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921.
Studies from 1994–1998 on the TananaFlats in central Alaska reveal that permafrostdegradation is widespread and rapid, causing largeshifts in ecosystems from birch forests to fens andbogs. Fine-grained soils under the birch forest areice-rich and thaw settlement typically is 1–2.5 mafter the permafrost thaws. The collapsed areas arerapidly colonized by aquatic herbaceous plants,leading to the development of a thick, floatingorganic mat. Based on field sampling of soils,permafrost and vegetation, and the construction of aGIS database, we estimate that 17% of the study area(263,964 ha) is unfrozen with no previous permafrost,48% has stable permafrost, 31% is partiallydegraded, and 4% has totally degraded. For thatportion that currently has, or recently had,permafrost (83% of area), 42% has been affected bythermokarst development. Based on airphoto analysis,birch forests have decreased 35% and fens haveincreased 29% from 1949 to 1995. Overall, the areawith totally degraded permafrost (collapse-scar fensand bogs) has increased from 39 to 47% in 46 y. Based on rates of change from airphoto analysis andradiocarbon dating, we estimate 83% of thedegradation occurred before 1949. Evidence indicatesthis permafrost degradation began in the mid-1700s andis associated with periods of relatively warm climateduring the mid-late 1700s and 1900s. If currentconditions persist, the remaining lowland birchforests will be eliminated by the end of the nextcentury.  相似文献   
922.
Soil venting, in addition to removing volatile organic compounds, has secondary effects on soil temprature and moisture content. A simple enthalpy balance model is used to illustrate the maganitude and direction of temperature and moisture content changes in the soil during ordinary venting and with several potential modifications to venting. Because of the importance of latent heat of vaporization, injection of warm, dry air into the substance is generally ineffective in heating the soil. In contrast, injection of humidified, slightly heated air is found to result in significant soil warming even at low flow rates. Soil warming is thought to be an important mechanism for enhancing remediation, particularly in the final or tail stage of cleanup where concentrations slowly decline wiht time. A variety of soil venting alternatives are simulated at hypothetical sites in Chicago, Illinois, and Tucson, Arizona, including simple humidification, humidification with solar heating, and venting under positive pressure. All there methods result in higher final soil temperatures than the control case of normal soil venting. Humidification of the input air at the rates applied does not result in significant change in average soil moisture content or saturation of the soil wtih water.  相似文献   
923.
Eloctromigraiion offers a potential tool for remediating ground water contaminated with highly soluble components, such as Na+, Cl, NO3 and SO4. A field experiment was designed to lest the efficacy of electromigration for preconcontrating dissolved SO42 in ground water associated with a fossil-fuel power plant. Two shallow wells, 25 feel apart (one 25 feel deep, the other 47 feet deep), were constructed in the upper portion of an unconfined alluvial aquifer. The wells were constructed with a double-wall design, with an outer casing of 4-inch PVC and an inner lube of 2-inch FVC; both were fully slotted (0.01 inch). Electrodes were constructed by wrapping the inner lulling with a 100-foot length of rare-earth metal oxide/copper wire. An electrical potential of 10.65 volts DC Was applied, and tests were run for periods of 12, 44, and 216 hours. Results showed large changes in the pH from the initial pH of ground water of about 7.5 to values of approximately 2 and 12 at the anode and cathode, respectively. Despite the fact that the test conditions were far from ideal, dissolved SO42-; was significantly concentrated at the anode. Over a period of approximately nine days, the concentration of SO42- at the anode reached what appeared to he a steady-state value of 2200 mg/L. compared lo the initial value in ground water of approximately 1150 mg/L. The results of this field lest should encourage further investigation of electromigration as a tool in the remediation of contaminated ground water.  相似文献   
924.
Short-term otolith growth rates, residence times, and forage of two species of juvenile salmon (Oncorhynchus spp.) were compared in a created and natural estuarine slough on the Chehalis River in Washington to assess the functional equivalency of the created slough in providing suitable rearing habitat. Otolith microstructure, mark-recapture data, and forage of sub-yearling chinook, O. tshawytscha, and coho, O. kisutch, residing in both sloughs during the spring of 1991 and 1992 served as indicators of rearing habitat quality. No significant differences in the number or width of coho daily otolith increments were detected between the sloughs. Juvenile chinook residence and emigration times were also comparable. Aquatic and terrestrial insects composed the majority of all chinook and coho diets; however, the order of importance of main prey items did differ between sloughs, and salmon in the created slough had emptier stomachs, possibly because of reduced prey availability and/or foraging efficiency.  相似文献   
925.
Submersed aquatic vegetation (SAV) is an important component of shallow water estuarine systems that has declined drastically in recent decades. SAV has particularly high light requirements, and losses of SAV have, in many cases, been attributed to increased light attenuation in the water column, frequently due to coastal eutrophication. The desire to restore these valuable habitats to their historical levels has created the need for a simple but accurate management tool for translating light requirements into water quality targets capable of supporting SAV communities. A procedure for calculating water quality targets for concentrations of chlorophyll and total suspended solids (TSS) is derived, based on representing the diffuse attenuation coefficient for photosynthetically active radiation, Kd(PAR), as a linear function of contributions due to water plus colored dissolved organic matter (CDOM), chlorophyll, and TSS. It is assumed that Kd(PAR) conforms to the Lambert-Beer law. Target concentrations are determined as the intersection of a line representing intended reduction of TSS and chlorophyll by management actions, with another line describing the dependence of TSS on chlorophyll at a constant value of Kd(PAR). The validity of applying the Lambert-Beer law to Kd(PAR) in estuarine waters was tested by comparing the performance of a linear model of Kd(PAR) with data simulated using a more realistic model of light attenuation. The linear regression model tended to underestimate Kd(PAR) at high light attenuation, resulting in erroneous predictions of target concentrations at shallow restoration depths. The errors result more from the wide spectral bandwidth of PAR, than from irrecoverable nonlinearities in the diffuse attenuation coefficient per se. In spite of the failure of the Lambert-Beer law applied to Kd(PAR), the variation of TSS with chlorophyll at constant Kd(PAR) determined by the more mechanistic attenuation model was, nevertheless, highly linear. Use of the management tool based on intersecting lines is still possible, but coefficients in the line describing the dependence of TSS on chlorophyll at constant Kd(PAR) must be determined empirically by application of an optical model suitably calibrated for the region of interest. An example application of the procedure to data from the Rhode River, Maryland, indicates that approximately 15% reduction in both TSS and chlorophyll concentrations, or 50% reduction in chlorophyll alone, will be needed to restore conditions for growth of SAV to levels that existed in the late 1960s.  相似文献   
926.
The late Cenozoic deposits of central Yukon contain numerous distal tephra beds, derived from vents in the Wrangell Mountains and Aleutian arc–Alaska Peninsula region. We use a few of these tephra beds to gain a better understanding on the timing of extensive Pleistocene glaciations that affected this area. Exposures at Fort Selkirk show that the Cordilleran Ice Sheet advanced close to the outer limit of glaciation about 1.5 myr ago. At the Midnight Dome Terrace, near Dawson City, exposed outwash gravel, aeolian sand, and loess, related to valley glaciers in the adjacent Ogilvie Mountains, are of the same age. Reid glacial deposits at Ash Bend on the Stewart River are older than oxygen isotope stage (OIS) 6 and likely of OIS 8 age, that is, about 250,000 yr B.P. Supporting evidence for this chronology comes from major peaks in the rates of terrigeneous sediment input into the Gulf of Alaska at 1.5 and 0.25 myr B.P.  相似文献   
927.
Reference Minerals for the Microanalysis of Light Elements   总被引:2,自引:0,他引:2  
The quantitative determination of light element concentrations in geological specimens represents a major analytical challenge as the electron probe is generally not suited to this task. With the development of new in situ analytical techniques, and in particular the increasing use of secondary ion mass spectrometry, the routine determination of Li, Be and B contents has become a realistic goal. However, a major obstacle to the development of this research field is the critical dependence of SIMS on the availability of well characterized, homogeneous reference materials that are closely matched in matrix (composition and structure) to the sample being studied. Here we report the first results from a suite of large, gem crystals which cover a broad spectrum of minerals in which light elements are major constituents. We have characterized these materials using both in situ and wet chemical techniques. The samples described here are intended for distribution to geochemical laboratories active in the study of light elements. Further work is needed before reference values for these materials can be finalized, but the availability of this suite of materials represents a major step toward the routine analysis of the light element contents of geological specimens.  相似文献   
928.
929.
Self-diffusion coefficients for Si and O in Di58An42 liquid were measured from 1 to 4 GPa and temperatures from 1510 to 1764°C. Glass starting powders enriched in 18O and 28Si were mated to isotopically normal glass powders to form simple diffusion couples, and self-diffusion experiments were conducted in the piston cylinder device (1 and 2 GPa) and in the multianvil apparatus (3.5 and 4 GPa). Profiles of 18O/16O and 29,30Si/28Si were measured using secondary ion mass spectrometry. Self-diffusion coefficients for O (D(O)) are slightly greater than self-diffusion coefficients for Si (D(Si)) and are often the same within error. For example, D(O) = 4.20 ± 0.42 × 10−11 m2/s and D(Si) = 3.65 ± 0.37 × 10−11 m2/s at 1 GPa and 1662°C. Activation energies for self-diffusion are 215 ± 13 kJ/mol for O and 227 ± 13 kJ/mol for Si. Activation volumes for self-diffusion are −2.1 ± 0.4 cm3/mol and −2.3 ± 0.4 cm3/mol for O and Si, respectively. The similar self-diffusion coefficients for Si and O, similar activation energies, and small, negative activation volumes are consistent with Si and O transport by a cooperative diffusion mechanism, most likely involving the formation and disassociation of a high-coordinated intermediate species. The small absolute magnitudes of the activation volumes imply that Di58An42 liquid is close to a transition from negative to positive activation volume, and Adam-Gibbs theory suggests that this transition is linked to the existence of a critical fraction (∼0.6) of bridging oxygen.  相似文献   
930.
Phil Charles and Andy Fabian review the changes brought to X-ray astronomy by the two orbiting observatories, XMM-Newton and Chandra.
We describe here the changes to X-ray astronomy that are being brought about by the two new orbiting X-ray observatories, NASA's Chandra and ESA's XMM-Newton. Between them they bring a dramatic gain in sensitivity, spatial resolution (now comparable to ground-based optical and infrared telescopes) and spectral resolution. The superb Chandra mirrors rapidly resolved the diffuse X-ray background and have produced stunning detailed images of a wide variety of cosmic objects. Large gains have been made by both missions in spectroscopic performance, with individual X-ray emission lines now detectable in hot stellar coronae, supernova remnants, X-ray binaries, active galactic nuclei and galaxy clusters.  相似文献   
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