Composition of rhodizite     

Clifford Frondel  Jun Ito 《Mineralogy and Petrology》1965,10(1-4):409-412

Summary A chemical analysis of rhodizite from Manjaka, Madagascar, establishes the new formula CsAl₄Be₄B₁₁(OH)₄O₂₅. Space group P43m; a₀ 7.317±0.001 Å; density 3.44±0.01 (meas.), 3.47 (calc.); Z=1. The index of refraction, 1.693±0.001 (Na), and the unit cell dimension are identical within the limits state for material from lithia-pegmatites at Manjaka, Antsongombato, Antandrokomby and Ambalalehifotsy, in Madagascar. Hardness 81/2.

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Zusammenfassung Eine chemische Analyse von Rhodizit an Material von Manjaka, Madagaskar, liefert die neue Formel CsAl₄Be₄B₁₁(OH)₄O₂₅. Raumgruppe P43m, a₀=7,317±0,001 Å; Dichte 3,44±0,01 (exp.), 3,47 (ber.); Z=1. Der Brechungsindex, 1,693±0,001 (Na), und die Gitterkonstante sind innerhalb der angegebenen Grenzen für Material von den Lithium-Pegmatiten bei Manjaka, Antsongombato, Antandrokomby und Ambalalehifotsy auf Madagaskar gleich. Härte 81/2.

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Dedicated to ProfessorF. Machatschki on the occasion of his 70th birthday.  相似文献   

Interstellar colonization: A new parameter for the Drake equation?     

Clifford Walters  Raymond A. Hoover  R.K. Kotra 《Icarus》1980,41(2):193-197

M.H. Hart (1975, Quart. J. Roy. Astron. Soc.16, 128–135) has argued that the absence of evidence for extraterrestrial visits to Earth indicates that there are no other advanced civilizations in our galaxy capable of interstellar colonization. If so, the possible success of any SETI program must be questioned. The authors propose that limited interstellar colonization may occur and an attempt is made to show the effects of such a journey on the Drake equation.  相似文献   

Sedimentary processes,stratigraphic sequences and middens: the link between archaeology and geoheritage—a case study from the Quaternary of the Broome region,Western Australia     

P. Clifford 《Australian Journal of Earth Sciences》2019,66(6):955-972

The cliffed and active dune coastal region of Broome provides an excellent record of Pleistocene and Holocene stratigraphy of desert environments interfacing with the Indian Ocean. The Mesozoic Broome Sandstone is the basal stratigraphic unit in the area and is overlain by Pleistocene red desert quartz sand (Mowanjum Sand). Modern coastal processes of waves, wind and tide have resulted in distinctive sedimentary bodies (stratigraphic units) clearly linked to the sedimentary environment. The Mowanjum Sand, reworked by coastal winds, generates the landward-ingressing orange quartzose Churchill Sand, or reworked by waves and abraded to white sand with the addition of carbonate grains that form the beaches (Cable Beach Sand) and with eolian action, coastal dunes or inland-ingressing white dunes (Shoonta Hill Sand). These sedimentary bodies and stratigraphic units form a template with which to locate and interpret archaeological middens and Indigenous occupation over the past 5000?years in a context of coastal occupation, coastal stability, mean sea-level changes, climate changes, and availability of marine food and freshwater. Shell middens and stone artefacts form definitive layers or horizons in relation to the stratigraphy, in places in situ, and elsewhere reworked as sheets and plumes; understanding their inter-relationships has enabled the unravelling of the archaeological history and relating Indigenous occupation to biofacies and lithofacies. The array of sedimentary, biofacies and stratigraphic units are of national geoheritage significance in their own right. The addition of archaeological deposits as stratigraphic units provides a link between geoheritage and archaeology, where the archaeological materials are viewed as part of the complex stratigraphic story, part of the coastal history, and part of the geoheritage story.  相似文献   

Controls on deep critical zone architecture: a historical review and four testable hypotheses   总被引：1，自引：0，他引：1       下载免费PDF全文

Clifford S. Riebe  W. Jesse Hahm  Susan L. Brantley 《地球表面变化过程与地形》2017,42(1):128-156

The base of Earth's critical zone (CZ) is commonly shielded from study by many meters of overlying rock and regolith. Though deep CZ processes may seem far removed from the surface, they are vital in shaping it, preparing rock for infusion into the biosphere and breaking Earth materials down for transport across landscapes. This special issue highlights outstanding challenges and recent advances of deep CZ research in a series of articles that we introduce here in the context of relevant literature dating back to the 1500s. Building on several contributions to the special issue, we highlight four exciting new hypotheses about factors that drive deep CZ weathering and thus influence the evolution of life‐sustaining CZ architecture. These hypotheses have emerged from recently developed process‐based models of subsurface phenomena including: fracturing related to subsurface stress fields; weathering related to drainage of bedrock under hydraulic head gradients; rock damage from frost cracking due to subsurface temperature gradients; and mineral reactions with reactive fluids in subsurface chemical potential gradients. The models predict distinct patterns of subsurface weathering and CZ thickness that can be compared with observations from drilling, sampling and geophysical imaging. We synthesize the four hypotheses into an overarching conceptual model of fracturing and weathering that occurs as Earth materials are exhumed to the surface across subsurface gradients in stress, hydraulic head, temperature, and chemical potential. We conclude with a call for a coordinated measurement campaign designed to comprehensively test the four hypotheses across a range of climatic, tectonic and geologic conditions. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Downvalley fining of hillslope sediment in an alpine catchment: implications for downstream fining of sediment flux in mountain rivers     

Leonard S. Sklar  Clifford S. Riebe  Jennifer Genetti  Shirin Leclere  Claire E. Lukens 《地球表面变化过程与地形》2020,45(8):1828-1845

The size distributions of sediment delivered from hillslopes to rivers profoundly influence river morphodynamics, including river incision into bedrock and the quality of aquatic habitat. Yet little is known about the factors that influence size distributions of sediment produced by weathering on hillslopes. We present results of a field study of hillslope sediment size distributions at Inyo Creek, a steep catchment in granitic bedrock of the Sierra Nevada, USA. Particles sampled near the base of hillslopes, adjacent to the trunk stream, show a pronounced decrease in sediment size with decreasing sample elevation across all but the coarsest size classes. Measured size distributions become increasingly bimodal with decreasing elevation, exhibiting a coarse, bouldery mode that does not change with elevation and a more abundant finer mode that shifts from cobbles at the highest elevations to gravel at mid elevations and finally to sand at low elevations. We interpret these altitudinal variations in hillslope sediment size to reflect changes in physical, chemical, and biological weathering that can be explained by the catchment's strong altitudinal gradients in topography, climate, and vegetation cover. Because elevation and travel distance to the outlet are closely coupled, the altitudinal trends in sediment size produce a systematic decrease in sediment size along hillslopes parallel to the trunk stream. We refer to this phenomenon as ‘downvalley fining.’ Forward modeling shows that downvalley fining of hillslope sediment is necessary for downstream fining of the long-term average flux of coarse sediment in mountain landscapes where hillslopes and channels are coupled and long-term net sediment deposition is negligible. The model also shows that abrasion plays a secondary role in downstream fining of coarse sediment flux but plays a dominant role in partitioning between the bedload and suspended load. Patterns observed at Inyo Creek may be widespread in mountain ranges around the world. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

Strong slope-aspect control of regolith thickness by bedrock foliation     

Jordan D. Leone  W. Steven Holbrook  Clifford S. Riebe  Jon Chorover  Ty P.A. Ferré  Bradley J. Carr  Russell P. Callahan 《地球表面变化过程与地形》2020,45(12):2998-3010

The porous near-surface layer of the Earth's crust – the critical zone – constitutes a vital reservoir of water for ecosystems, provides baseflow to streams, guides recharge to deep aquifers, filters contaminants from groundwater, and regulates the long-term evolution of landscapes. Recent work suggests that the controls on regolith thickness include climate, tectonics, lithology, and vegetation. However, the relative paucity of observations of regolith structure and properties at landscape scales means that theoretical models of critical zone structure are incompletely tested. Here we present seismic refraction and electrical resistivity surveys that thoroughly characterize subsurface structure in a small catchment in the Santa Catalina Mountains, Arizona, USA, where slope-aspect effects on regolith structure are expected based on differences in vegetation. Our results show a stark contrast in physical properties and inferred regolith thickness on opposing slopes, but in the opposite sense of that expected from environmental models and observed vegetation patterns. Although vegetation (as expressed by normalized difference vegetation index [NDVI]) is denser on the north-facing slope, regolith on the south-facing slope is four times thicker (as indicated by lower seismic velocities and resistivities). This contrast cannot be explained by variations in topographic stress or conventional hillslope morphology models. Instead, regolith thickness appears to be controlled by metamorphic foliation: regolith is thicker where foliation dips into the topography, and thinner where foliation is nearly parallel to the surface. We hypothesize that, in this catchment, hydraulic conductivity and infiltration capacity control weathering: infiltration is hindered and regolith is thin where foliation is parallel to the surface topography, whereas water infiltrates deeper and regolith is thicker where foliation intersects topography at a substantial angle. These results suggest that bedrock foliation, and perhaps by extension sedimentary layering, can control regolith thickness and must be accounted for in models of critical zone development. © 2020 John Wiley & Sons, Ltd.  相似文献   

Development of ST:REAM: a reach‐based stream power balance approach for predicting alluvial river channel adjustment          下载免费PDF全文

Chris Parker  Colin R Thorne  Nicholas J Clifford 《地球表面变化过程与地形》2015,40(3):403-413

River channel sediment dynamics are important in integrated catchment management because changes in channel morphology resulting from sediment transfer have important implications for many river functions. However, application of existing approaches that account for catchment‐scale sediment dynamics has been limited, largely due to the difficulty in obtaining data necessary to support them. It is within this context that this study develops a new, reach‐based, stream power balance approach for predicting river channel adjustment. The new approach, named ST:REAM (sediment transport: reach equilibrium assessment method), is based upon calculations of unit bed area stream power (ω) derived from remotely sensed slope, width and discharge datasets. ST:REAM applies a zonation algorithm to values of ω that are spaced every 50 m along the catchment network in order to divide the branches of the network up into relatively homogenous reaches. ST:REAM then compares each reach's ω value with the ω of its upstream neighbour in order to predict whether or not the reach is likely to be either erosion dominated or deposition dominated. The paper describes the application of ST:REAM to the River Taff in South Wales, UK. This test study demonstrated that ST:REAM can be rapidly applied using remotely sensed data that are available across many river catchments and that ST:REAM correctly predicted the status of 87.5% of sites within the Taff catchment that field observations had defined as being either erosion or deposition dominated. However, there are currently a number of factors that limit the usefulness of ST:REAM, including inconsistent performance and the need for additional, resource intensive, data to be collected to both calibrate the model and aid interpretation of its results. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Geophysical constraints on deep weathering and water storage potential in the Southern Sierra Critical Zone Observatory   总被引：1，自引：0，他引：1       下载免费PDF全文

W. Steven Holbrook  Clifford S. Riebe  Mehrez Elwaseif  Jorden L. Hayes  Kyle Basler‐Reeder  Dennis L. Harry  Armen Malazian  Anthony Dosseto  Peter C. Hartsough  Jan W. Hopmans 《地球表面变化过程与地形》2014,39(3):366-380

The conversion of bedrock to regolith marks the inception of critical zone processes, but the factors that regulate it remain poorly understood. Although the thickness and degree of weathering of regolith are widely thought to be important regulators of the development of regolith and its water‐storage potential, the functional relationships between regolith properties and the processes that generate it remain poorly documented. This is due in part to the fact that regolith is difficult to characterize by direct observations over the broad scales needed for process‐based understanding of the critical zone. Here we use seismic refraction and resistivity imaging techniques to estimate variations in regolith thickness and porosity across a forested slope and swampy meadow in the Southern Sierra Critical Zone Observatory (SSCZO). Inferred seismic velocities and electrical resistivities image a weathering zone ranging in thickness from 10 to 35 m (average = 23 m) along one intensively studied transect. The inferred weathering zone consists of roughly equal thicknesses of saprolite (P‐velocity < 2 km s^?1) and moderately weathered bedrock (P‐velocity = 2–4 km s^?1). A minimum‐porosity model assuming dry pore space shows porosities as high as 50% near the surface, decreasing to near zero at the base of weathered rock. Physical properties of saprolite samples from hand augering and push cores are consistent with our rock physics model when variations in pore saturation are taken into account. Our results indicate that saprolite is a crucial reservoir of water, potentially storing an average of 3 m³ m^?2 of water along a forested slope in the headwaters of the SSCZO. When coupled with published erosion rates from cosmogenic nuclides, our geophysical estimates of weathering zone thickness imply regolith residence times on the order of 10⁵ years. Thus, soils at the surface today may integrate weathering over glacial–interglacial fluctuations in climate. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

3-D seismic tomography of the Adelaide fold belt     

Peter Clifford  Stewart Greenhalgh  Greg Houseman  Frank Graeber 《Geophysical Journal International》2008,172(1):167-186

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Protracted thrusting followed by late rapid cooling of the Greater Himalayan Sequence,Annapurna Himalaya,Central Nepal: Insights from titanite petrochronology   总被引：2，自引：0，他引：2       下载免费PDF全文

Jesse B. Walters  Matthew J. Kohn 《Journal of Metamorphic Geology》2017,35(8):897-917

The Greater Himalayan Sequence (GHS) has commonly been treated as a large coherently deforming high‐grade tectonic package, exhumed primarily by simultaneous thrust‐ and normal‐sense shearing on its bounding structures and erosion along its frontal exposure. A new paradigm, developed over the past decade, suggests that the GHS is not a single high‐grade lithotectonic unit, but consists of in‐sequence thrust sheets. In this study, we examine this concept in central Nepal by integrating temperature–time (T–t) paths, based on coupled Zr‐in‐titanite thermometry and U–Pb geochronology for upper GHS calcsilicates, with traditional thermobarometry, textural relationships and field mapping. Peak Zr‐in‐titanite temperatures are 760–850°C at 10–13 kbar, and U–Pb ages of titanite range from c. 30 to c. 15 Ma. Sector zoning of Zr and distribution of U–Pb ages within titanite suggest that diffusion rates of Zr and Pb are slower than experimentally determined rates, and these systems remain unaffected into the lower granulite facies. Two types of T–t paths occur across the Chame Shear Zone (CSZ). Between c. 25 and 17–16 Ma, hangingwall rocks cool at rates of 1–10°C/Ma, while footwall rocks heat at rates of 1–10°C/Ma. Over the same interval, temperatures increase structurally upwards through the hangingwall, but by 17–16 Ma temperatures converge. In contrast, temperatures decrease upwards in footwall rocks at all times. While the footwall is interpreted as an intact, structurally upright section, the thermometric inversion within the hangingwall suggests thrusting of hotter rocks over colder from c. 25 to c. 17–16 Ma. Retrograde hydration that is restricted to the hangingwall, and a lithological repetition of orthogneiss are consistent with thrust‐sense shear on the CSZ. The CSZ is structurally higher than previously identified intra‐GHS thrusts in central Nepal, and thrusting duration was 3–6 Ma longer than proposed for other intra‐GHS thrusts in this region. Cooling rates for both the hangingwall and footwall of the CSZ are comparable to or faster than rates for other intra‐GHS thrust sheets in Nepal. The overlap in high‐T titanite U–Pb ages and previously published muscovite ⁴⁰Ar/³⁹Ar cooling ages imply cooling rates for the hangingwall of ≥200°C/Ma after thrusting. Causes of rapid cooling include passive exhumation driven by a combination of duplexing in the Lesser Himalayan Sequence, and juxtaposition of cooler rocks on top of the GHS by the STDS. Normal‐sense displacement does not appear to affect T–t paths for rocks immediately below the STDS prior to 17–16 Ma.  相似文献