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11.
Gamma ray logging is a method routinely employed by geophysicists and environmental engineers in site geology evaluations. Modelling of gamma ray data from individual boreholes assists in the local identification of major lithological changes; modelling these data from a network of boreholes assists with lithological mapping and spatial stratigraphic correlation. In this paper we employ Bayesian spatial partition models to analyse gamma ray data spatially. In particular, a spatial partition is defined via a Voronoi tessellation and the mean intensity is assumed constant in each cell of the partition. The number of vertices generating the tessellation as well as the locations of vertices are assumed unknown, and uncertainty about these quantities is described via a hierarchical prior distribution. We describe the advantages of the spatial partition modelling approach in the context of smoothing gamma ray count data and describe an implementation that may be extended to the fitting of a more general model than a constant mean within each cell of the partition. As an illustration of the methodology we consider a data set collected from a network of eight boreholes, which is part of a geophysical study to assist in mapping the lithology of a site. Gamma ray logs are linked with geological information from cores and the spatial analysis of log data assists with predicting the lithology at unsampled locations.  相似文献   
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Smoothing and Change Point Detection for Gamma Ray Count Data   总被引:1,自引:0,他引:1  
Gamma ray detectors are used to measure the natural radioactivity of rocks. For a number of boreholes drilled at a site the gamma ray detector is lowered into each borehole and counts of gamma ray emissions at different depths are recorded as the instrument is gradually raised to ground level. The profile of gamma counts can be informative about the geology at each location. The raw count data are highly variable, and in this paper we describe the use of adaptive smoothing techniques and change point models in order to identify changes in the geology based on the gamma logs. We formulate all our models for the data in the framework of the class of generalized linear models, and describe computational methods for Bayesian inference and model selection for generalized linear models that improve on existing techniques. Application is made to gamma ray data from the Castelreagh Waste Management Centre which served as a hazardous waste disposal facility for the Sydney region between March 1974 and August 1998. Understanding the geological structure of this site is important for further modelling the transport of pollutants beneath the waste disposal area.  相似文献   
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The zircons from an eclogite and an enclosed eclogite-facies vein from the Monviso ophiolite (Western Alps) display contrasting chemical and morphologic features and document different stages of the evolution of the ophiolite. The zircons from the eclogite show a typical magmatic zoning and are enriched in heavy rare earth elements (HREEs) over middle rare earth elements (MREEs) and have an accentuated negative Eu anomaly, which indicates that the grains co-crystallised with plagioclase. These magmatic zircons document the formation of oceanic crust at 163 ± 2 Ma. In contrast, zircons from the vein contain inclusions of garnet, omphacite, and rutile, which indicate that they crystallised under eclogite-facies conditions. The vein zircons have Th/U ratios < 0.09, lack Eu anomalies, and are only weakly enriched in HREE with respect to MREE. These features are consistent with a garnet-bearing, plagioclase-free, i.e., eclogite-facies paragenesis. Vein zircons yield an age of 45 ± 1 Ma, which is evidence for Eocene subduction-zone metamorphism of the Monviso ophiolite.In the vein, the apparent coexistence of zircon, omphacite, and garnet permits the determination of a set of trace element distribution coefficients among these minerals at high pressure. This set of partitioning can demonstrate chemical equilibrium among these phases in rocks that show less clear evidence of textural equilibrium. In addition, zircon age can now be linked to sensors of metamorphic pressure-temperature conditions. The presence of zircon and rutile in the vein is another example of high field strength element (HFSE) mobility over short distances in aqueous fluids at eclogite-facies conditions. However, the concentrations of Zr and Hf in the aqueous fluid are estimated to be at least a factor of 10 less than primitive mantle values.Mass balance calculations demonstrate that zircon hosts > 95% of the bulk Zr, 90% of Hf, and ∼25% of U in the vein. Zircon is a residual phase in subducted basalts and sediments up to temperatures of at least 800 to 900 °C. Therefore, residual zircon in subducted crust, together with rutile, control the HFSE in liberated subduction zone fluids/melts and might be partly responsible for negative Zr and Hf anomalies in subduction zone magmas.  相似文献   
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At T > 100°C development of thermodynamic models suffers from missing experimental data, particularly for solubilities of sulfate minerals in mixed solutions. Solubilities in Na+-K+-Ca2+-Cl-SO42−/H2O subsystems were investigated at 150, 200°C and at selected compositions at 100°C. The apparatus used to examine solid-liquid phase equilibria under hydrothermal conditions has been described.In the system NaCl-CaSO4-H2O the missing anhydrite (CaSO4) solubilities at high NaCl concentrations up to halite saturation have been determined. In the system Na2SO4-CaSO4-H2O the observed glauberite (Na2SO4 · CaSO4) solubility is higher than that predicted by the high temperature model of Greenberg and Møller (1989), especially at 200°C. At high salt concentrations, solubilities of both anhydrite and glauberite increase with increasing temperature. Stability fields of the minerals syngenite (K2SO4 · CaSO4 · H2O) and goergeyite (K2SO4 · 5 CaSO4 · H2O) were determined, and a new phase was found at 200°C in the K2SO4-CaSO4-H2O system. Chemical and single crystal structure analysis give the formula K2SO4 · CaSO4. The structure is isostructural with palmierite (K2SO4 · PbSO4). The glaserite (“3 K2SO4 · Na2SO4”) appears as solid solution in the system Na2SO4-K2SO4-H2O. Its solubility and stoichiometry was determined as a function of solution composition.  相似文献   
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The combined use of field investigation and laboratory analyses allowed the detailed stratigraphic reconstruction of the Pollena eruption (472 AD) of Somma-Vesuvius. Three main eruptive phases were recognized, related either to changes in the eruptive processes and/or to relative changes of melt composition. The eruption shows a pulsating behavior with deposition of pyroclastic fall beds and generation of dilute and dense pyroclastic density currents (PDC). The eruptive mechanisms and transportation dynamics were reconstructed for the whole eruption. Column heights were between 12 and 20 km, corresponding to mass discharge rates (MDR) of 7×106 kg/s and 3.4×107 kg/s. Eruptive dynamics were driven by magmatic fragmentation of a phono-tephritic to tephri-phonolitic magma during Phases I and II, whereas phreatomagmatic fragmentation dominated Phase III. Magma composition varies between phonolitic and tephritic-phonolitic, with melt viscosity likely not in excess of 103 Pa s. The volume of the pyroclastic fall deposits, calculated by using of proximal isopachs, is 0.44 km3. This increases to 1.38 km3 if ash volumes are extrapolated on a log thickness vs. square root area diagram using one distal isopach and column height.Editorial responsibility: R Cioni  相似文献   
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In situ analysis of a garnet porphyroblast from a granulite facies gneiss from Sør Rondane Mountains, East Antarctica, reveals discontinuous step‐wise zoning in phosphorus and large δ18O variations from the phosphorus‐rich core to the phosphorus‐poor rim. The gradually decreasing profile of oxygen isotope from the core (δ18O = ~15‰) to the rim (δ18O = ~11‰) suggests that the 18O/16O zoning was originally step‐wise, and modified by diffusion after the garnet rim formation at ~800°C and 0.8 GPa. Fitting of the 18O/16O data to the diffusion equation constrains a duration of the high‐T event (~800°C) to c. 0.5–40 Ma after the garnet rim formation. The low δ18O value of the garnet rim, together with the previously reported low δ18O values in metacarbonates, indicates regional infiltration, probably along a detachment fault, of low δ18O fluid/melt possibly derived from meta‐mafic to ultramafic rocks.  相似文献   
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