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21.
High spatial resolution radio continuum and 6.67-GHz methanol spectral line data are presented for methanol masers previously detected by Walsh et al. (1997). Methanol maser and/or radio continuum emission is found in 364 cases towards IRAS -selected regions. For those sources with methanol maser emission, relative positions have been obtained to an accuracy of typically 0.05 arcsec, with absolute positions accurate to around 1 arcsec. Maps of selected sources are provided. The intensity of the maser emission does not seem to depend on the presence of a continuum source. The coincidence of water and methanol maser positions in some regions suggests there is overlap in the requirements for methanol and water maser emission to be observable. However, there is a striking difference between the general proximity of methanol and water masers to both cometary and irregularly shaped ultracompact (UC) H  ii regions, indicating that, in other cases, there must be differing environments conducive to stimulating their emission. We show that the methanol maser is most likely present before an observable UC H  ii region is formed around a massive star and is quickly destroyed as the UC H  ii region evolves. There are 36 out of 97 maser sites that are linearly extended. The hypothesis that the maser emission is found in a circumstellar disc is not inconsistent with these 36 maser sites, but is unlikely. It cannot, however, account for all other maser sites. An alternative model which uses shocks to create the masing spots can more readily reproduce the maser spot distributions.  相似文献   
22.
The newly commissioned University of New South Wales Infrared Fabry–Perot (UNSWIRF) has been used to image molecular hydrogen emission at 2.12 and 2.25 μm in the reflection nebula Parsamyan 18. P 18 is known to exhibit low values of the (1–0)/(2–1) S(1) ratio, suggestive of UV-pumped fluorescence rather than thermal excitation by shocks. Our line ratio mapping reveals the full extent of this fluorescent emission from extended arc-like features, as well as a more concentrated thermal component in regions closer to the central exciting star. We show that the emission morphology, line fluxes and gas density are consistent with the predictions of photodissociation region (PDR) theory. Those regions with the highest intrinsic 1–0 S(1) intensities also tend to show the highest (1–0)/(2–1) S(1) line ratios. Furthermore, variations in the line ratio can be attributed to intrinsic fluctuations in the incident radiation field and/or the gas density, through the self-shielding action of H2. An isolated knot of emission discovered just outside P 18, and having both an unusually high (1–0)/(2–1) S(1) ratio and relative velocity, provides additional evidence for an outflow source associated with P 18.  相似文献   
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Fractionation by ultra-filtration of the dissolved organic material (DOM) in the River Beaulieu, with typical concentrations of dissolved organic carbon (DOC) of 7–8 mg C/l, showed it to be mainly in the nominal molecular weight range of 103–105, with 16–23% of the total DOC in the fraction > 105. The molecular weight distribution of DOM in the more alkaline River Test (average DOC, 2 mg C/l) was similar. In the River Beaulieu water, containing 136–314 βg Fe/l in ‘dissolved’ forms, 90% or more of this Fe was in the nominal molecular weight fraction > 105. Experiments showed that DOM of nominal molecular weight <105 could stabilize Fe(III) in ‘dissolved’ forms. The concentrations of ‘dissolved’ Fe in the river water probably reflect the presence of colloidal Fe stabilized by organic material and this process may influence the apparent molecular weight of the DOM. Dissolved. Mn (100–136 βg/l) in the River Beaulieu was mainly in true solution, probably as Mn(II), with some 30% in forms of molecular weight greater than ca 104.During mi xing in the Beaulieu Estuary, DOC and dissolved Mn behave essentially conservatively. This contrasts with the removal of a large fraction of the dissolved Fe (Holliday and LISS, 1976, Est. Coastal Mar. Sci. 4, 349–353). Concentrations of lattice-held Fe and Mn in suspended particulate material were essentially uniform in the estuary, at 3.2 and 0.012%, respectively, whereas the non-lattice held fractions decreased markedly with increase in salinity. For Mn the decrease was linear and could be most simply accounted for by the physical mixing of riverborne and marine participates, although the possibility that some desorption occurs is not excluded. The non-linear decrease in the concentration of non-lattice held Fe in particulates reflected the more complex situation in which physical mixing is accompanied by removal of material from the ‘dissolved’ fraction.  相似文献   
25.
The first application of the SHETRAN basin‐scale, landslide erosion and sediment yield model is carried out for a major landsliding event in the upper 505 km2 of the Llobregat basin, in the eastern Spanish Pyrenees, in November 1982. The model simulates the spatial distribution of shallow landslides and their sediment yield. Acknowledging uncertainty in the model parameter evaluation, the aim of the application was not to reproduce the observed occurrence of landslides as accurately as possible with one simulation, but to bracket the observed pattern with several simulations representing uncertainty in the key input conditions. Bounds on the landslide simulations were thus determined as a function of uncertainty in the vegetation root cohesion (used in the model factor of safety calculations). The resulting upper bound considerably overestimates the observed pattern (17 000 landslides compared with an observation of around 700), but it reproduces several of the principal clusters in the observed pattern. The lower bound contains around 500 landslides. The sediment yield estimates (2670–14 630 t km?2) are comparable to measurements elsewhere in the Pyrenees for extreme events. The results demonstrate an ability to simulate the basin‐scale landslide response to a rainfall event and the resulting sediment yield. They also highlight the need for further research in setting the uncertainty bounds and in avoiding large overestimates of landslide occurrence arising in part from a current inability to model small‐scale controls for a basin of the given size. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
26.
Spinel lherzolite xenoliths from Mont Briançon, French Massif Central, retain evidence for multiple episodes of melt depletion and melt/fluid infiltration (metasomatism). Evidence for primary melt depletion is still preserved in the co-variation of bulk-rock major elements (MgO 38.7-46.1 wt.%; CaO 0.9-3.6 wt.%), and many samples yield unradiogenic bulk-rock Os isotope ratios (187Os/188Os = 0.11541-0.12626). However, many individual xenoliths contain interstitial glasses and melt inclusions that are not in equilibrium with the major primary minerals. Incompatible trace element mass balance calculations demonstrate that metasomatic components comprise a significant proportion of the bulk-rock budget for these elements in some rocks, ranging to as much as 25% of Nd and 40% of Sr Critically, for Re-Os geochronology, melt/fluid infiltration is accompanied by the mobilisation of sulfide. Consequently, bulk-rock isotope measurements, whether using lithophile (e.g. Rb-Sr, Sm-Nd) or siderophile (Re-Os) based isotope systems, may only yield a perturbed and/or homogenised average of these multiple events.Osmium mass balance calculations demonstrate that bulk-rock Os in peridotite is dominated by contributions from two populations of sulfide grain: (i) interstitial, metasomatic sulfide with low [Os] and radiogenic 187Os/188Os, and (ii) primary sulfides with high [Os] and unradiogenic 187Os/188Os, which have been preserved within host silicate grains and shielded from interaction with transient melts and fluid. The latter can account for >97% of bulk-rock Os and preserve geochronological information of the melt from which they originally precipitated as an immiscible liquid. The Re-depletion model ages of individual primary sulfide grains preserve evidence for melt depletion beneath the Massif Central from at least 1.8 Gyr ago despite the more recent metasomatic event(s).  相似文献   
27.
Thermodynamic mixing properties and subsolidus phase relations of the rhombohedral carbonate system, (1 − x) · CaCO3 − x · MgCO3, were modelled in the temperature range of 623-2023 K with static structure energy calculations based on well-parameterised empirical interatomic potentials. Relaxed static structure energies of a large set of randomly varied structures in a 4 × 4 × 1 supercell of calcite (a = 19.952 Å, c = 17.061 Å) were calculated with the General Utility Lattice Program (GULP). These energies were cluster expanded in a basis set of 12 pair-wise effective interactions. Temperature-dependent enthalpies of mixing were calculated by the Monte Carlo method. Free energies of mixing were obtained by thermodynamic integration of the Monte Carlo results. The calculated phase diagram is in good agreement with experimental phase boundaries.  相似文献   
28.
We determined the abundances and enantiomeric compositions of amino acids in Sutter's Mill fragment #2 (designated SM2) recovered prior to heavy rains that fell April 25–26, 2012, and two other meteorite fragments, SM12 and SM51, that were recovered postrain. We also determined the abundance, enantiomeric, and isotopic compositions of amino acids in soil from the recovery site of fragment SM51. The three meteorite stones experienced terrestrial amino acid contamination, as evidenced by the low d/l ratios of several proteinogenic amino acids. The d/l ratios were higher in SM2 than in SM12 and SM51, consistent with rain introducing additional l‐ amino acid contaminants to SM12 and SM51. Higher percentages of glycine, β‐alanine, and γ‐amino‐n‐butyric acid were observed in free form in SM2 and SM51 compared with the soil, suggesting that these free amino acids may be indigenous. Trace levels of d +l‐ β‐aminoisobutyric acid (β‐AIB) observed in all three meteorites are not easily explained as terrestrial contamination, as β‐AIB is rare on Earth and was not detected in the soil. Bulk carbon and nitrogen and isotopic ratios of the SM samples and the soil also indicate terrestrial contamination, as does compound‐specific isotopic analysis of the amino acids in the soil. The amino acid abundances in SM2, the most pristine SM meteorite analyzed here, are approximately 20‐fold lower than in the Murchison CM2 carbonaceous chondrite. This may be due to thermal metamorphism in the Sutter's Mill parent body at temperatures greater than observed for other aqueously altered CM2 meteorites.  相似文献   
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30.
Recent near-IR imaging of the Orion molecular cloud has revealed a complex of dense bullets, visible as [FeII] emitting HH-objects at the tips of H2 wakes, ejected explosively from the cloud core. Having resolved individual bow-shock structures for the first time in this bright source, we have observed [FeII] 1.644µm velocity profiles of selected bullets and H2 1-0 S(1), 2.122µm velocity profiles for a series of positions along and across the corresponding bow-shock wakes. We present observed profiles for the bullet M42 HH1 and its associated wake and compare with theoretical bow-shock models.  相似文献   
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