Structure of Cl-containing silicate and aluminosilicate glasses: A Cl MAS-NMR study     

Travis O. Sandland  Jonathan F. Stebbins  James D. Webster 《Geochimica et cosmochimica acta》2004,68(24):5059-5069

Chlorine-35 magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectra were collected at 14.1 and 18.8 Tesla fields to determine the atomic scale structural environments of the chloride ions in anhydrous and hydrous silicate and aluminosilicate glasses containing 0.2 to 0.7 wt% Cl. NMR peaks are broad and featureless, but are much narrower than the total chemical shift range for the nuclide in inorganic chlorides. Peak widths are primarily due to quadrupole interactions and to a lesser extent to chemical shift distributions. Peak positions are quite different for the Na- and Ca-containing glasses, suggesting that most Cl⁻ coordination environments contain network modifier cations. Comparison of peak positions and shapes for silicate and aluminosilicate glasses containing either Na or Ca suggests that there is no obvious contribution from Cl⁻ bonded to Al, and relative quantitation of peak areas indicates that there is no systematic undercounting of ³⁵Cl spins in the aluminous vs. the Al-free samples. In Ca-Na silicate glasses with varying Ca/(Ca + Na), the mixed-cation glasses have intermediate chemical shifts between those of the end members, implying that there is not a strong preference of either Ca²⁺ or of Na⁺ around Cl⁻. Hydrous Na-aluminosilicate glasses with H₂O contents up to 5.9 wt% show a shift to higher frequency NMR signal with increasing H₂O content, while the quadrupole coupling constant (C_Q) remains constant at ∼3.3 MHz. However, the change in frequency is much smaller than that expected if H₂O systematically replaced Na⁺ in the first-neighbor coordination shell around Cl⁻. A series of hydrous Ca-aluminosilicate glasses with H₂O contents up to 5.5 wt% show no shift in NMR signal with increasing H₂O content. The C_Q remains constant at ∼4.4 MHz, again suggesting no direct interaction between Cl⁻ and H₂O in these samples.  相似文献   

Hydrothermal convection in carbonaceous chondrite parent bodies     

Bryan J. Travis  Gerald Schubert 《Earth and Planetary Science Letters》2005,240(2):234-250

Numerical simulations of the thermal evolution of carbonaceous chondrite parent bodies indicate a period of several million years during which convective motion of water could occur. The present study considers variations of permeability, radiogenic heating, and body radius. The model accounts for the radial variation of gravity within the body, melting of ice, freezing of liquid water, and variable water properties and incorporates a realistic equation of state for water. Some regions of a parent body experience no pore water flow while other regions experience hundreds of pore volumes of liquid water flow. The spatial heterogeneity in pore water flow reflects the convective pattern in the body. Hydrothermal alteration of minerals inside the parent body will accordingly vary greatly with location in the body, and one parent body could be the source of chemically diverse meteorites.  相似文献   

Near-infrared spectroscopic search for the close orbiting planet HD 75289b     

J. R. Barnes  C. J. Leigh  H. R. A. Jones  Travis S. Barman  D. J. Pinfield  A. Collier Cameron  J. S. Jenkins 《Monthly notices of the Royal Astronomical Society》2007,379(3):1097-1107

We present a search for the near-infrared spectroscopic signature of the close orbiting extrasolar giant planet HD 75289b. We obtained ∼230 spectra in the wavelength range 2.18–2.19 μm using the Phoenix spectrograph at Gemini South. By considering the direct spectrum, derived from irradiated model atmospheres, we search for the absorption profile signature present in the combined star and planet light. Since the planetary spectrum is separated from the stellar spectrum at most phases, we apply a phase-dependent orbital model and tomographic techniques to search for absorption signatures.
Because the absorption signature lies buried in the noise of a single exposure we apply a multiline deconvolution to the spectral lines available in order to boost the effective signal-to-noise ratio (S/N) of the data. The wavelength coverage of 80 Å is expected to contain ∼100 planetary lines, enabling a mean line with S/N of 800 to be achieved after deconvolution. We are nevertheless unable to detect the presence of the planet in the data and carry out further simulations to show that broader wavelength coverage should enable a planet like HD 75289b to be detected with 99.9 per cent confidence. We investigate the sensitivity of our method and estimate detection tolerances for mismatches between observed and model planetary atmospheres.  相似文献   

Galileo Photopolarimetry of Jupiter at 678.5 nm     

C.J. BraakJ.F. de Haan  J.W. Hovenier  L.D. Travis 《Icarus》2002,157(2):401-418

Brightness and linear polarization measurements at 678.5 nm for four south-north strips of Jupiter are studied. These measurements were obtained in 1997 by the Galileo photopolarimeter/radiometer. The observed brightness exhibits latitudinal variations consistent with the belt/zone structure of Jupiter. The observed degree of linear polarization is small at low latitudes and increases steeply toward higher latitudes. No clear correlations were observed between the degree of linear polarization and the brightness. The observed direction of polarization changes from approximately parallel to the local scattering plane at low latitudes to perpendicular at higher latitudes. For our studies, we used atmospheric models that include a haze layer above a cloud layer. Parameterized scattering matrices were employed for the haze and cloud particles. On a pixel-wise basis, the haze optical thickness and the single-scattering albedo of the cloud particles were derived from the observed brightness and degree of linear polarization; results were accepted only if they were compatible with the observed direction of polarization. Using atmospheric parameter values obtained from Pioneer 10 and 11 photopolarimetry for the South Tropical Zone and the north component of the South Equatorial Belt, this analysis yielded acceptable results for very few pixels, particularly at small phase angles. However, for almost all pixels, acceptable results were found when the parameterized scattering matrix of the cloud particles was adjusted to produce more negative polarization for single scattering of unpolarized light, especially at large scattering angles, similar to some laboratory measurements of ammonia ice crystals. Using this adjusted model, it was found that the derived latitudinal variation of the single-scattering albedo of the cloud particles is consistent with the belt/zone structure, and that the haze optical thickness steeply increases toward higher latitudes.  相似文献   

Anomalous bathymetry, 3D edge driven convection, and dynamic topography at the western Atlantic passive margin     

Travis Ramsay  Russell Pysklywec 《Journal of Geodynamics》2011,52(1):45-56

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Coupling thermodynamic modeling and high-resolution in situ LA-ICP-MS monazite geochronology: evidence for Barrovian metamorphism late in the Grenvillian history of southeastern Ontario     

Travis McCarron  Fred Gaidies  Christopher R. M. McFarlane  R. Michael Easton  Peter Jones 《Mineralogy and Petrology》2014,108(6):741-758

The Flinton Group is a greenschist to upper amphibolite facies package of metasediments in southeastern Ontario that was metamorphosed during the Ottawan Orogeny. Thermodynamic modeling of metapelitic mineral assemblages suggests an increase in peak conditions of metamorphism across the 40 km wide study area from 3.5 to 7.9 kbar and 540 to 715 °C. Garnet isopleth thermobarometry applied to the cores of compositionally zoned porphyroblasts reveals remarkably similar P-T conditions of initial crystallization at approximately 3.7–4.0 kbar and 512–520 °C, corresponding to a relatively high geothermal gradient of ca. 34–45 °C km^?1. It is inferred from modeling and reaction textures that metamorphism was along Barrovian P-T paths. Major and trace element zoning in garnet from one sample records a complex growth history as evidenced by major and trace element zoning and the distribution of xenotime, allanite and monazite inclusions. High-resolution (6 μm) LA-ICP-MS U-Pb geochronology performed on monazite in the rock matrix and included in the outer 150 μm of garnet rim-ward of a Y annulus revealed an age of 976?±?4 Ma. The age is interpreted to reflect monazite growth at the expense of allanite and apatite late in garnet’s growth history over the P-T interval 4.5–6.8 kbar and 540–640 °C. This new age estimate for near peak metamorphism fits well into the regional framework but is significantly younger than previously reported ages for Ottawan metamorphism. Based on microstructures this new age suggests that compressional tectonics were operating much later in the history of the Grenville of southeastern Ontario than previously thought.  相似文献   

Evaluation of Long‐Term Performance and Sustained Treatment at Enhanced Anaerobic Bioremediation Sites          下载免费PDF全文

Travis M. McGuire  David. T. Adamson  Michael S. Burcham  Philip B. Bedient  Charles J. Newell 《Ground Water Monitoring & Remediation》2016,36(2):32-44

This study evaluated the long‐term performance of enhanced anaerobic bioremediation (EAB) at chlorinated solvent sites to determine if sustained treatment processes were helping to prevent concentration rebound. A database of groundwater concentration versus time records was compiled for 34 sites, with at least 3 years of posttreatment monitoring data (median = 4.7 years, range = 3.0 to 11.7 years). Long‐term performance was evaluated based on order‐of‐magnitude (OoM) changes in parent compound concentrations during various monitoring periods. Results indicate that, relative to the pretreatment concentration, a median concentration reduction for all 34 sites of 1.0 OoM (90% reduction) was achieved by the end of the posttreatment monitoring period. No rebound was observed at 65% of the sites between the first year of posttreatment monitoring and the final year. During this posttreatment period, Mann‐Kendall trend analysis indicated that the concentration was stable or decreasing at 89% of the sites where a trend could be established (n = 27; 33% decreasing, 56% stable, 11% increasing). Statistical analysis indicates there is no evidence that the distribution of median concentration reductions after the first year of posttreatment monitoring was different than the distribution of median reductions 2 to 11 years later at the end of the monitoring period (p = 0.67). Similarly, statistical analysis indicates that there is no evidence that the distribution of median reductions for a larger set of sites (n = 84) with less than 3 years of posttreatment monitoring data (1.1 OoM; 92% reduction) was different than the distribution of median OoM reductions for the 34‐site dataset with longer monitoring periods (p = 0.80). This suggests that, at a typical site, a 3‐year monitoring period should be sufficient for evaluating performance. The results of this study indicate that, in the long term, after the end of active treatment, sustained treatment processes contribute to relatively modest concentration reductions but do mitigate rebound at the majority of EAB sites.  相似文献   

A Surface Model for Aeolian Dune Topography     

Travis Swanson  David Mohrig  Gary Kocurek  Man Liang 《Mathematical Geosciences》2017,49(5):635-655

A surface model for aeolian bedform topography is adapted from a surface model of subaqueous bedform topography. The aeolian bedform surface model is developed using a uniform grid with a cell-centered finite volume approximation of the sediment continuity equation. The resulting modeling framework approximates the dynamic motions of aeolian bedform topography driven by bedform field boundary conditions. The numerical model is applied to simulate bedforms growing from unimodal and bimodal transport regimes from both a fixed elevation (sediment source area) and within a domain with fully periodic boundary conditions. The rates at which modeled aeolian bedforms grow and morphologically mature are sensitive to the chosen boundary conditions. Video files of model simulations and source code for the presented aeolian bedform surface modeling framework are available in supplemental materials. The aeolian bedform surface model code is malleable and readily modified for exploratory study of dynamic bedform topography that inherits morphological traits from aeolian bedform field boundary conditions.  相似文献   

Iron concretions within a highly altered unit of the Berlins Porphyry,New Zealand: an abiotic or biotic story?     

Cox  Toni L.  Oze  Christopher  Horton  Travis W. 《Mineralogy and Petrology》2017,111(2):173-181

Mineralogy and Petrology - The Berlins Porphyry located on the South Island of New Zealand provides an opportunity to examine iron concretions formed in a subterranean system. Specifically, an...  相似文献   

Snow disappearance timing is dominated by forest effects on snow accumulation in warm winter climates of the Pacific Northwest,United States          下载免费PDF全文

Susan E. Dickerson‐Lange  Rolf F. Gersonde  Jason A. Hubbart  Timothy E. Link  Anne W. Nolin  Gwyneth H. Perry  Travis R. Roth  Nicholas E. Wayand  Jessica D. Lundquist 《水文研究》2017,31(10):1846-1862

Forests modify snow processes and affect snow water storage as well as snow disappearance timing. However, forest influences on snow accumulation and ablation vary with climate and topography and are therefore subject to temporal and spatial variability. We utilize multiple years of snow observations from across the Pacific Northwest, United States, to assess forest–snow interactions in the relatively warm winter conditions characteristic of maritime and transitional maritime–continental climates. We (a) quantify the difference in snow magnitude and disappearance timing between forests and open areas and (b) assess how forest modifications of snow accumulation and ablation combine to determine whether snow disappears later in the forest or in the open. We find that snow disappearance timing at 12 (out of 14) sites ranges from synchronous in the forest and open to snow persisting up to 13 weeks longer in the open relative to a forested area. By analyzing accumulation and ablation rates up to the day when snow first disappears from the forest, we find that the difference between accumulation rates in the open and forest is larger than the difference between ablation rates. Thus, canopy snow interception and subsequent loss, rather than ablation, set up longer snow duration in the open. However, at two relatively windy sites (hourly average wind speeds up to 8 and 17 m/s), differential snow disappearance timing is reversed: Snow persists 2–5 weeks longer in the forest. At the windiest sites, accumulation rates in the forest and open are similar. Ablation rates are higher in the open, but the difference between ablation rates in the forest and open at these sites is approximately equivalent to the difference at less windy sites. Thus, longer snow retention in the forest at the windiest sites is controlled by depositional differences rather than by reduced ablation rates. These findings suggest that improved quantification of forest effects on snow accumulation processes is needed to accurately predict the effect of forest management or natural disturbance on snow water resources.  相似文献