismotectonic areas.In order to compare the apparent Q of the whole S wave train, ～ 10 s long, with the (intrinsic) apparent Q of the single direct S wave (usually 1 s or less), the maximum entropy method is applied in the energy spectrum computation for shorter wave trains. The use of shorter time windows does not reveal any significant variation in the tendency of Q to increase linearly with frequency as the length of the time window containing the sample of the S waves decreases. This seems to indicate that scattering-dependent Q is generally inseparable from intrinsic Q in the lithosphere when estimates based on variations with distance of the seismic signal spectrum are used. While the type of linear growth with frequency does not seem to undergo any variations (it remains of the Q = qf type), the data show there are a considerable decrease in the coefficient of proportionality Q with decreasing duration of the window of S waves analysed, probably as a result of variations in seismic attenuation with depth.  相似文献