Permeability of JSC-1A: A lunar soil simulant     

Casey Q. LaMarche  Jennifer Sinclair Curtis 《Icarus》2011,212(1):383-389

The permeability of lunar soil simulant, JSC-1A, is measured over a range of bulk densities from 1550 to 2000 kg m⁻³. The corresponding viscous flow permeability is 1 × 10⁻¹² m² to 6.1 × 10⁻¹² m² for this bulk density range. Implications of these values on the contamination of regolith by rockets, on barrier/enhancement to bulk flow of ice, and on cratering are discussed. Although the particle size and shape distribution of the JSC-1A are extremely wide, the permeability measurements agree surprisingly well with the Carman-Kozeny equation. The results provide evidence that the Carman-Kozeny model could be applicable to other naturally occurring soils if effective soil properties are considered.  相似文献   

Residence times for protons bound to three oxygen sites in the AlO₄Al₁₂(OH)₂₄(H₂O)₁₂ polyoxocation     

Jacqueline R. Houston  William H. Casey 《Geochimica et cosmochimica acta》2006,70(7):1636-1643

Although, the kinetic reactivity of a mineral surface is determined, in part, by the rates of exchange of surface-bound oxygens and protons with bulk solution, there are no elementary rate data for minerals. However, such kinetic measurements can be made on dissolved polynuclear clusters, and here we report lifetimes for protons bound to three oxygen sites on the AlO₄Al₁₂(OH)₂₄(H₂O)₁₂⁷⁺ (Al₁₃) molecule, which is a model for aluminum-hydroxide solids in water. Proton lifetimes were measured using ¹H NMR at pH ∼ 5 in both aqueous and mixed solvents. The ¹H NMR peak for protons on bound waters (η-H₂O) lies near 8 ppm in a 2.5:1 mixture of H₂O/acetone-d₆ and broadens over the temperature range −20 to −5 °C. Extrapolated to 298 K, the lifetime of a proton on a η-H₂O is τ²⁹⁸ ∼ 0.0002 s, which is surprisingly close to the lifetime of an oxygen in the η-H₂O (∼0.0009 s), but in the same general range as lifetimes for protons on fully protonated monomer ions of trivalent metals (e.g., Al(H₂O)₆³⁺). The lifetime is reduced somewhat by acid addition, indicating that there is a contribution from the partly deprotonated Al₁₃ molecule in addition to the fully protonated Al₁₃ at self-buffered pH conditions. Proton lifetimes on the two distinct sets of hydroxyls bridging two Al(III) (μ₂-OH) differ substantially and are much shorter than the lifetime of an oxygen at these sites. The average lifetimes for hydroxyl protons were measured in a 2:1 mixture of H₂O/dmso-d₆ over the temperature range 3.7-95.2 °C. The lifetime of a hydrogen on one of the μ₂-OH was also measured in D₂O. The τ²⁹⁸ values are ∼0.013 and ∼0.2 s in the H₂O/dmso-d₆ solution and the τ²⁹⁸ value for the μ₂-OH detectable in D₂O is τ²⁹⁸ ∼ 0.013 s. The ¹H NMR peak for the more reactive μ₂-OH broadens slightly with acid addition, indicating a contribution from an exchange pathway that involves a proton or hydronium ion. These data indicate that surface protons on minerals will equilibrate with near-surface waters on the diffusional time scale.  相似文献   

Environmental dependence of active galactic nuclei activity in the supercluster A901/2     

R. Gilmour  M. E. Gray  O. Almaini  P. Best  C. Wolf  K. Meisenheimer  C. Papovich  E. Bell 《Monthly notices of the Royal Astronomical Society》2007,380(4):1467-1487

We present XMM data for the supercluster A901/2, at   z ∼ 0.17  , which is combined with deep imaging and 17-band photometric redshifts (from the COMBO-17 survey), two degree field (2dF) spectra and Spitzer 24 μm data, to identify active galactic nuclei (AGN) in the supercluster. The 90 ksec XMM image contains 139 point sources, of which 11 are identified as supercluster AGN with   L _{X(0.5−7.5 keV)} > 1.7 × 10⁴¹ erg cm⁻² s⁻¹  . The host galaxies have   M _R < −20  and only two of eight sources with spectra could have been identified as AGN by the detected optical emission lines. Using a large sample of 795 supercluster galaxies, we define control samples of massive galaxies with no detected AGN. The local environments of the AGN and control samples differ at ≳98 per cent significance. The AGN host galaxies lie predominantly in areas of moderate projected galaxy density and with more local blue galaxies than the control sample, with the exception of one very bright type I AGN very near the centre of a cluster. These environments are similar to, but not limited to, cluster outskirts and blue groups. Despite the large number of potential host galaxies, no AGN are found in regions with the highest galaxy density (excluding some cluster cores where emission from the intra-cluster medium obscures moderate luminosity AGN). AGN are also absent from the areas with lowest galaxy density. We conclude that the prevalence of cluster AGN is linked to their environment.  相似文献   

Cooling-induced fractionation of mantle Li isotopes from the ultraslow-spreading Gakkel Ridge     

Yongjun Gao  Jonathan E. Snow  John F. Casey  Junbao Yu 《Earth and Planetary Science Letters》2011,301(1-2):231-240

Li isotopic compositions of magmatic rocks have gained considerable attention recently as probes of mantle-scale processes. However, the concentrations and isotopic composition of Li in mantle minerals from mid-ocean ridges remain relatively unconstrained. This is largely because of the general presence of seawater alteration in abyssal peridotites. Lithium elemental and isotopic compositions for mineral separates of coexisting olivine, clinopyroxene, orthopyroxene and bulk rocks of serpentine-free Gakkel Ridge peridotites were investigated. Bulk rocks have Li contents of 1.6 to 2.7 ppm and δ⁷Li values of 3 to 5‰, which fall within the range of reported normal pristine “MORB mantle” values. Lithium concentrations vary in the order cpx (2.1–4.7 ppm) > opx (0.9–1.7 ppm) ≥ olivine (0.4–0.9 ppm), the opposite found in “equilibrated” mantle peridotite xenoliths (Seitz and Woodland, 2000). The Li isotopic compositions indicate a systematic mineral variation with δ⁷Li_olivine (7.14‰–15.09‰) > δ⁷Li_opx (1.81‰–3.66‰) > δ⁷Li_cpx (?2.43‰ ? ?0.39‰). The δ⁷Li values of cpx are negatively correlated with their Li concentrations with the lightest value for the most enriched cpx grains. There is a first order negative linear correlation between Δ_{olivine–cpx} (δ⁷Li_olivine ? δ⁷Li_cpx) and ^ol/cpxD (Li_olivine/Li_cpx).Numerical simulations indicate that the observed systematic inter-mineral variations of Li concentrations and isotopic compositions could be explained by a cooling driven diffusive redistribution between minerals in a closed system if there is a temperature dependent partitioning of Li between olivine and clinopyroxene. The studied Gakkel Ridge abyssal peridotites may alternatively have cooled under a variable cooling rate with a rapid cooling before the Li system was closed, which is less likely given the tectonic setting. Our calculations confirm that Li systematics in minerals, especially in coexisting mineral phases could potentially be used as a mantle geospeedometer, even for slowly cooled mantle rocks.  相似文献   

Hydroclimate risk to economic growth in sub-Saharan Africa     

Casey Brown  Robyn Meeks  Kenneth Hunu  Winston Yu 《Climatic change》2011,106(4):621-647

In order to plan strategies for adaptation to climate change, the current effects of climate on economic growth need to be understood. This study reviews evidence of climate effects on economic growth and presents original analysis of the effect in Sub-Saharan Africa (SSA). Case studies from the literature demonstrate that historically, climate has had significant and negative effects on household income, agricultural productivity and economic growth in SSA. This study focuses on the effects hydroclimatic variability on economic growth in the countries of SSA. We utilize a new national level precipitation statistic that incorporates spatial and temporal variability within each country. Country level economic growth statistics are analyzed in panel regressions. Persistent negative precipitation anomalies (drought) are found to be the most significant climate influence on GDP per capita growth. Temperature and precipitation variability show significant effects in some cases. Results imply the consideration of hydroclimatic risks, namely drought, may be the priority concern for adaptation to a changing climate for Sub-Saharan Africa. This conclusion is contrary to the premise of many climate change impact assessments that focus on temperature increases as the primary concern.  相似文献   

利用反向法评价气候变化下的水资源系统风险          下载免费PDF全文

李科  齐晶瑶  王昭阳  冯岩  BROWN Casey 《水科学进展》2013,24(2):184-189

目前多数研究直接将大气环流模式(GCM)获得的气候要素输入水文模型或者系统动力学模型评价气候变化所引起的风险,而忽视了一些重要统计要素的实际影响。针对目前研究存在的问题,利用随机模型产生大量模拟数据并输入到关于水资源系统的系统动力模型,通过评价指数和模拟数据间的统计关系建立"气候响应模型",最终利用多种大气环流模式来进行风险评价。通过A2气候变化情景下36种GCM对美国麻州Quabbin水库未来两个时段2036—2065年和2066—2095年由气候变化引起的风险进行评价。结果表明,在1950—1999年流域净流量年际方差100%～140%范围内,2036—2065年的风险为0.25～0.30,2066—2095年的风险为0.30～0.45。  相似文献   

Paleo-reconstructed net basin supply scenarios and their effect on lake levels in the upper great lakes     

Yonas Ghile  Paul Moody  Casey Brown 《Climatic change》2014,127(2):305-319

Paleo-reconstructed hydrologic records offer the potential to evaluate water resources system performance under conditions that may be more extreme than seen in the historical record. This study uses a stochastic simulation framework consisting of a non-homogeneous Markov chain model (NHMM) to simulate the climate state using Palmer Drought Severity Index (PDSI)-reconstructed data, and K-nearest neighbor (K-NN) to resample observational net basin supply magnitudes for the Great Lakes of North America. The method was applied to generate 500 plausible simulations, each with 100 years of monthly net basin supply for the Upper Great Lakes, to place the observed data into a longer temporal context. The range of net basin supply sequences represents what may have occurred in the past 1,000 years and which can occur in future. The approach was used in evaluation of operational plans for regulation of Lake Superior outflows with implications for lake levels of Superior, Michigan, Huron and Erie, and their interconnecting rivers. The simulations generally preserved the statistics of the observed record while providing new variability statistics. The framework produced a variety of high and low net basin supply sequences that provide a broader estimate of the likelihood of extreme lake levels and their persistence than with the historical record. The method does not rely on parametrically generated net basin supply values unlike parametric stochastic simulation techniques, yet still generates new variability through the incorporation of the paleo-record. The process described here generated new scenarios that are plausible based on the paleo and historic record. The evaluation of Upper Great Lakes regulation plans, subject to these scenarios, was used to evaluate robustness of the regulation plans. While the uncertain future climate cannot be predicted, one can evaluate system performance on a wide range of plausible climate scenarios.  相似文献   

Representations of utopian urbanism and the feminist geopolitics of “new city” development     

Casey R. Lynch 《Urban geography》2013,34(8):1148-1167

Increasingly over the past few years the building of new cities “from scratch” has become a key strategy to promote development across much of the Global South. While several projects are currently under construction, many others exist primarily as proposals awaiting adequate investment or government action. This paper builds on previous literature that considers representations of such projects – promotional materials, digitally-produced video simulations, and master plans – as key components in the production of imagined urban futures. Through an exploration of the proposed Zone for Economic Development and Employment (ZEDE) in Honduras, this article demonstrates a feminist geopolitical approach focused on how such representations of utopian urbanism circulate through the local communities slated for new city development. I examine how representations of future urban spaces and future urban governance regimes become appropriated by local residents in organizing opposition or otherwise making sense of the proposed project’s potential impact on their lives.  相似文献   

Combining regression and spatial proximity for catchment model regionalization: a comparative study     

Scott Steinschneider  Yi-Chen E. Yang  Casey Brown 《水文科学杂志》2013,58(6):1026-1043

Abstract

Spatial error regression is employed to regionalize the parameters of a rainfall–runoff model. The approach combines regression on physiographic watershed characteristics with a spatial proximity technique that describes the spatial dependence of model parameters. The methodology is tested for the monthly abcd model at a network of gauges in southeast United States and compared against simpler regression and spatial proximity approaches. Unlike other comparative regionalization studies that only evaluate the skill of regionalized streamflow predictions in ungauged catchments, this study also examines the fit between regionalized parameters and their optimal (i.e. calibrated) values. Interestingly, the spatial error model produces parameter estimates that better resemble the optimal parameters than either of the simpler methods, but the spatial proximity method still yields better hydrologic simulations. The analysis suggests that the superior streamflow predictions of spatial proximity result from its ability to better preserve correlations between compensatory hydrological parameters.