Localized shock-induced melting of sandstone at low shock pressures (<17.5 GPa): An experimental study          下载免费PDF全文

Matthias Ebert  Astrid Kowitz  Ralf Thomas Schmitt  Wolf Uwe Reimold  Ulrich Mansfeld  Falko Langenhorst 《Meteoritics & planetary science》2018,53(8):1633-1643

Shock-induced recovery experiments were performed to investigate melt formation in porous sandstones in the low shock pressure regime between 2.5 and 17.5 GPa. The sandstone shocked at 2.5 and 5 GPa is characterized by pore closure, fracturing of quartz (Qtz), and compression and deformation of phyllosilicates; no melting was observed. At higher pressures, five different types of melts were generated around pores and alongside fractures in the sandstone. Melting of kaolinite (Kln), illite (Ill), and muscovite (Ms) starts at 7.5, 12, and 15 GPa, respectively. The larger the amount of water in these minerals (Kln ~14 wt%, Ill ~6–10 wt%, and Ms ~4 wt% H₂O), the higher the shock compressibility and the lower the shock pressure required to induce melting. Vesicles in the almost dry silicate glasses attest to the loss of structural water during the short shock duration of the experiment. The compositions of the phyllosilicate-based glasses are identical to the composition of the parental minerals or their mixtures. Thus, this study has demonstrated that phyllosilicates in shocked sandstone undergo congruent melting during shock loading. In experiments at 10 GPa and higher, iron melt from the driver plate was injected into the phyllosilicate melts. During this process, Fe is partitioned from the metal droplets into the surrounding silicate melts, which induced unmixing of silicate melts with different chemical properties (liquid immiscibility). At pressures between 7.5 and 15 GPa, a pure SiO₂ glass was formed, which is located as short and thin bands within Qtz grains. These bands were shown to contain tiny crystals of experimentally generated stishovite.  相似文献   

The natural latitudinal distribution of atmospheric CO₂     

John A. Taylor  James C. Orr 《Global and Planetary Change》2000,26(4)

Although poorly understood, the north–south distribution of the natural component of atmospheric CO₂ offers information essential to improving our understanding of the exchange of CO₂ between the atmosphere, oceans, and biosphere. The natural or unperturbed component is equivalent to that part of the atmospheric CO₂ distribution which is controlled by non-anthropogenic CO₂ fluxes from the ocean and terrestrial biosphere. Models should be able to reproduce the true north–south gradient in CO₂ due to the natural component before they can reliably estimate present-day CO₂ sources and sinks and predict future atmospheric CO₂. We have estimated the natural latitudinal distribution of atmospheric CO₂, relative to the South Pole, using measurements of atmospheric CO₂ during 1959–1991 and corresponding estimates of anthropogenic CO₂ emissions to the atmosphere. Key features of the natural latitudinal distribution include: (1) CO₂ concentrations in the northern hemisphere that are lower than those in the southern hemisphere; (2) CO₂ concentration differences that are higher in the tropics (associated with outgassing of the oceans) than those currently measured; and (3) CO₂ concentrations over the southern ocean that are relatively uniform. This natural latitudinal distribution and its sensitivity to increasing fossil fuel emissions both indicate that near-surface concentrations of atmospheric CO₂ in the northern hemisphere are naturally lower than those in the southern hemisphere. Models that find the contrary will also mismatch present-day CO₂ in the northern hemisphere and incorrectly ascribe that region as a large sink of anthropogenic CO₂.  相似文献   

The morphodynamics of fluvial sand dunes in the River Rhine, near Mainz, Germany. I. Sedimentology and morphology   总被引：2，自引：0，他引：2  

Carling  Gölz  Orr  & Radecki-Pawlik 《Sedimentology》2000,47(1):227-252

The dynamics of large isolated sand dunes moving across a gravel lag layer were studied in a supply‐limited reach of the River Rhine, Germany. Bed sediments, dune geometry, bedform migration rates and the internal structure of dunes are considered in this paper. Hydrodynamic and sediment transport data are considered in a companion paper. The pebbles and cobbles (D₅₀ of 10 mm) of the flat lag layer are rarely entrained. Dunes consist of well‐sorted medium to coarse sand (D₅₀ of 0·9 mm). Small pebbles move over the dunes by ‘overpassing’, but there is a degree of size and shape selectivity. Populations of ripples in sand (D₅₀ < 0·6 mm), and small and large dunes are separated by distinct breaks in the bedform length data in the regions of 0·7–1 m and 5–10 m. Ripples and small dunes may have sinuous crestlines but primarily exhibit two‐dimensional planforms. In contrast, large dunes are primarily three‐dimensional barchanoid forms. Ripples on the backs of small dunes rarely develop to maximum steepness. Small dunes may achieve an equilibrium geometry, either on the gravel bed or as secondary dunes within the boundary layer on the stoss side of large dunes. Secondary dunes frequently develop a humpback profile as they migrate across the upper stoss slope of large dunes, diminishing in height but increasing in length as they traverse the crestal region. However, secondary dunes more than 5 m in length are rare. The dearth of equilibrium ripples and long secondary dunes is probably related to the limited excursion length available for bedform development on the parent bedforms. Large dunes with lengths between 20 m and 100 m do not approach an equilibrium geometry. A depth limitation rather than a sediment supply limitation is the primary control on dune height; dunes rarely exceed 1 m high in water depths of ≈4 m. Dune celerity increases as a function of the mean flow velocity squared, but this general relationship obscures more subtle morphodynamics. During rising river stage, dunes tend to grow in height owing to crestal accumulation, which slows downstream progression and steepens the dune form. During steady or falling stage, an extended crestal platform develops in association with a rapid downstream migration of the lee side and a reduction in dune height. These diminishing dunes actually increase in unit volume by a process of increased leeside accumulation fed by secondary dunes moving past a stalled stoss toe. A six‐stage model of dune growth and diminution is proposed to explain variations in observed morphology. The model demonstrates how the development of an internal boundary layer and the interaction of the water surface with the crests of these bedload‐dominated dunes can result in dunes characterized by gentle lee sides with weak flow separation. This finding is significant, as other studies of dunes in large rivers have attributed this morphological response to a predominance of suspended load transport.  相似文献   

Microscopic evidence of stishovite generated in low‐pressure shock experiments on porous sandstone: Constraints on its genesis          下载免费PDF全文

Ulrich Mansfeld  Falko Langenhorst  Matthias Ebert  Astrid Kowitz  Ralf Thomas Schmitt 《Meteoritics & planetary science》2017,52(7):1449-1464

It has been almost exactly half a century since the first synthesis of stishovite in shock experiments on quartz was reported, but its formation conditions during shock is still under debate. Here, we present direct transmission electron microscopic observation of stishovite within material recovered from high‐explosive shock experiments on porous sandstone shocked at 7.5 and 12.5 GPa. Our observations allow for new conclusions on the genesis of stishovite in a close‐to‐nature environment. The formation of stishovite in short‐time shock experiments proves that its crystallization is ultrafast (<1 μs). Crystals were found only embedded in amorphous veins indicating homogeneous nucleation. Crystallization from melt rather than from glass can be concluded from the observation of roundish, defect‐free crystals up to 150 nm in diameter embedded in nondensified glass. The formation of stishovite at 7.5 GPa is in accordance with the phase diagram of silica, if rapid undercooling is present that becomes only possible by the existence of small hot spots in an otherwise cold material, which is supported by transient heat calculation. The absence of coesite at 7.5 GPa suggests kinetic hindrance of its crystallization from melt and, thus, smaller critical cooling rates compared to stishovite where critical cooling rates are estimated to be as large as 10¹¹ K s^?1. While the amorphous veins containing stishovite represent unambiguously hot spots, no associated pressure amplification could be verified within these veins. The rapid liquidus crystallization of stishovite only in hot spots generated in porous material is an alternative formation mechanism to the widely accepted theory of solid–solid transition from quartz to stishovite and might represent the more general mechanism occurring in nature for low shock pressure events.  相似文献   

Knowledge-based systems as decision support tools in an ecosystem approach to fisheries: Comparing a fuzzy-logic and a rule-based approach   总被引：1，自引：0，他引：1  

Astrid Jarre  Barbara Paterson  Coleen L. Moloney  David C.M. Miller  John G. Field  Anthony M. Starfield 《Progress in Oceanography》2008,79(2-4):390

In an ecosystem approach to fisheries (EAF), management must draw on information of widely different types, and information addressing various scales. Knowledge-based systems assist in the decision-making process by summarising this information in a logical, transparent and reproducible way. Both rule-based Boolean and fuzzy-logic models have been used successfully as knowledge-based decision support tools. This study compares two such systems relevant to fisheries management in an EAF developed for the southern Benguela. The first is a rule-based system for the prediction of anchovy recruitment and the second is a fuzzy-logic tool to monitor implementation of an EAF in the sardine fishery. We construct a fuzzy-logic counterpart to the rule-based model, and a rule-based counterpart to the fuzzy-logic model, compare their results, and include feedback from potential users of these two decision support tools in our evaluation of the two approaches. With respect to the model objectives, no method clearly outperformed the other. The advantages of numerically processing continuous variables, and interpreting the final output, as in fuzzy-logic models, can be weighed up against the advantages of using a few, qualitative, easy-to-understand categories as in rule-based models. The natural language used in rule-based implementations is easily understood by, and communicated among, users of these systems. Users unfamiliar with fuzzy-set theory must “trust” the logic of the model. Graphical visualization of intermediate and end results is an important advantage of any system. Applying the two approaches in parallel improved our understanding of the model as well as of the underlying problems. Even for complex problems, small knowledge-based systems such as the ones explored here are worth developing and using. Their strengths lie in (i) synthesis of the problem in a logical and transparent framework, (ii) helping scientists to deliberate how to apply their science to transdisciplinary issues that are not purely scientific, and (iii) representing vehicles for delivering state-of-the-art science to those who need to use it. Possible applications of this approach for ecosystems of the Humboldt Current are discussed.  相似文献   

Discovery of cryptotephra at Middle–Upper Paleolithic sites Arma Veirana and Riparo Bombrini,Italy: a new link for broader geographic correlations     

Jayde N. Hirniak  Eugene I. Smith  Racheal Johnsen  Minghua Ren  Jamie Hodgkins  Caley Orr  Fabio Negrino  Julien Riel-Salvatore  Shelby Fitch  Christopher E. Miller  Andrea Zerboni  Guido S. Mariani  Jacob A. Harris  Claudine Gravel-Miguel  David Strait  Marco Peresani  Stefano Benazzi  Curtis W. Marean 《第四纪科学杂志》2020,35(1-2):199-212

Chemical characterization of cryptotephra is critical for temporally linking archaeological sites. Here, we describe cryptotephra investigations of two Middle–Upper Paleolithic sites from north-west Italy, Arma Veirana and Riparo Bombrini. Cryptotephra are present as small (<100 µm) rhyolitic glass shards at both sites, with geochemical signatures rare for volcanoes in the Mediterranean region. Two chemically distinct shard populations are present at Arma Veirana (P1 and P2). P1 is a high silica rhyolite (>75 wt.%) with low FeO (<1 wt.%) and a K₂O/Na₂O > 1 and P2 is also a high silica rhyolite (>75 wt.%) but with higher FeO (2.33–2.65 wt.%). Shards at Riparo Bombrini (P3) are of the same composition as P1 shards at Arma Veirana, providing a distinct link between deposits at both sites. Geochemical characteristics suggest three possible sources for P1 and P3: eruptions from Lipari Island (56–37.7 ka) in Italy, the Acigöl volcanic field (200–20 ka) in Turkey and the Miocene Kirka-Phrigian caldera (18 Ma) in Turkey. Eruptions from Lipari Island are the most likely source for P1,3 cryptotephra. This study highlights how cryptotephra can benefit archaeology, by providing a direct link between Arma Veirana and Riparo Bombrini as well as other deposits throughout the Mediterranean.  相似文献   

Exploring pathways for sustainable water management in river deltas in a changing environment   总被引：2，自引：1，他引：1  

Marjolijn Haasnoot  Hans Middelkoop  Astrid Offermans  Eelco van Beek  Willem P. A. van Deursen 《Climatic change》2012,115(3-4):795-819

Exploring adaptation pathways into an uncertain future can support decisionmaking in achieving sustainable water management in a changing environment. Our objective is to develop and test a method to identify such pathways by including dynamics from natural variability and the interaction between the water system and society. Present planning studies on long-term water management often use a few plausible futures for one or two projection years, ignoring the dynamic aspect of adaptation through the interaction between the water system and society. Our approach is to explore pathways using multiple realisations of transient scenarios with an Integrated Assessment Meta Model (IAMM). This paper presents the first application of the method using a hypothetical case study. The case study shows how to explore and evaluate adaptation pathways. With the pathways it is possible to identify opportunities, threats, timing and sequence of policy options, which can be used by policymakers to develop water management roadmaps into the future. By including the dynamics between the water system and society, the influence of uncertainties in both systems becomes clearer. The results show, among others, that climate variability rather than climate change appears to be important for taking decisions in water management.  相似文献   

70 Years of Sunspot Observations at the Kanzelhöhe Observatory: Systematic Study of Parameters Affecting the Derivation of the Relative Sunspot Number     

Werner Pötzi  Astrid M. Veronig  Manuela Temmer  Dietmar J. Baumgartner  Heinrich Freislich  Heinz Strutzmann 《Solar physics》2016,291(9-10):3103-3122

  相似文献   

Revision and recalibration of existing shock classifications for quartzose rocks using low‐shock pressure (2.5–20 GPa) recovery experiments and mesoscale numerical modeling          下载免费PDF全文

Astrid Kowitz  Nicole Güldemeister  Ralf Thomas Schmitt  Wolf‐Uwe Reimold  Kai Wünnemann  Andreas Holzwarth 《Meteoritics & planetary science》2016,51(10):1741-1761

A combination of shock recovery experiments and numerical modeling of shock deformation in the low‐shock pressure range from 2.5 to 20 GPa for two dry sandstone types of different porosity, a completely water‐saturated sandstone, and a well‐indurated quartzite provides new insights into strongly heterogeneous distribution of different shock features. (1) For nonporous quartzo‐feldspathic rocks, the traditional classification scheme (Stöffler 1984 ) is suitable with slight changes in pressure calibration. (2) For water‐saturated quartzose rocks, a cataclastic texture (microbreccia) seems to be typical for the shock pressure range up to 20 GPa. This microbreccia does not show formation of PDFs but diaplectic quartz glass/SiO₂ melt is formed at 20 GPa (~1 vol%). (3) For porous quartzose rocks, the following sequence of shock features is observed with progressive increase in shock pressure (1) crushing of pores, (2) intense fracturing of quartz grains, and (3) increasing formation of diaplectic quartz glass/SiO₂ melt replacing fracturing. The formation of diaplectic quartz glass/SiO₂ melt, together with SiO₂ high‐pressure phases, is a continuous process that strongly depends on porosity. This experimental observation is confirmed by our concomitant numerical modeling. Recalibration of the shock classification scheme results in a porosity versus shock pressure diagram illustrating distinct boundaries for the different shock stages.  相似文献   

Heterogeneous accretion,composition and core–mantle differentiation of the Earth     

David C. Rubie  Daniel J. Frost  Ute Mann  Yuki Asahara  Francis Nimmo  Kyusei Tsuno  Philip Kegler  Astrid Holzheid  Herbert Palme 《Earth and Planetary Science Letters》2011,301(1-2):31-42

A model of core formation is presented that involves the Earth accreting heterogeneously through a series of impacts with smaller differentiated bodies. Each collision results in the impactor's metallic core reacting with a magma ocean before merging with the Earth's proto-core. The bulk compositions of accreting planetesimals are represented by average solar system abundances of non-volatile elements (i.e. CI-chondritic), with 22% enhancement of refractory elements and oxygen contents that are defined mainly by the Fe metal/FeO silicate ratio. Based on an anhydrous bulk chemistry, the compositions of coexisting core-forming metallic liquid and peridotitic silicate liquid are calculated by mass balance using experimentally-determined metal/silicate partition coefficients for the elements Fe, Si, O, Ni, Co, W, Nb, V, Ta and Cr. Oxygen fugacity is fixed by the partitioning of Fe between metal and silicate and depends on temperature, pressure and the oxygen content of the starting composition. Model parameters are determined by fitting the calculated mantle composition to the primitive mantle composition using least squares minimization. Models that involve homogeneous accretion or single-stage core formation do not provide acceptable fits. In the most successful models, involving 24 impacting bodies, the initial 60–70% (by mass) of the Earth accretes from highly-reduced material with the final 30–40% of accreted mass being more oxidised, which is consistent with results of dynamical accretion simulations. In order to obtain satisfactory fits for Ni, Co and W, it is required that the larger (and later) impactor cores fail to equilibrate completely before merging with the Earth's proto-core, as proposed previously on the basis of Hf-W isotopic studies. Estimated equilibration conditions may be consistent with magma oceans extending to the core–mantle boundary, thus making core formation extremely efficient. The model enables the compositional evolution of the Earth's mantle and core to be predicted throughout the course of accretion. The results are consistent with the late accretion of the Earth's water inventory, possibly with a late veneer after core formation was complete. Finally, the core is predicted to contain ~ 5 wt.% Ni, ~ 8 wt.% Si, ~ 2 wt.% S and ~ 0.5 wt.% O.  相似文献