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21.
M. Z. Stout M. L. Crawford E. D. Ghent 《Contributions to Mineralogy and Petrology》1986,92(2):236-247
Metamorphosed pelitic rocks from Mica Creek, British Columbia contain sillimanite, kyanite with minor fibrolite and andalusite-bearing quartz pods. Mineral equilibria were used to infer peak P-T conditions and fluid compositions in equilibrium with the solid phases. Fluid inclusions in three schist samples appear to be good indicators of conditions affecting those rocks during and after peak metamorphic conditions. In samples from two localities, fluid inclusions from schist and quartz-rich segregations have densities appropriate to the peak metamorphic conditions. The observed compositions for these fluids (low salinity with 12 mole % dissolved CO2) agree with calculated
values of 0.84 to 0.85, based upon paragonite-quartz-albite-Al2SiO5 equilibria. The fluids unmixed as the schists were uplifted and cooled; fluid inclusions trapped during this stage outline a solvus in the CO2-H2O-NaCl system. A later influx of fluids containing CH4 and N2 accompanied formation of andalusite-bearing plagioclaserich segregations. The restricted association of andalusite-bearing pods and low density fluids suggest a localized but pervasive fluid influx during uplift. Preservation of high density fluid inclusions during uplift and erosion, coupled with evidence for unmixing of H2O- and CO2-rich fluids on the solvus, provide constraints on the P-T uplift path. 相似文献
22.
Mike Hapgood and Ian Crawford assess the relevance of the BNSC UKSEWG Report for the Royal Astronomical Society. 相似文献
23.
High-Mg potassic rocks from Taiwan: implications for the genesis of orogenic potassic lavas 总被引:15,自引:0,他引:15
Sun-Lin Chung Kuo-Lung Wang Anthony J. Crawford V. S. Kamenetsky Cheng-Hong Chen Ching-Ying Lan Chang-Hwa Chen 《Lithos》2001,59(4):153-170
Taiwan is an active mountain belt formed by oblique collision between the Luzon arc and the Asian continent. Regardless of the ongoing collision in central and southern Taiwan, a post-collisional extension regime has developed since the Plio–Pleistocene in the northern part of this orogen, and led to generation of the Northern Taiwan Volcanic Zone. Emplaced at 0.2 Ma in the southwest of the Volcanic Zone, lavas from the Tsaolingshan volcano are highly magnesian (MgO≈15 wt.%) and potassic (K2O≈5 wt.%; K2O/Na2O≈1.6–3.0). Whereas these basic rocks (SiO2≈48 wt.%) have relatively low Al2O3≈12 wt.%, total Fe2O3≈7.5 wt.% and CaO≈7.2 wt.%, they are extremely enriched in large ion lithophile elements (LILE, e.g. Cs, Rb, Ba, Th and U). The Rb and Cs abundances, >1000 and 120 ppm, respectively, are among the highest known from terrestrial rocks. In addition, these rocks are enriched in light rare earth elements (LREE), depleted in high field strength elements (HFSE), and display a positive Pb spike in the primitive mantle-normalized variation diagram. Their REE distribution patterns mark with slight Eu negative anomalies (Eu/Eu*≈0.90–0.84), and Sr and Nd isotope ratios are uniform (87Sr/86Sr≈0.70540–0.70551; 143Nd/144Nd≈0.51268–0.51259). Olivine, the major phenocryst phase, shows high Fo contents (90.4±1.8; 1σ deviation), which are in agreement with the whole rock Mg-values (83–80). Spinel inclusions in olivine are characterized by high Cr/Cr+Al ratios (0.94–0.82) and have compositions similar to those from boninites that originate from highly refractory peridotites. Such petrochemical characteristics are comparable to the Group I ultrapotassic rocks defined by Foley et al. [Earth-Sci. Rev. 24 (1987) 81], such as orogenic lamproites from central Italy, Span and Tibet. We therefore suggest that the Tsaolingshan lavas resulted from a phlogopite-bearing harzburgitic source in the lithospheric mantle that underwent a recent metasomatism by the nearby Ryukyu subduction zone processes. The lavas exhibit unique incompatible trace element ratios, with Rb/Cs≈8, Ba/Rb≈1, Ce/Pb≈2, Th/U≈1 and Nb/U≈0.8, which are significantly lower than the continental crust values and those of most mantle-derived magmas. Nonmagmatic enrichment in the mantle source is therefore required. Based on published experimental data, two subduction-related metasomatic components, i.e., slab-released hydrous fluid and subducted sediment, are proposed, and the former is considered to be more pervasive for causing the extraordinary trace element ratios observed. Our observations lend support to the notion that dehydration from subducting slabs at convergent margins, as a continuing process through geologic time, can account for the fractionation of these elemental pairs between the Earth's crust and mantle. 相似文献
24.
Flow distortion is a universal consideration in the measurement of wind. Usually the distortion results from deflection of the flow by the support. Instruments mounted on airplanes, however, experience an additional deflection associated with lift, which changes rapidly and continuously during flight. In front of the airplane, this deflection appears as upwash. Characteristic upwash contamination ranges from 0.5 to 2.5 m s-1, depending on wing loading, flight speed, and forward distance from the wing to the measurement location. On pressure-radome installations the distance from the wing is usually small and the potential for upwash contamination large. Sensors mounted at the end of long probes attached to smaller airplanes with light wing loading are less susceptible to upwash contamination. Since wing loading also depends on the local vertical wind velocity the upwash velocity is directly correlated with vertical wind velocity. Generally, empirical corrections are derived from flight tests. We develop a simple method from principles of aerodynamics which explains these corrections in terms of upwash. The applicability of our approach to moderate upwash is demonstrated with data collected from the NOAA Long-EZ research airplane. More severe upwash conditions require a more sophisticated correction beyond the scope of this paper, but basically derived from the same principles.Oak Ridge Associated Universities, assigned to NOAA/ATDD 相似文献
25.
Using the correspondence principle of viscoelasticity the Displacement Discontinuity Method has been extended to model the rate-dependent behaviour of a jointed rock mass. The intact rock is assumed to behave as a linear viscoelastic material while, in general, a non-linear rate-dependent behaviour of the rock joints can be accounted for. A number of numerical examples are presented which illustrate the accuracy and potential of the method for analysing complex engineering problems. 相似文献
26.
G. V. Gibbs D. F. Cox T. D. Crawford M. B. Boisen Jr M. Lim 《Physics and Chemistry of Minerals》2002,29(5):307-318
The electron localization function, η, evaluated for first-principles geometry optimized model structures generated for quartz and coesite, reveals that the oxide anions are coordinated by two hemispherically shaped η-isosurfaces located along each of the SiO bond vectors comprising the SiOSi angles. With one exception, they are also coordinated by larger banana-shaped isosurfaces oriented perpendicular to the plane centered in the vicinity of the apex of each angle. The hemispherical isosurfaces, ascribed to domains of localized bond-pair electrons, are centered ~0.70 Å along the bond vectors from the oxide anions and the banana-shaped isosurfaces, ascribed to domains of localized nonbonding lone-pair electrons, are centered ~0.60 Å from the apex of the angle. The oxide anion comprising the straight SiOSi angle in coesite is the one exception in that the banana-shaped isosurface is missing; however, it is coordinated by two hemispherically shaped isosurfaces that lie along the bond vectors. In the case of a first-principles model structure generated for stishovite, the oxide anion is coordinated by five hemispherically shaped η-isosurfaces, one located along each of the three SiO bond vectors (ascribed to domains of bonding-electron pairs) that are linked to the anion with the remaining two (ascribed to domains of nonbonding-electron pairs) located on opposite sides of the plane defined by three vectors, each isosurface at a distance of ~0.5 Å from the anion. The distribution of the five isosurfaces is in a one-to-one correspondence with the distribution of the maxima displayed by experimental Δρ and theoretical ??2ρ maps. Isosurface η maps calculated for quartz and the (HO) 3 SiOSi(OH) 3 molecule also exhibit maxima that correspond with the (3,?3) maxima displayed by distributions of ??2ρ. Deformation maps observed for the SiOSi bridges for the silica polymorphs and a number of silicates are similar to that calculated for the molecule but, for the majority, the maxima ascribed to lone-pair features are absent. The domains of localized nonbonding-electron pair coordinating the oxide anions of quartz and coesite provide a basis for explaining the flexibility and the wide range of the SiOSi angles exhibited by the silica polymorphs with four-coordinate Si. They also provide a basis for explaining why the SiO bond length in coesite decreases with increasing angle. As found in studies of the interactions of solute molecules with a solvent, a mapping of η-isosurfaces for geometry-optimized silicates is expected to become a powerful tool for deducing potential sites of electrophilic attack and reactivity for Earth materials. The positions of the features ascribed to the lone pairs in coesite correspond with the positions of the H atoms recently reported for an H-doped coesite crystal. 相似文献
27.
Andrew Ball and Ian Crawford report on NASA's planning for a return to the Moon, with some thoughts on opportunities open to the UK. 相似文献
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