Effects of Rainwater Iron and Hydrogen Peroxide on Iron Speciation and Phytoplankton Growth in Seawater near Bermuda     

Joan D. Willey  Robert J. Kieber  G. Brooks Avery Jr. 《Journal of Atmospheric Chemistry》2004,47(3):209-222

Rainwater is a major source of dissolved iron to much of the world's oceans, including regions where iron may be a limiting nutrient for marine phytoplankton primary production. Rainwater iron is therefore potentially important in regulating global photosynthetic uptake of CO₂, and hence climate. Two rainwater addition bioassay experiments (2% rain) conducted at the Bermuda Atlantic Time-series Station (BATS) during March 2000 using 50 or 100 nM FeCl₂ or FeCl₃ in synthetic rain (pH 4.5 H₂SO₄) showed an increase in chlorophyll a 50% greater than controls after three days. Addition of 20 μM hydrogen peroxide, a typical rainwater concentration at BATS, completely removed the chlorophyll a increase with both forms of iron additions, suggesting stimulation of phytoplankton growth by rainwater iron can be limited by rainwater H₂O₂. In laboratory experiments using Gulf Stream seawater, iron-enriched (100 nM Fe(III)) synthetic rain was mixed with seawater in a 5% rain 95% seawater ratio. Dissolved iron concentrations increased two times above concentrations predicted based on dilution alone. The increase in soluble iron probably resulted from release from seawater particles and was maintained for more than 24 hours. No increase was observed in controls that did not have iron added to the synthetic rain, or with synthetic rainwater containing both added iron and H₂O₂. The increase in iron concentration above that predicted by dilution indicates rain may have a larger effect on seawater iron concentrations than that calculated for rainwater iron addition alone.  相似文献   

Sr and Nd isotopic compositions, age and petrogenesis of A-type granitoids of the Vernon Supersuite, New Jersey Highlands, USA   总被引：3，自引：0，他引：3  

Richard A. Volkert  Mark D. Feigenson  Lina C. Patino  Jeremy S. Delaney  Avery Ala Drake Jr. 《Lithos》2000,50(4):895-347

Voluminous late Mesoproterozoic monzonite through granite of the Vernon Supersuite underlies an area of approximately 1300 km² in the Highlands of northern New Jersey. The Vernon Supersuite consists of hastingsite±biotite-bearing granitoids of the Byram Intrusive Suite (BIS) and hedenbergite-bearing granitoids of the Lake Hopatcong Intrusive Suite (LHIS). These rocks have similar major and trace element abundances over a range of SiO₂ from 58 to 75 wt.%, are metaluminous to weakly peraluminous, and have a distinctive A-type chemistry characterized by high contents of Y, Nb, Zr, LREE, and Ga/Al ratios, and low MgO, CaO, Sr and HREE. Whole-rock Rb–Sr isochrons of BIS granite yield an age of 1116±41 Ma and initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70389, and of LHIS granite an age of 1095±9 Ma and initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70520. Both suites have similar initial ¹⁴³Nd/¹⁴⁴Nd ratios of 0.511267 to 0.511345 (BIS) and 0.511359 to 0.511395 (LHIS). Values of _Nd are moderately high and range from +1.21 to +2.74 in the BIS and +2.24 to +2.95 in the LHIS. Petrographic evidence, field relationships, geochemistry, and isotopic data support an interpretation of comagmatism and the derivation of both suites from a mantle-derived or a juvenile lower crustal parent with little crustal assimilation. Both suites crystallized under overlapping conditions controlled by P–T–f_H2O. Lake Hopatcong magma crystallized at a liquidus temperature that approached 900°C and a pressure of about 6 kbar, and remained relatively anhydrous throughout its evolution. Initial P–T conditions of the Byram magma were ≥850°C and about 5.5 kbar. BIS magma was emplaced contemporaneous with, or slightly preceding LHIS magma, and both magmas were emplaced during a compressional tectonic event prior to granulite facies metamorphism that occurred in the Highlands between 1080 and 1030 Ma.  相似文献   

Recharge characteristics of a phreatic aquifer as determined by storage accumulation     

Neil J. Ketchum  Joseph J. Donovan  William H. Avery 《Hydrogeology Journal》2000,8(6):579-593

The cumulative storage accumulation curve (CSAC) is a tool for saturated-volume fluctuation (SVF) analysis of transient recharge to shallow phreatic aquifers discharging only to springs. The method assumes that little underflow or phreatic evapotranspiration occurs. The CSAC is a modified water-table hydrograph that distinguishes storage increase caused by recharge from loss due to springflow-induced recession. Required for the analysis are water-table fluctuations at a single representative location within the catchment of a single spring and either direct measurements or robust interpolations of springflows at different aquifer stages. The method employs empirical manipulation of head observations, varying spring catchment area to minimize CSAC water-level changes in late portions of long recessions. Results include volumetric estimates of recharge integrated over individual events and instantaneous rates of recharge to the water table, at the temporal resolution of the water-level sampling interval. The analysis may also yield physically realistic information on spring catchment and recharge focusing. In a test case in West Virginia, USA, recharge estimates by this technique were consistent with integrated springflow time series but greater than estimates based on potential evapotranspiration. Results give insight into dynamic recharge behavior over time as well as an indication of recharge catchment size. Electronic Publication  相似文献   

Energy transfer by the scattering of resonant photons     

Avery Meiksin 《Monthly notices of the Royal Astronomical Society》2006,370(4):2025-2037

A formal derivation is presented of the energy transfer rate between radiation and matter due to the scattering of an isotropic distribution of resonance line photons. The derivation is developed in the context of the two-level atom in the absence of collisions and radiative transitions to and from the continuum, but includes the full angle-averaged redistribution function for photon scattering. The result is compared with previous derivations, all of which have been based on a Fokker–Planck approximation (FPA) to the radiative transfer equation. A new FPA, including a Kramers–Moyal extension to higher (post-diffusive) orders, is derived to solve the radiative transfer equation, and time-dependent numerical solutions are found. The relaxation of the colour temperature to the matter temperature is computed as the radiation field approaches statistical equilibrium through scattering. The results are discussed in the context of the Wouthuysen–Field mechanism for coupling the 21-cm spin temperature of neutral hydrogen to the kinetic temperature of the gas through Lyα scattering. The evolution of the heating rate is also computed, and shown to diminish as the gas approaches statistical equilibrium.  相似文献   

A multidimensional, adiabatic hydrodynamics code for studying tidal excitation     

Avery E. Broderick  Yasser Rathore 《Monthly notices of the Royal Astronomical Society》2006,372(2):923-932

We have developed a massively parallel, simple and fast hydrodynamics code for multidimensional, self-gravitating and adiabatic flows. Our primary motivation is the study of the non-linear development of white dwarf oscillations excited via tidal resonances, typically over hundreds of stellar dynamical times. Consequently, we require long-term stability, low diffusivity and high-numerical efficiency. This is accomplished by an Eulerian finite-difference scheme on a regular Cartesian grid. This choice of coordinates provides uniform resolution throughout the flow as well as simplifying the computation of the self-gravitational potential, which is done via spectral methods. In this paper, we describe the numerical scheme and present the results of some common diagnostic problems. We also demonstrate the stability of a cold white dwarf in three dimensions over hundreds of dynamical times. Finally, we compare the results of the numerical scheme to the linear theory of adiabatic oscillations, finding numerical quality factors on the order of 6000 and excellent agreement with the oscillation frequency obtained by the linear analysis.  相似文献   

Imaging bright-spots in the accretion flow near the black hole horizon of Sgr A*   总被引：1，自引：0，他引：1  

Avery E. Broderick  Abraham Loeb 《Monthly notices of the Royal Astronomical Society》2005,363(2):353-362

Solar active regions are distinguished by their strong magnetic fields. Modern local helioseismology seeks to probe them by observing waves which emerge at the solar surface having passed through their interiors. We address the question of how an acoustic wave from below is partially converted to magnetic waves as it passes through a vertical magnetic field layer where the sound and Alfvén speeds coincide (the equipartition level), and find that (i) there is no associated reflection at this depth, either acoustic or magnetic, only transmission and conversion to an ongoing magnetic wave; and (ii) conversion in active regions is likely to be strong, though not total, at frequencies typically used in local helioseismology, with lower frequencies less strongly converted. A simple analytical formula is presented for the acoustic-to-magnetic conversion coefficient.  相似文献   

Resonant excitation of white dwarf oscillations in compact object binaries – I. The no back reaction approximation     

Yasser Rathore  Roger D. Blandford  Avery E. Broderick 《Monthly notices of the Royal Astronomical Society》2005,357(3):834-846

We consider the evolution of white dwarfs with compact object companions (specifically black holes with masses up to  ∼10⁶  M_⊙  , neutron stars, and other white dwarfs). We suppose that the orbits are initially quite elliptical and then shrink and circularize under the action of gravitational radiation. During this evolution, the white dwarfs will pass through resonances when harmonics of the orbital frequency match the stellar oscillation eigenfrequencies. As a star passes through these resonances, the associated modes will be excited and can be driven to amplitudes that are so large that there is a back reaction on the orbit which, in turn, limits the growth of the modes. A formalism is presented for describing this dynamical interaction for a non-rotating star in the linear approximation when the orbit can be treated as non-relativistic. A semi-analytical expression is found for computing the resonant energy transfer as a function of stellar and orbital parameters for the regime where back reaction may be neglected. This is used to calculate the results of passage through a sequence of resonances for several hypothetical systems. It is found that the amplitude of the  ℓ= m = 2  f -mode can be driven into the non-linear regime for appropriate initial conditions. We also discuss where the no back reaction approximation is expected to fail, and the qualitative effects of back reaction.  相似文献   

Biogeochemistry of Ethanol and Acetaldehyde in Freshwater Sediments     

J. Alan RoebuckJr.  G. Brooks Avery  J. David Felix  Robert J. Kieber  Ralph N. Mead  Stephen A. Skrabal 《Aquatic Geochemistry》2016,22(3):177-195

This study reports the first ethanol and acetaldehyde measurements in sediment porewaters collected at multiple freshwater locations. Ethanol concentrations ranged from 11 to 2535 nM and acetaldehyde concentrations ranged from 6 to 320 nM. A significant positive correlation (p < 0.001) was observed between ethanol concentrations and the percent organic carbon content of sediments (TOC). Porewater depth profiles at two sites within the same lake indicated potential diffusion of ethanol into sediments from the overlying water at a lower TOC site and upwards diffusion from sediment into the water column at a higher TOC site. Diffusion of water column ethanol into sediments was observed at individual sites from October to January, whereas the opposite was true from June to August indicating the seasonal variability of ethanol flux from sediments. Changes in ethanol concentrations during a long-term sediment incubation experiment showed an inverse relation with acetaldehyde concentrations. The lack of a quantitative conversion was likely due to other sources and sinks that control their abundance. Our study provided new information on the biogeochemistry of ethanol in freshwater sediments and shed light on the potential role of ethanol in the global carbon cycle.  相似文献   

Diatom assemblages reveal regional-scale differences in lake responses to recent climate change at the boreal-tundra ecotone,Manitoba, Canada     

Avery L. C. Shinneman  Charles E. Umbanhowar  Mark B. Edlund  William O. Hobbs  Philip Camill  Christoph Geiss 《Journal of Paleolimnology》2016,56(4):275-298

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Helium reionization and the thermal proximity effect     

Avery Meiksin  Eric R. Tittley  Calum K. Brown 《Monthly notices of the Royal Astronomical Society》2010,401(1):77-87

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