Diffusion of uranium in compacted sodium bentonite     

Arto Muurinen 《Engineering Geology》1990,28(3-4):359-367

Sorption and diffusion of uranium in sodium bentonite MX-80 were measured in aerobic conditions. The batch method was used for the sorption measurements and the steady state method for the diffusion measurements. Clear sorption was noticed only when high uranium concentrations were used so that the pH of the solution decreased.

The diffusivities of uranium were strongly dependent on the compaction of bentonite so that in the highly compacted samples the diffusion was very restricted. Uranium shows both features of ion-exclusion and sorption. Further studies are, however, needed to explain the diffusion mechanisms of uranium.  相似文献   

Palaeoenvironment of the Karelian Isthmus, the easternmost part of the Gulf of Finland, during the Litorina Sea stage of the Baltic Sea history     

Arto Miettinen  Larissa Savelieva  Dmitry A. Subetto  Rimma Dzhinoridze  Khikmat Arslanov  Hannu Hyv&#;rinen 《Boreas: An International Journal of Quaternary Research》2007,36(4):441-458

The palaeoenvironment of the Karelian Isthmus area during the Litorina Sea stage of the Baltic Sea history, between 8.0 and 4.5 kyr BP (8.8-5.2 cal. kyr BP), was reconstructed by studying four sites located on the Karelian Isthmus in Russia. Methods included diatom and pollen analyses, sediment lithostratigraphical interpretation and ¹⁴C dating. The brackish-water (Litorina) transgression began c. 7.7 kyr BP (8.45 cal. kyr BP) in the Karelian Isthmus area. The transgression maximum occurred between 6.7 and 5.7 kyr BP (7.6-6.5 cal. kyr BP), depending on the glacio-isostatic land uplift rate. Regarding the vegetation, the maximum occurrence of temperate deciduous trees took place at the same time. The transgression was interrupted by a short-lived sea-level standstill during the middle phase of the main transgression, c. 6.3 kyr BP (7.2 cal. kyr BP), on the eastern part of the isthmus. The highest Litorina shoreline is located between 8 and 13 m above present sea-level and the amplitude of the Litorina transgression has varied between 5 and 7 m. The 8.2-kyr cold event is not evident, but the sea-level standstill around 6.3 kyr BP (7.2 cal. kyr BP) could reflect a cool episode at that time in the Karelian Isthmus area.  相似文献   

Chemical and genetic characterization of the ungrouped pallasite Lieksa     

Emily M. Chiappe  Richard D. Ash  Arto Luttinen  Sari Lukkari  Jukka Kuva  Connor D. Hilton  Richard J. Walker 《Meteoritics & planetary science》2023,58(12):1747-1759

The meteorite Lieksa was found in 2017 in Löpönvaara, Finland, and later donated to the Finnish Museum of Natural History. Here, we report siderophile element concentrations, genetic isotopic data, and a metal–silicate segregation age for the meteorite. The ~280 g Lieksa is ~80% metal and ~20% silicate and oxide inclusions by volume, with the inclusions consisting primarily of Fe-rich olivine. Due to Lieksa's silicate content, coupled with a texture characterized by metal enclosing the silicates, it has been classified as a pallasite. Lieksa's olivine and bulk chemical characteristics are distinct from those of the known pallasite and iron meteorite groups, consistent with its classification as ungrouped. The meteorite exhibits a flat, chondrite-normalized highly siderophile element pattern, consistent with an origin as an early crystallization product from a metallic melt with chondritic relative abundances. Molybdenum, Ru, and ¹⁸³W isotopic data indicate that Lieksa formed in the non-carbonaceous (NC) domain of the solar nebula. Radiogenic ¹⁸²W abundances for Lieksa yield a model metal–silicate segregation age of 1.5 ± 0.8 Myr after calcium-aluminum-rich inclusion formation, which is within the range established for other NC-type pallasite and iron meteorite parent bodies.  相似文献