Hydrogeochemical characteristics and its role in controlling arsenic mobilization in a shallow aquifer     

Das  Ayan  Mandal  Abhijit 《中国地球化学学报》2021,40(6):912-925

The relevance of groundwater hydrogeochemistry to explain the occurrence and distribution of arsenic in groundwater is of great interest. The insightful discussions on the control of shallow groundwater (< 50 m) hydrogeochemistry in arsenic mobilization are known to be a viable tool to explain the arsenic menace in shallow groundwater. The present investigation emphasizes the hydrogeochemical driver and/or control over the reductive dissolution of Fe-bearing host minerals and thereby releasing arsenic into the shallow groundwater of the study area. The study suggests that hydrogeochemical evolution is mainly governed by carbonate minerals dissolution, silicate weathering, and competitive ion-exchange processes in the shallow aquifers (< 50 m). The present study also indicates the prevalence of carbonate minerals dissolution over silicate weathering. The emergence of Cl⁻ concentration in the shallow groundwater founds the possibilities of anthropogenic inputs into the shallow aquifers (< 50 m). The reducing environment in shallow aquifers (< 50 m) of the study area is evident in the reductive dissolution of Fe- bearing shallow aquifer minerals which absorb arsenic in the solid phase and mobilize arsenic onto shallow groundwater. The study opted for many statistical approaches to delineate the correlation among major and minor ionic constituents of the groundwater which are very helpful to understand the comprehensive mechanism of arsenic mobilization into shallow groundwater.

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Hydrogeological characterization of the Quaternary aquifer of south Bengal Basin in India and the impact of urbanization on the groundwater resources of the system     

Banerjee  Sumanta  Sikdar  Pradip K. 《Hydrogeology Journal》2021,29(4):1463-1484

Hydrogeology Journal - The study defines the hydrogeological framework of the Quaternary aquifer of south Bengal Basin, India, and the impact of urbanisation on the groundwater resources in and...  相似文献   

Rock-magnetic proxies of climate change in the loess-palaeosol sequences of the western Loess Plateau of China   总被引：5，自引：0，他引：5  

Christopher P. Hunt  Subir K. Banerjee  Jiamao Han  Peter A. Solheid  Eric Oches  Weiwei Sun  Tungsheng Liu 《Geophysical Journal International》1995,123(1):232-244

Results of the first detailed study of the climate proxy record in the loess-palaeosol sequence at Xining-one of the few palaeoclimate sites in the currently arid western Loess Plateau of China-illustrate the importance of making many types of rock-magnetic measurements other than susceptibility. A multiparameter approach yielded confirmation that here, as elsewhere in the Loess Plateau, the susceptibility enhancement in palaeosols was caused primarily by ultrafine magnetite and maghaemite. Nevertheless, magnetic enhancement was caused not exclusively by changes in relative grain size, but also by variations in concentration and mineralogy of the magnetic fraction.
The effects of concentration variations were removed through normalization of susceptibility and anhysteretic remanence with saturation magnetization and saturation remanence, respectively. the resulting signal was ascribed more confidently to variation in magnetic grain size, which in turn was interpreted as a better proxy of pedogenesis than simple susceptibility. Variations in magnetic mineralogy were also determined to constrain interpretations further. the data were then used to discuss climate history at Xining. Finally, results from Xining were compared with other western sites and contrasted with eastern sites.
In summary: (1) data is presented from a new Loess Plateau site which also appears to yield a global climate signal; (2) a demonstration is made of a more rock-magnetically robust way to separate concentration, composition and grain-size controls on susceptibility and other magnetic parameters; and (3) models are provided for inter-regional comparisons of palaeoclimate proxy records.  相似文献   

A fundamental solution due to a periodic point force in the interior of an elastic half-space     

P. K. Banerjee  S. M. Mamoon 《地震工程与结构动力学》1990,19(1):91-105

The fundamental solution for a periodic point force in the interior of a three-dimensional, homogeneous, isotropic, elastic half-space is derived. The method of synthesis and superposition is employed to obtain the solution in the Laplace transform as well as the frequency domain. These correspond to the dynamic equivalent of Mindlin's static half-space point force solutions. It is reduced, for certain limiting conditions, to the dynamic equivalent of Boussinesq's and Cerruti's problems of a normal and tangential periodic point force respectively, on the boundary of a half-space. Also, static solutions of Mindlin, Boussinesq and Cerruti are recovered for small frequency parameters. Finally, results are presented and compared with other available solutions.  相似文献   

Response of piles and pile groups to travelling SH-waves     

S. M. Mamoon  P. K. Banerjee 《地震工程与结构动力学》1990,19(4):597-610

The response of single piles and pile groups under vertically and obliquely incident seismic waves is obtained using the hybrid boundary element (BEM) formulation. The piles are represented by compressible beam-column elements and the soil as a hysteretic viscoelastic half-space. A recently developed Green function corresponding to the dynamic Mindlin problem is implemented in the numerical formulation. Exact analytical solutions for the differential equations for the piles under distributed harmonic excitations are used. Treating the half-space as a three-dimensional elastic continuum, the interaction problem is formulated by satisfying equilibrium and displacement compatibility along the pile-soil interface. Solutions adopted for the seismic waves are obtained by direct integration of the differential equations in terms of amplitudes. Salient features of the seismic response are identified in several non-dimensional plots. Results of the analyses compare favourably with the limited data available in the literature.  相似文献   

Multilayer Sampling in the Water-Table Region of a Sandy Aquifer     

Edward Kaplan  Sujit Banerjee  Daniel Ronen  Mordeckai Magaritz  Albert Machlin  Michael Sosnow  Eric Koglin 《Ground water》1991,29(2):191-198

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Genetic reinterpretation of crystallographicintergrowths of jacobsite andhausmannite from natural assemblages     

Dr. Somnath Dasgupta  P. K. Bhattacharya  G. Chattopadhyay  M. Fukuoka  H. Banerjee  Supriya Roy 《Mineralogy and Petrology》1987,37(2):109-116

Summary Crystallographic intergrowths of jacobsite and hausmannite (vredenburgite) occur in association with braunite in the Precambrian Sausar Group of rocks, India, that were metamorphosed under 600-700°C and P 6 kb. Quartz, hematite, rhodochrosite and a later hausmannite may occasionally occur as minor associates. Detailed characterization of the intergrown phases reveals that hausmannite lamellae, oriented in 4 or 5 crystallographic directions in the jacobsite host, show a wide variation in thickness and tapered intersections at low angles. The lamellae may be locally deformed. Analytical data reveal that the composition of natural hausmannite and jacobsite in the intergrowths cannot be approximated within the system Fe₃O₄ -Mn₃O₄, as has been conventionally done. These really belong to the Fe₂O₃-Mn₃O₄ subsystem. In the two phase intergrowths, hausmannite is depleted and the jacobsite is enriched in Fe in higher grade rocks. Mineral associations and petrographic considerations suggest that the jacobsite-hausmannite intergrowth originated through prograde decarbonation-oxidation reactions of a carbonatic precursor in an unbuffered X CO₂ situation, but f O₂ was held between hematite-magnetite and bixbyite-hausmannite buffers at the ambient physical conditions of metamorphism. Subsequent oxidation yielded a strong oxygenbuffering assemblage jacobsite, hausmannite, braunite, hematite and quartz. This study negates the commonly held idea that hausmannite jacobsite crystallographic intergrowth (vredenburgite) originates through unmixing of a high ([ldvredenburgite) originates through unmixing of a high temperature spinel_ss temperature spinel_ss during cooling.

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Genetische Reinterpretation der kristallographischen Verwachsungen von Jakobsit und Hausmannit in natürlichen Vorkommen

Zusammenfassung Kristallographische Verwachsungen von Jakobsit und Hausmannit (Vredenburgit) treten in Verbindung mit Braunit in Gesteinen der präkambrischen Sausargruppe in Indien auf. Die Gesteine wurden bei Drucken von ca. 6 kbar und Termperaturen von 600–700°C metamorphosiert. Quarz, Hämatit, Rhodochrosit, und Hausmannit als Spätphase treten gelegentlich als untergeordnete Gemengteile auf. Hausmannit-Lamellen, die in vier oder fünf kristallographischen Richtungen in Jakobsit orientiert sind, haben sehr unterschiedliche Durchmesser und bilden versetzte Zwickel in kleinem Winkel mit dem Jakobsit. Die Lamellen können lokal deformiert sein. Analytische Daten zeigen, daß die Zusammensetzung von natürlichem Hausmannit und Jakobsit in Verwachsungen nicht, wie bisher angenommen, in dem System Fe₃O₄-Mn₃O₄ dargestellt werden kann. Diese Verwachsungen gehören vielmehr in das Fe₂O₃-Mn₃O₄ System. In höher-gradigen metamorphen Gesteinen ist Fe in zwei-phasigen Verwachsungen im Hausmannit ab- und im Jakobsit angereichert. Die Mineralzusammensetzung und petrographische Gesichtspunkte lassen darauf schließen, daß die Jakobsit/Hausmannit Verwachsung durch prograde Dekarbonatisierung/Oxydationsreaktion eines karbonatischen Vorläufers in einem nicht gepufferten X CO₂ Milieu entstanden ist. F O₂ wurde durch Hämatit-Magnetit und Bixbyit-Hausmannit Puffer unter den gegebenen physikalischen Bedingungen der Metamorphose stabil gehalten. Eine nachfolgende Oxydation führte zu einer starken Sauerstoff-puffernden Assoziation von Jakobsit, Hausmannit, Braunit, Hämatit und Quarz. Diese Untersuchungen widerlegen die allgemein verbreitete Ansicht, daß die kristallographische Verwachsung von Hausmannit und Jakobsit (Vredenburgit) durch Entmischung eines Hochtemperatur-Spinells während der Abkühlung entstanden ist.

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Precambrian phosphorites in the Bijawar rocks of Hirapur-Bassia areas,sagar district,madhya pradesh,India     

D. M. Banerjee  M. W. Y. Khan  Neeta Srivastava  G. C. Saigal 《Mineralium Deposita》1982,17(3):349-362

The Precambrian phosphorites of Bijawar Group of rocks show characteristics of a epicontinental sea with restricted and very shallow marine environment of formation along some shoals, which existed during the iron-rich Precambrian times. These phosphorite deposits located in the Hirapur-Bassia areas show extensive leaching of carbonate and phosphate minerals during episodes of weathering. X-ray diffraction studies indicated that carbonate-flourapatite is the major apatitic phase in these phosphorites while crandallite developed on the surface outcrops. There is a general tendency for the depletion of CO₂ in these apatites leading to formation of flourapatite. This CO₂ is an indicator of hidden weathering in the rocks. Major and trace element determinations of phosphorite have been used to indicate various correlation factors responsible for the concentration of elements in these Precambrian leached phosphorites.The paper is a contribution to the aims and objectives of IGCP Project 156The paper is dedicated to Prof. Dr. R. C. Misra, who as a teacher and guide had been a source of inspiration to the senior author for the last two decades  相似文献   

Impact of Doppler Radar Wind in Simulating the Intensity and Propagation of Rainbands Associated with Mesoscale Convective Complexes Using MM5-3DVAR System     

S. Abhilash  Someshwar Das  S. R. Kalsi  M. Das Gupta  K. Mohankumar  John P. George  S. K. Banerjee  S. B. Thampi  D. Pradhan 《Pure and Applied Geophysics》2007,164(8-9):1491-1509

Pre-monsoon rainfall around Kolkata (northeastern part of India) is mostly of convective origin as 80% of the seasonal rainfall is produced by Mesoscale Convective Systems (MCS). Accurate prediction of the intensity and structure of these convective cloud clusters becomes challenging, mostly because the convective clouds within these clusters are short lived and the inaccuracy in the models initial state to represent the mesoscale details of the true atmospheric state. Besides the role in observing the internal structure of the precipitating systems, Doppler Weather Radar (DWR) provides an important data source for mesoscale and microscale weather analysis and forecasting. An attempt has been made to initialize the storm-scale numerical model using retrieved wind fields from single Doppler radar. In the present study, Doppler wind velocities from the Kolkata Doppler weather radar are assimilated into a mesoscale model, MM5 model using the three-dimensional variational data assimilation (3DVAR) system for the prediction of intense convective events that occurred during 0600 UTC on 5 May and 0000 UTC on 7 May, 2005. In order to evaluate the impact of the DWR wind data in simulating these severe storms, three experiments were carried out. The results show that assimilation of Doppler radar wind data has a positive impact on the prediction of intensity, organization and propagation of rain bands associated with these mesoscale convective systems. The assimilation system has to be modified further to incorporate the radar reflectivity data so that simulation of the microphysical and thermodynamic structure of these convective storms can be improved.  相似文献   

Experimental Seasonal Forecast of Monsoon 2005 Using T170L42 AGCM on PARAM Padma     

J. Venkata Ratnam  D. R. Sikka  Akshara Kaginalkar  Amit Kesarkar  N. Jyothi  Sudipta Banerjee 《Pure and Applied Geophysics》2007,164(8-9):1641-1665

As a part of the Experimental Extended Range Monsoon Prediction Experiment, ensemble mode seasonal runs for the monsoon season of 2005 were made using the National Centre for Environmental Prediction (NCEP), T170L42 AGCM. The seasonal runs were made using six initial atmospheric conditions based on the NCEP operational analysis and with forecast monthly sea-surface temperature (SST) of the NCEP Coupled forecast system (CFS). These simulations were carried out on the PARAM Padma supercomputer of Centre for Development of Advanced Computing (C-DAC), India. The model climatology was prepared by integrating the model for ten years using climatological SST as the lower boundary. The climatology of the model compares well with the observed, in terms of the spatial distribution of rainfall over the Indian land mass. The model-simulated rainfall compares well with the Tropical Rainfall Measuring Mission (TRMM) estimates for the 2005 monsoon season. Compared to the model climatology (7.81 mm/day), the model had simulated a normal rainfall (7.75 mm/day) for the year 2005 which is in agreement with the observations (99% of long-term mean). However, the model could not capture the observed increase in September rainfall from that of a low value in August 2005. The circulation patterns simulated by the model are also comparable to the observed patterns. The ensemble mean onset is found to be nearer to the observed onset date within one pentad.  相似文献