Iron-sulfide and trace element behaviour in sediments of Coombabah Lake, southern Moreton Bay (Australia)     

Burton ED  Sullivan LA  Bush RT  Powell B 《Marine pollution bulletin》2008,56(7):1353-1358

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Role of a rheophyte in bench development on a sand‐bed river in southeast Australia     

Wayne Erskine  Anita Chalmers  Annabelle Keene  Michael Cheetham  Richard Bush 《地球表面变化过程与地形》2009,34(7):941-953

Casuarina cunninghamiana Miq. is an important rheophytic tree in New South Wales, Australia because it is fast growing and can tolerate flood disturbance. Widden Brook is an active sand‐bed stream that has widened substantially since initial European settlement in the early 1800s and is characterized by high flood variability and multi‐decadal periods of alternating high and low flood frequency, called flood‐ and drought‐dominated regimes. Channel contraction by bench formation is currently occurring. Conversion of coarse‐grained point bars to benches is an important process of channel contraction. When point bars grow to a height where suspended sediment is first deposited to thicknesses of at least 50 mm by sub‐bankfull floods, rapid establishment of C. cunninghamiana occurs. As the trees grow they partially block bankside flows, thereby locally reducing flow velocity and inducing further deposition on the benches. Such synergistic relationships between bar height and inundation, fine‐grained sediment deposition, tree establishment and the development of a bankside low current velocity zone are fundamental for bench development. Size‐class frequency data demonstrate that C. cunninghamiana on the benches consists of pure even‐aged stands with most trees clustering near the average diameter. Two benches have similar size class frequency distributions but a third has significantly smaller trees. Recruitment on benches is episodic, may occur in areas open to grazing and is dependent on favourable conditions that allow tree survival. These favourable conditions include high seed availability, low levels of competition, deposition of fine sediments and adequate moisture for tree growth. Although C. cunninghamiana germinates on bars, seedlings are eliminated by prolonged inundation or flood scour and do not reach maturity. Recurring catastrophic floods or a sequence of large floods in rapid succession episodically destroy benches by substantial channel widening and initiate a new phase of bar and bench development. A conceptual model of the conversion of point bars to benches by thick mud deposition and C. cunninghamiana recruitment has been developed for sand‐bed streams draining similar sandstone catchments. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Schwertmannite transformation to goethite via the Fe(II) pathway: Reaction rates and implications for iron-sulfide formation   总被引：1，自引：0，他引：1  

E.D. Burton  R.T. Bush  D.R.G. Mitchell 《Geochimica et cosmochimica acta》2008,72(18):4551-4564

Schwertmannite (Fe₈O₈(OH)₆SO₄) is a common Fe(III)-oxyhydroxysulfate mineral in acid-sulfate systems, where its formation and fate strongly influence water quality. The present study examines transformation of schwertmannite to goethite (FeOOH), as catalyzed by interactions with Fe(II) in anoxic aquatic environments. This study also evaluates the role of the Fe(II) pathway in influencing the formation of iron-sulfide minerals in such environments. At pH > 5, the rates of Fe(II)-catalyzed schwertmannite transformation were several orders of magnitude faster than transformation in the absence of Fe(II). Complete transformation of schwertmannite occurred within only 3-5 h at pH > 6 and Fe(II)_(aq) ? 5 mmol L⁻¹. Model calculations indicate that the Fe(II)-catalyzed transformation of schwertmannite to goethite greatly decreases the reactivity of the Fe(III) pool, thereby favoring SO₄-reduction and facilitating the formation of iron-sulfide minerals (particularly mackinawite, tetragonal FeS). Examination of in situ sediment geochemistry in an acid-sulfate system revealed that the rapid Fe(II)-catalyzed transformation was consistent with an abrupt shift from an acidic Fe(III)-reducing regime with abundant schwertmannite near the sediment surface, to a near-neutral mackinawite-forming regime where goethite was dominant. This study demonstrates that the Fe(II) pathway exerts a major influence on schwertmannite transformation and iron-sulfide formation in anoxic acid-sulfate systems. These findings have important implications for understanding acidity dynamics and trace element mobility in such systems.  相似文献   

The Solar Oscillations Investigation - Michelson Doppler Imager     

P. H. Scherrer  R. S. Bogart  R. I. Bush  J. T. Hoeksema  A. G. Kosovichev  J. Schou  W. Rosenberg  L. Springer  T. D. Tarbell  A. Title  C. J. Wolfson  I. Zayer  The MDI Engineering Team 《Solar physics》1995,162(1-2):129-188

The Solar Oscillations Investigation (SOI) uses the Michelson Doppler Imager (MDI) instrument to probe the interior of the Sun by measuring the photospheric manifestations of solar oscillations. Characteristics of the modes reveal the static and dynamic properties of the convection zone and core. Knowledge of these properties will improve our understanding of the solar cycle and of stellar evolution. Other photospheric observations will contribute to our knowledge of the solar magnetic field and surface motions. The investigation consists of coordinated efforts by several teams pursuing specific scientific objectives.The instrument images the Sun on a 1024² CCD camera through a series of increasingly narrow spectral filters. The final elements, a pair of tunable Michelson interferometers, enable MDI to record filtergrams with a FWHM bandwidth of 94 m. Normally 20 images centered at 5 wavelengths near the Ni I 6768 spectral line are recorded each minute. MDI calculates velocity and continuum intensity from the filtergrams with a resolution of 4 over the whole disk. An extensive calibration program has verified the end-to-end performance of the instrument.To provide continuous observations of the longest-lived modes that reveal the internal structure of the Sun, a carefully-selected set of spatial averages are computed and downlinked at all times. About half the time MDI will also be able to downlink complete velocity and intensity images each minute. This high rate telemetry (HRT) coverage is available for at least a continuous 60-day interval each year and for 8 hours each day during the rest of the year. During the 8-hour HRT intervals, 10 of the exposures each minute can be programmed for other observations, such as measurements in MDI's higher resolution (1.25) field centered about 160 north of the equator; meanwhile, the continuous structure program proceeds during the other half minute. Several times each day, polarizers will be inserted to measure the line-of-sight magnetic field.MDI operations will be scheduled well in advance and will vary only during the daily 8-hour campaigns. Quick-look and summary data, including magnetograms, will be processed immediately. Most high-rate data will be delivered only by mail to the SOI Science Support Center (SSSC) at Stanford, where a processing pipeline will produce 3 Terabytes of calibrated data products each year. These data products will be analyzed using the SSSC and the distributed resources of the co-investigators. The data will be available for collaborative investigations.The MDI Engineering Team leaders include: D. Akin, B. Carvalho, R. Chevalier, D. Duncan, C. Edwards, N. Katz, M. Levay, R. Lindgren, D. Mathur, S. Morrison, T. Pope, R. Rehse, and D. Torgerson.  相似文献   

STRUCTURE AND ROTATION OF THE SOLAR INTERIOR: INITIAL RESULTS FROM THE MDI MEDIUM-L PROGRAM     

Kosovichev  A. G.  Schou  J.  Scherrer  P. H.  Bogart  R. S.  Bush  R. I.  Hoeksema  J. T.  Aloise  J.  Bacon  L.  Burnette  A.  De Forest  C.  Giles  P. M.  Leibrand  K.  Nigam  R.  Rubin  M.  Scott  K.  Williams  S. D.  Basu  Sarbani  Christensen-dalsgaard  J.  DÄppen  W.  Duvall  T. L.  Howe  R.  Thompson  M. J.  Gough  D. O.  Sekii  T.  Toomre  J.  Tarbell  T. D.  Title  A. M.  Mathur  D.  Morrison  M.  Saba  J. L. R.  Wolfson  C. J.  Zayer  I.  Milford  P. N. 《Solar physics》1997,170(1):43-61

The medium-l program of the Michelson Doppler Imager instrument on board SOHO provides continuous observations of oscillation modes of angular degree, l, from 0 to 300. The data for the program are partly processed on board because only about 3% of MDI observations can be transmitted continuously to the ground. The on-board data processing, the main component of which is Gaussian-weighted binning, has been optimized to reduce the negative influence of spatial aliasing of the high-degree oscillation modes. The data processing is completed in a data analysis pipeline at the SOI Stanford Support Center to determine the mean multiplet frequencies and splitting coefficients. The initial results show that the noise in the medium-l oscillation power spectrum is substantially lower than in ground-based measurements. This enables us to detect lower amplitude modes and, thus, to extend the range of measured mode frequencies. This is important for inferring the Sun's internal structure and rotation. The MDI observations also reveal the asymmetry of oscillation spectral lines. The line asymmetries agree with the theory of mode excitation by acoustic sources localized in the upper convective boundary layer. The sound-speed profile inferred from the mean frequencies gives evidence for a sharp variation at the edge of the energy-generating core. The results also confirm the previous finding by the GONG (Gough et al., 1996) that, in a thin layer just beneath the convection zone, helium appears to be less abundant than predicted by theory. Inverting the multiplet frequency splittings from MDI, we detect significant rotational shear in this thin layer. This layer is likely to be the place where the solar dynamo operates. In order to understand how the Sun works, it is extremely important to observe the evolution of this transition layer throughout the 11-year activity cycle.  相似文献   

Magnetic Field Vector Retrieval With the Helioseismic and Magnetic Imager     

J. M. Borrero  S. Tomczyk  A. Norton  T. Darnell  J. Schou  P. Scherrer  R. Bush  Y. Liu 《Solar physics》2007,240(1):177-196

We investigate the accuracy to which we can retrieve the solar photospheric magnetic field vector using the Helioseismic and Magnetic Imager (HMI) that will fly onboard of the Solar Dynamics Observatory by inverting simulated HMI profiles. The simulated profiles realistically take into account the effects of the photon noise, limited spectral resolution, instrumental polarization modulation, solar p modes, and temporal averaging. The accuracy of the determination of the magnetic field vector is studied by considering the different operational modes of the instrument.  相似文献   

Abundance and fractionation of Al,Fe and trace metals following tidal inundation of a tropical acid sulfate soil     

Scott G. Johnston  Edward D. Burton  Richard T. Bush  Annabelle F. Keene  Leigh A. Sullivan  Douglas Smith  Angus E. McElnea  Col R. Ahern  Bernard Powell 《Applied Geochemistry》2010

Tidal inundation was restored to a severely degraded tropical acid sulfate soil landscape and subsequent changes in the abundance and fractionation of Al, Fe and selected trace metals were investigated. After 5 a of regular tidal inundation there were large decreases in water-soluble and exchangeable Al fractions within former sulfuric horizons. This was strongly associated with decreased soil acidity and increases in pH, suggesting pH-dependent immobilisation of Al via precipitation as poorly soluble phases. The water-soluble fractions of Fe, Zn, Ni and Mn also decreased. However, there was substantial enrichment (2–5×) of the reactive Fe fraction (Fe_R; 1 M HCl extractable) near the soil surface, plus a closely corresponding enrichment of 1 M HCl extractable Cr, Zn, Ni and Mn. Surficial accumulations of Fe(III) minerals in the inter-tidal zone were poorly crystalline (up to 38% Fe_R) and comprised mainly of schwertmannite (Fe₈O₈(OH)₆SO₄) with minor quantities of goethite (α-FeOOH) and lepidocrocite (γ-FeOOH). These Fe (III) mineral accumulations provide an effective substrate for the adsorption/co-precipitation and accumulation of trace metals. Arsenic displayed contrary behaviour to trace metals with peak concentrations (∼60 μg g⁻¹) near the redox minima. Changes in the abundance and fractionation of the various metals can be primarily explained by the shift in the geochemical regime from oxic–acidic to reducing-circumneutral conditions, combined with the enrichment of reactive Fe near the soil surface. Whilst increasing sequestration of trace metals via sulfidisation is likely to occur over the long-term, the current abundance of reactive Fe near the sediment–water interface favours a dynamic environment with respect to metals in the tidally inundated areas.  相似文献   

Fire and drought as drivers of early Holocene tree line changes in the Peruvian Andes     

Dunia H. Urrego  Brittany A. Niccum  Christopher F. La Drew  Miles R. Silman  Mark B. Bush 《第四纪科学杂志》2011,26(1):28-36

Three pollen and charcoal records from three lakes lying at 3400 m elevation in southern Peru provided a record of landscape change spanning the last ca.18 000 cal. a BP. The tree line lay close to the site between ca. 16 000 and 12 000 cal. a BP, with Polylepis woodlands growing near the lakes. Progressively drying conditions led to increased fire after 12 000 cal. a BP, coinciding with a decline in Polylepis cover and Andean forest relicts as puna grasslands expanded. A strong decrease in the rate of sediment deposition between ca. 12 000 and ca. 4400 cal. a BP was interpreted to indicate the presence of sedimentary hiatuses. With the return of wet conditions after 4400 cal. a BP, forests did not reassemble around the lakes. Instead, fire‐maintained grasslands dominated the landscape. Humans probably induced the intensified fire activity during the late Holocene and thereby deflected local successions. The modern fragmented landscape, with Polylepsis woodlands existing in fire‐resistant pockets above the general limit of the Andean tree line, resulted from the intensification of human land use practices during the last 4400 cal. a BP. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Vegetation and climate change on the Bolivian Altiplano between 108,000 and 18,000 yr ago   总被引：1，自引：0，他引：1  

Alex Chepstow-Lusty  Mark B. Bush  Paul A. Baker  Sherilyn C. Fritz  James Aronson 《Quaternary Research》2005,63(1):90-98

A 90,000-yr record of environmental change before 18,000 cal yr B.P. has been constructed using pollen analyses from a sediment core obtained from Salar de Uyuni (3653 m above sea level) on the Bolivian Altiplano. The sequence consists of alternating mud and salt, which reflect shifts between wet and dry periods. Low abundances of aquatic species between 108,000 and 50,000 yr ago (such as Myriophyllum and Isoëtes) and marked fluctuations in Pediastrum suggest generally dry conditions dominated by saltpans. Between 50,000 yr ago and 36,000 cal yr B.P., lacustrine sediments become increasingly dominant. The transition to the formation of paleolake “Minchin” begins with marked rises in Isoëtes and Myriophyllum, suggesting a lake of moderate depth. Similarly, between 36,000 and 26,000 cal yr B.P., the transition to paleolake Tauca is also initiated by rises in Isoëtes and Myriophyllum; the sustained presence of Isoëtes indicates the development of flooded littoral communities associated with a lake maintained at a higher water level. Polylepis tarapacana-dominated communities were probably an important component of the Altiplano terrestrial vegetation during much of the Last Glacial Maximum (LGM) and previous wet phases.  相似文献   

Orbital forcing signal in sediments of two Amazonianlakes     

M.B. Bush  M.C. Miller  P.E. De Oliveira  P.A. Colinvaux 《Journal of Paleolimnology》2002,27(3):341-352

Paleolimnological data from two ancient lakes at 0° latitudein Amazonia indicate that past lake level changes reflect precessional (19,000to 22,000 years) variations in insolation over the last 170,000 years. Waterlevel in Lakes Pata and Verde, Brazil, is determined by the ratio ofprecipitation:leakage. Times of low lake level are indicated in sediments byoxidized clays, evidence of algal blooms and high K⁺ concentrations.Peak K⁺ values are attributed to biogenic concentration when thelake was reduced to a shallow, productive pool. Low lake phases correlate withmaximum insolation during the dry season (June–July–August). Thusthe last glacial maximum 18,000 to 22,000 yr BP was a wet time in northernAmazonia, and the driest period of the last 170,000 years was from 35,000 to27,000 yr BP. These results from near the equator do not imply thatprecipitation changed synchronously across Amazonia, because geographiclocations throughout the vast watershed were undoubtedly influenced by localmoisture sources.  相似文献