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21.
Interferometric Synthetic Aperture Radar (InSAR), nowadays, is a precise technique for monitoring and detecting ground deformation at a millimetric level over large areas using multi-temporal SAR images. Persistent Scatterer Interferometric SAR (PSInSAR), an advanced version of InSAR, is an effective tool for measuring ground deformation using temporally stable reference points or persistent scatterers. We have applied both PSInSAR and Small Baseline Subset (SBAS) methods, based on the spatial correlation of interferometric phase, to estimate the ground deformation and time-series analysis. In this study, we select Las Vegas, Nevada, USA as our test area to detect the ground deformation along satellite line-of-sight (LOS) during November 1992–September 2000 using 44 C-band SAR images of the European Remote Sensing (ERS-1 and ERS-2) satellites. We observe the ground displacement rate of Las Vegas is in the range of ?19 to 8 mm/year in the same period. We also cross-compare PSInSAR and SBAS using mean LOS velocity and time-series. The comparison shows a correlation coefficient of 0.9467 in the case of mean LOS velocity. Along this study, we validate the ground deformation results from the satellite with the ground water depth of Las Vegas using time-series analysis, and the InSAR measurements show similar patterns with ground water data.  相似文献   
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23.
For the purpose of testing our previously described theory of SO2 scavenging a laboratory investigation was carried out in the UCLA 33 m long rainshaft. Drops with radii between 250 and 2500 m were allowed to come to terminal velocity, after which they passed through a chamber of variable length filled with various SO2 concentrations in air. After falling through a gas separating chamber consisting of a fluorocarbon gas the drops were collected and analyzed for their total S content in order to determine the rate of SO 2 absorption.The SO2 concentration in air studied ranged between 1 and 60% (v). Such relatively large concentrations were necessary due to the short times the drops were exposed to SO2 in the present setup. The present experimental results were therefore not used to simulate atmospheric conditions but rather to test our previously derived theory which is applicable to any laboratory or atmospheric condition. Comparison of our studies with the results from our theory applied to our laboratory conditions led to predicted values for the S concentration in the drops which agreed well with those observed if the drops had radii smaller than 500 m. In order to obtain agreement between predicted and observed S concentrations in larger drops, an empirically derived eddy diffusivity for SO2 in water had to be included in the theory to take into account the effect of turbulent mixing inside such large drops.In a subsequent set of experiments, drops initially saturated with S (IV) were allowed to fall through S-free air to determine the rate of SO 2 desorption. The results of these studies also agreed well with the results of our theoretical model, thus justifying the reversibility assumption made in our theoretical models.In a final set of experiments, the effects of oxidation on SO2 absorption was studied by means of drops containing various amounts of H2O2. For comparable exposure times to SO2, the S concentration in drops with H2O2 was found to be up to 10 times higher than the concentration in drops in which no oxidation occurred.  相似文献   
24.
Simple, rapid, and sensitive spectrophotometric methods have been proposed for the determination of cationic surfactants (CS) as cetyltrimethylammonium bromide (CTAB), dodecyltrimethylammonium (DTAB), and cetylpyridinium bromide (CPB). The methods are based on the effects of CSs on the complexes of Al3+ and Be2+ with Chrome Azurol S (CAS). The optimum reaction conditions such as CAS concentration, metal ion concentration, and pH have been studied and found to be 2.0 × 10?4 mol L?1 CAS, 0.5 mg L?1 Al3+ or 0.4 mg L?1 Be2+ and pH 5.4. The analytical characteristics of the methods such as limit of detections, limit of quantifications, and linear ranges have been obtained. CTAB, CPB, and DTAB could be determined by the Al–CAS complex in the ranges of 0.50–40.00, 0.20–10.00, and 0.40–10.00 µmol L?1, and for the Be–CAS complex in the ranges of 0.08–5.00, 0.08–3.00, and 0.20–6.00 µmol L?1, respectively. The limit of the detections of the method for the determination of CTAB, CPB, and DTAB for the Be–CAS complex has been found as 0.025, 0.024, and 0.061 µmol L?1, respectively. The interfering effect of some anions and cations was also tested. The method was applied to the determination of CS CTAB in conditioner shampoo and water samples.  相似文献   
25.
The effect of river runoff over the northern Indian Ocean(NIO) especially over the Bay of Bengal(Bo B) has been studied using global Nucleus for European Modelling of the Ocean(NEMO). Two sensitivity experiments, with and without river runoff are conducted and the influence of river runoff on the Indian Ocean hydrography,stratification and circulation features are studied. It is found that due to river runoff surface salinity over the northern Bo B decreases by more than 5 and the East India Coastal Current strengthens by 2 cm/s during post monsoon season. The fresh river water reaches up to 15°N in the Bo B and is the main cause for low salinity there.Sea surface temperature in the northwestern Bo B increases by more than 0.2℃ due to the river runoff in summer monsoon while surface cooling upto 0.2℃ is seen in north-west part of Bo B in winter season. The seasonal mixed layer depth in the region is found to be dependent on river runoff. The effect of vertical shear and Brunt Vaisala frequency on stratification is also examined. The ocean water becomes highly stratified up to 3 035 m due to the river runoff. It is found that the energy required for mixing is high in the northern and coastal Bo B.  相似文献   
26.
Groundwater is a resource under stress. In both developed and developing countries, it has been found that increasing human influence has led to the contamination of the groundwater resource. To understand the magnitude of this problem, a study was conducted in 58 wards within Northern part of Kolkata, India, where water samples from tube wells were collected and analysed on essential drinking water quality parameters, prescribed by WHO. Using Principal component analysis, and Water quality index mapping, the aforementioned results have been interpreted. This has helped to depict that not only is the groundwater unsuitable for drinking, but that the parametric values have a tendency to increase abruptly within the shortest of ranges, indicating urban pollution as the root cause of contamination. This paper shall thus discuss the spatial change in groundwater quality in northern Kolkata and suggest measures which might be implemented to secure a sustainable future for the city.  相似文献   
27.
Operational meteorology is perceived as a fuzzy environment in which information is vaguely defined. The mesoscale processes such as fog, stratus and convection are generally dependent on the topography of the place and has always been difficult to forecast for the meteorologists. The main objective of the present study is to introduce the concept of fuzzy inference system (FIS) in the prediction of fog. This approach uses the concept of a pure fuzzy logic system where the fuzzy rule base consists of a collection of fuzzy IF-THEN rules. The fuzzy inference engine uses these fuzzy IF-THEN rules to determine a mapping from fuzzy sets in the input universe of discourse to fuzzy sets in the output universe of discourse based on fuzzy logic principles. Basic weather elements, which affect weather characteristics of fog, are fuzzified. These are then used in fuzzy weather prediction models based on fuzzy inferences. These models are simulated and the crisp results obtained using developed defuzzification strategies are compared with the actual weather data. The basis of methodology is to construct the fuzzy rule base domain from the available daily current weather observations in winter season over New Delhi. The results reveal that dew point spread and rate of change of dew point spread are the most important parameters for the formation of fog. The results further indicate that fog formation over New Delhi are dominant when (i) dew point is greater then 7°C along with dew point spread between 1 and 3°C. (ii) rate of change of dew point spread must be negative and wind speed should be less than 4 knots. This study presents a technique for predicting the probability of fog over New Delhi for 5–6 hours in advance. The skill score indicates that the performance of FIS is appreciably good. The method is found to be promising for operational application.  相似文献   
28.
An experimental study has been carried out in the Mainz vertical wind tunnel to determine the rate at which NH3 in the presence of CO2 is absorbed by freely suspended water drops. The experimental uptake rates were found to be in good agreement with the rates predicted by the Kronig-Brink convective diffusion model and, for gas concentrations in the ppbv range also by the model in which it is assumed that the absorbed gas is well mixed inside the drop (henceforth called well mixed model). The same conclusion was shown to apply also to the desorption of NH3 from a drop previously exposed to NH3. The latter result is in contrast to the desorption of SO2 which must be described by a model which accounts for the diffusion of the species inside the drop. Comparison of our experimental results with theory show further that the uptake of NH3 in presence of CO2 is significantly overestimated if the slow reaction CO2(aq)+H2OHCO 3 +H+ is neglected in the theoretical computation.  相似文献   
29.
An experimental investigation of the simultaneous absorption of NH3 and SO2 from the ambient atmosphere by freely falling water drops has been carried out in the Mainz vertical wind tunnel. The experimental results were found to be in good agreement with the results derived from computations with the Kronig-Brink convective diffusion model and also with a model which assumes a drop to be well mixed at all times. Encouraged by this agreement, these computation schemes for the uptake of gas by single drops where incorporated in a pollution washout model with realistic SO2, NH3 and CO2 gas profiles. This model allows an entire raindrop size distribution to fall through a gas layer. The results of this plume-model show that the SO2 uptake is strongly dependent on the NH3 concentration in the atmosphere and on the rainrate. We also find that the small drops contribute more towards the washout of these gases. In the case of simultaneous presence of NH3 and SO2, desorption of these gases is negligible.  相似文献   
30.
Coal gasification with CO2 has emerged as a cleaner and more efficient way for the production of energy, and it offers the advantages of CO2 mitigation policies through simultaneous CO2 sequestration. In the present investigation, a feasibility study on the gasification of three low-quality, high-sulphur coals from the north-eastern region (NER) of India in a CO2 atmosphere using thermogravimetric analysis (TGA-DTA) has been made in order to have a better understanding of the physical and chemical characteristics in the process of gasification of coal. Model-free kinetics was applied to determine the activation energies (E) and pre-exponential factors (A) of the CO2 gasification process of the coals. Multivariate non-linear regression analyses were performed to find out the formal mechanisms, kinetic model, and the corresponding kinetic triplets. The results revealed that coal gasification with CO2 mainly occurs in the temperature range of 800°–1400°C and a maximum of at around 1100°C. The reaction mechanisms responsible for CO2 gasification of the coals were observed to be of the ‘nth order with autocatalysis (CnB)’ and ‘nth order (Fn) mechanism’. The activation energy of the CO2 gasification was found to be in the range 129.07–146.81 kJ mol?1.  相似文献   
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