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981.
1 INTRODUCTION Agricultural use of pesticides has been recognized as one of the important non-point pollution sources in the world, and the pesticide application to agricultural lands has led to large amounts of residues discharged into surface water through runoff (Leonard, 1990). There have been growing concerns about the fate and transport of pesticides in agricultural lands, due to the associated adverse impacts on water environment and human health (Agassi et al., 1995; Ng and Clegg…  相似文献   
982.
Borehole Breakouts in Berea Sandstone Reveal a New Fracture Mechanism   总被引:6,自引:0,他引:6  
— Vertical drilling experiments in high-porosity (22% and 25%) Berea sandstone subjected to critical true triaxial far-field stresses, in which σ H (maximum horizontal stress) >σ v (vertical stress) >σ h (least horizontal stress), revealed a new and non-dilatant failure mechanism that results in thin and very long tabular borehole breakouts that have the appearance of fractures, and which counterintuitively develop orthogonally to σ H . These breakouts are fundamentally different from those induced in crystalline rocks, as well as limestones and medium-porosity Berea sandstone. Breakouts in these rocks are typically dog-eared in shape, a result of dilatant multi-cracking tangential to the hole and subparallel to the maximum far-field horizontal stress σ H , followed by progressive buckling and shearing of detached rock flakes created by the cracks. In the high-porosity sandstone a narrow layer of grains compacted normal to σ H is observed just ahead of the breakout tip. This layer is nearly identical to “compaction bands” observed in the field. It is suggested that when a critical tangential stress concentration is reached along the σ h spring line at the borehole wall, grain bonding breaks down and a compaction band is formed normal to σ H . Debonded loose grains are expelled into the borehole, assisted by the circulating drilling fluid. As the breakout tip advances, the stress concentration ahead of it persists or may even increase, extending the compaction band, which in turn leads to breakout lengthening.  相似文献   
983.
— It is well known that there is no “universal” permeability-porosity relationship valid in all porous media. However, the evolution of permeability and porosity in rocks can be constrained provided that the processes changing the pore space are known. In this paper, we review observations of the relationship between permeability and porosity during rock evolution and interpret them in terms of creation/destruction of effectively and non-effectively conducting pore space. We focus on laboratory processes, namely, plastic compaction of aggregates, elastic-brittle deformation of granular rocks, dilatant and thermal microcracking of dense rocks, chemically driven processes, as a way to approach naturally occurring geological processes. In particular, the chemically driven processes and their corresponding evolution permeability-porosity relationships are discussed in relation to sedimentary rocks diagenesis.  相似文献   
984.
Synthesis of regime observations of groundwater quality at deposits under operation and thermodynamic modeling of the geochemical interaction processes that govern the groundwater chemistry were used to recognize the geochemical causes and processes that bring about an increase in the groundwater fluorine content during water withdrawal accompanied by groundwater level drop and partial drying of the aquifer. The causes of the invalidity of previous forecasts are established.  相似文献   
985.
— Analytical expressions to predict the enhancement of permeability due to stress-induced microcracking in initially low porosity rock are presented. A fracture mechanical microcrack model is employed to derive integrated effective hydraulic variables as a function of stress, which are then used to calculate the evolution of permeability using the statistically-based Dienes model. The model enables determination of permeability enhancement as a function of two loading parameters and three material parameters. Results are in reasonable agreement with experimental measurements and indicate that appreciable increases in permeability can be anticipated during brittle failure. The analytical nature of the model makes it easily incorporatable into numerical models that require quantification of the permeability evolution as a function of stress, for which there is currently no law.  相似文献   
986.
A method of visualizing structures in closed chaotic flows out of homogenous particle distributions is presented in the example of models of a meandering jet. To this end, the system will be leaked or opened up by defining a region of the flow, so that a particle is considered to be escaped if it leaves this region. By applying this method to an ensemble of nonescaped tracers, we are able to characterize mixing processes by visualizing the converging and stretching filamentations (stable and unstable manifolds) in the flow without using additional mathematical tools. The possibility of applying the algorithm to analyze buoy data, and a comparison with the finite time manifolds are discussed.  相似文献   
987.
High spatial resolution U–Pb dates of zircons from two consanguineous ignimbrites of contrasting composition, the high-silica rhyolitic Toconao and the overlying dacitic Atana ignimbrites, erupted from La Pacana caldera, north Chile, are presented in this study. Zircons from Atana and Toconao pumice clasts yield apparent 238U/206Pb ages of 4.11±0.20 Ma and 4.65±0.13 Ma (2σ), respectively. These data combined with previously published geochemical and stratigraphic data, reveal that the two ignimbrites were erupted from a stratified magma chamber. The Atana zircon U–Pb ages closely agree with the eruption age of Atana previously determined by K–Ar dating (4.0±0.1 Ma) and do not support long (>1 Ma) residence times. Xenocrystic zircons were found only in the Toconao bulk ignimbrite, which were probably entrained during eruption and transport. Apparent 238U/206Pb zircon ages of 13 Ma in these xenocrysts provide the first evidence that the onset of felsic magmatism within the Altiplano–Puna ignimbrite province occurred approximately 3 Myr earlier than previously documented.  相似文献   
988.
‘No portion of the American continent is perhaps so rich in wonders as the Yellow Stone’ (F.V. Hayden, September 2, 1874)Discoveries from multi-beam sonar mapping and seismic reflection surveys of the northern, central, and West Thumb basins of Yellowstone Lake provide new insight into the extent of post-collapse volcanism and active hydrothermal processes occurring in a large lake environment above a large magma chamber. Yellowstone Lake has an irregular bottom covered with dozens of features directly related to hydrothermal, tectonic, volcanic, and sedimentary processes. Detailed bathymetric, seismic reflection, and magnetic evidence reveals that rhyolitic lava flows underlie much of Yellowstone Lake and exert fundamental control on lake bathymetry and localization of hydrothermal activity. Many previously unknown features have been identified and include over 250 hydrothermal vents, several very large (>500 m diameter) hydrothermal explosion craters, many small hydrothermal vent craters (1–200 m diameter), domed lacustrine sediments related to hydrothermal activity, elongate fissures cutting post-glacial sediments, siliceous hydrothermal spire structures, sublacustrine landslide deposits, submerged former shorelines, and a recently active graben. Sampling and observations with a submersible remotely operated vehicle confirm and extend our understanding of the identified features. Faults, fissures, hydrothermally inflated domal structures, hydrothermal explosion craters, and sublacustrine landslides constitute potentially significant geologic hazards. Toxic elements derived from hydrothermal processes also may significantly affect the Yellowstone ecosystem.  相似文献   
989.
Statistical analysis of the magnetic fabric of samples from several successive lava flows emplaced under similar conditions can allow determination of the mean flow direction when magnetic fabric data from individual flows do not lead to reliable results. A difference between the obtained flow direction and the present dip direction indicates that the flows were tilted after emplacement. For 2 successive series of flows on the Jeanne d’Arc Peninsula presently NNW dipping, this method shows lava emplacement along a SSW–NNE direction. This indicates a gentle tilting acquired during a period of weak deformation in the whole archipelago. Additionally, the magnetic fabric data allow the reconstruction of the different conditions of emplacement of these two series of lava flows and of formation of the local thick conglomerate interbedded between these series.  相似文献   
990.
Buried Quaternary valleys in Denmark are complex structures filled with various deposits consisting primarily of glacio-lacustrine clay, till and meltwater sand, and gravel. The valleys are important geophysical targets, because they often contain significant volumes of groundwater used for public water supply. About 700 km of buried valley structures have been imaged in the western part of Denmark by the transient electromagnetic (TEM) method. The ability to map the valleys depends primarily on valley geometry, infill architecture and the resistivity of the fill sediments as well as the substratum. One-dimensional (1-D) inversion models of the TEM soundings have been used to construct contour maps of 20 m average resistivities and depth to a good conductor, which provide images for geological interpretation. Images of buried valley morphology, fill properties, infill architecture, such as cut-and-fill structures, valley distribution and valley generations, are characterized for case studies from Hornsyld, Holstebro and the Vonsild/Agtrup areas of Denmark.  相似文献   
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