The effect of net-transfer reactions on the isotopic composition of minerals     

C. Page Chamberlain  John M. Ferry  Douglas Rumble III 《Contributions to Mineralogy and Petrology》1990,105(3):322-336

To interpret correctly the isotopic composition of metmorphic rocks and minerals, the effect of nettransfer reactions must be quantitatively evaluated. Such evaluation requires a complete set of linearly independent, net-transfer reactions that fully describe the reacting system. The set of net-transfer reactions is then coupled with mass-balance equations for stable isotopes. Reaction spaces can be contoured with isopleths of °¹⁸O, °¹³C, and D of minerals which allows evaluation of the effect of different reactions and bulk compositions on the stable isotopic composition of minerals and rocks. Using this approach, we examined the effect of fractionation of isotopes due to net-transfer reactions at the biotite and second-sillimanite isograds in northern New England. Our analysis shows that the shift in °¹³C and °¹⁸O at an isograd depends strongly upon the overall net-transfer reaction at the isograd and the bulk composition of the rock. The use of model isograd reactions to determine isotopic shifts, therefore, can lead to serious errors in the interpretation of isotopic data. At the second-sillimanite isograd °¹⁸O _qtz (quartz), °¹⁸O _kspar (K feldsdpar), and °¹⁸O _wr (whole rock) decrease by 0.5, 1.0, and 0.8 per mil, respectively. Quantitative evaluation of the effect of fractionation of isotopes by net-transfer reactions shows that: (1) the relative changes in oxygen isotopes across the isograd could be caused by distillation of fluids during develatilization reactions; (2) the magnitude of the observed isotopic shifts often differs by a factor of 2 from the calculated shifts due to reaction progress alone. The difference between observed and calculated shifts is attributed to either, differences in bulk composition between individual rocks, or, to isotopic exchange between minerals after peak metamorphism. At the biotite isograd the shifts in carbon and oxygen isotope values are different from predicted shifts caused by net-transfer reactions alone. This discrepancy suggests that fluids infiltrated the rocks during the formation of the biotite isograd.  相似文献   

Ti-in-zircon thermometry: applications and limitations   总被引：16，自引：5，他引：11  

Bin Fu  F. Zeb Page  Aaron J. Cavosie  John Fournelle  Noriko T. Kita  Jade Star Lackey  Simon A. Wilde  John W. Valley 《Contributions to Mineralogy and Petrology》2008,156(2):197-215

The titanium concentrations of 484 zircons with U-Pb ages of ∼1 Ma to 4.4 Ga were measured by ion microprobe. Samples come from 45 different igneous rocks (365 zircons), as well as zircon megacrysts (84) from kimberlite, Early Archean detrital zircons (32), and zircon reference materials (3). Samples were chosen to represent a large range of igneous rock compositions. Most of the zircons contain less than 20 ppm Ti. Apparent temperatures for zircon crystallization were calculated using the Ti-in-zircon thermometer (Watson et al. 2006, Contrib Mineral Petrol 151:413–433) without making corrections for reduced oxide activities (e.g., TiO₂ or SiO₂), or variable pressure. Average apparent Ti-in-zircon temperatures range from 500° to 850°C, and are lower than either zircon saturation temperatures (for granitic rocks) or predicted crystallization temperatures of evolved melts (∼15% melt residue for mafic rocks). Temperatures average: 653 ± 124°C (2 standard deviations, 60 zircons) for felsic to intermediate igneous rocks, 758 ± 111°C (261 zircons) for mafic rocks, and 758 ± 98°C (84 zircons) for mantle megacrysts from kimberlite. Individually, the effects of reduced or , variable pressure, deviations from Henry’s Law, and subsolidus Ti exchange are insufficient to explain the seemingly low temperatures for zircon crystallization in igneous rocks. MELTs calculations show that mafic magmas can evolve to hydrous melts with significantly lower crystallization temperature for the last 10–15% melt residue than that of the main rock. While some magmatic zircons surely form in such late hydrous melts, low apparent temperatures are found in zircons that are included within phenocrysts or glass showing that those zircons are not from evolved residue melts. Intracrystalline variability in Ti concentration, in excess of analytical precision, is observed for nearly all zircons that were analyzed more than once. However, there is no systematic change in Ti content from core to rim, or correlation with zoning, age, U content, Th/U ratio, or concordance in U-Pb age. Thus, it is likely that other variables, in addition to temperature and , are important in controlling the Ti content of zircon. The Ti contents of igneous zircons from different rock types worldwide overlap significantly. However, on a more restricted regional scale, apparent Ti-in-zircon temperatures correlate with whole-rock SiO₂ and HfO₂ for plutonic rocks of the Sierra Nevada batholith, averaging 750°C at 50 wt.% SiO₂ and 600°C at 75 wt.%. Among felsic plutons in the Sierra, peraluminous granites average 610 ± 88°C, while metaluminous rocks average 694 ± 94°C. Detrital zircons from the Jack Hills, Western Australia with ages from 4.4 to 4.0 Ga have apparent temperatures of 717 ± 108°C, which are intermediate between values for felsic rocks and those for mafic rocks. Although some mafic zircons have higher Ti content, values for Early Archean detrital zircons from a proposed granitic provenance are similar to zircons from many mafic rocks, including anorthosites from the Adirondack Mts (709 ± 76°C). Furthermore, the Jack Hills zircon apparent Ti-temperatures are significantly higher than measured values for peraluminous granites (610 ± 88°C). Thus the Ti concentration in detrital zircons and apparent Ti-in-zircon temperatures are not sufficient to independently identify parent melt composition. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Sensitivity of future U.S. Water shortages to socioeconomic and climate drivers: a case study in Georgia using an integrated human-earth system modeling framework   总被引：1，自引：0，他引：1  

Michael J. Scott  Don S. Daly  Mohamad I. Hejazi  G. Page Kyle  Lu Liu  Haewon C. McJeon  Anupriya Mundra  Pralit L. Patel  Jennie S. Rice  Nathalie Voisin 《Climatic change》2016,136(2):233-246

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Implications of uncertain future fossil energy resources on bioenergy use and terrestrial carbon emissions     

Katherine?CalvinEmail author  Marshall?Wise  Patrick?Luckow  Page?Kyle  Leon?Clarke  Jae?Edmonds 《Climatic change》2016,136(1):57-68

The magnitude and character of the global resource base of fossil fuels is a key determinant of the evolution of the future global energy system and corresponding fossil fuel carbon emissions. What is less well understood is the potential magnitude of impact of the availability of fossil fuels, due to the interaction with biomass energy, on agriculture, land use, ecosystems and therefore carbon emissions from land-use change. This paper explores these links and implications. We show that if oil resources are limited, then the consequently higher price for liquids induces both the use of coal-to-liquids technology deployment, but also enhanced production of bioenergy crops particularly in a business-as-usual scenario. This in turn implies greater pressure to convert unmanaged ecosystems to produce bioenergy, and higher rates of terrestrial carbon emissions from land use.  相似文献   

Legacies of a Contested Campus: Urban Renewal,Community Resistance,and the Origins of Gentrification in Denver     

Brian Page  Eric Ross 《Urban geography》2017,38(9):1293-1328

The postwar urban renewal experience varied among US cities according to the result of local social contests pitting those imposing their power to transform urban space against those resisting it. In this paper, we examine the role of one such contest in shaping urban renewal outcomes in Denver, using the case of the late 1960s Auraria project. The project sought to remove a poor, Hispanic neighborhood in order to build a new downtown college campus, generating community opposition from the inner city neighborhood residents, leaders of the city’s Chicano Movement, and historic preservation activists. We demonstrate how resistance actively shaped the ultimate form and character of the project, and how the legacies of this urban renewal contest extended—in unforeseen ways—beyond the immediate struggles of the time. We argue that these legacies provide the essential context for understanding planning practice, redevelopment strategies, and gentrification dynamics in the city today.  相似文献   

The effect of chromium absorption and depuration on the activities of glucose 6-phosphate dehydrogenase and aspartate amino transferase in Mytilus edulis     

David S. Page  E.S. Gilfillan  M. Clavette  J.C. Foster 《Marine environmental research》1985,17(2-4)

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Seasonal and Interannual Variability in the Distribution of Surface Nutrients and Dissolved Inorganic Carbon in the Northern North Pacific: Influence of El Niño     

Chi Shing Wong  Nathalie A. D. Waser  Yukihiro Nojiri  Wm. Keith Johnson  Frank A. Whitney  John S. C. Page  Jiye Zeng 《Journal of Oceanography》2002,58(2):227-243

The seasonal and interannual changes in surface nutrients, dissolved inorganic carbon (DIC) and total alkalinity (TA) were recorded in the North Pacific (30–54°N) from 1995 to 2001. This study focuses on the region north of the subarctic boundary (∼40°N) where there was extensive monthly coverage of surface properties. The nutrient cycles showed large interannual variations in the eastern and western subarctic gyres. In the Alaska Gyre the seasonal depletion of nitrate (ΔNO₃) increased from 8–14 μmol kg⁻¹ in 1995–1999 to 21.5 μmol kg⁻¹ in 2000. In the western subarctic the shifts were similar in amplitude but more frequent. The large ΔNO₃ levels were associated with high silicate depletions, indicating enhanced diatom production. The seasonal DIC:NO₃ drawdown ratios were elevated in the eastern and central subarctic due to calcification. In the western subarctic and the central Bering Sea calcification was significant only during 1997 and/or 1998, two El Ni?o years. Regional C/N stoichiometric molar ratios of 5.7 to 7.0 (>40°N) were determined based on the years with negligible or no calcification. The annual new production (NP_a) based on ΔNO₃ and these C/N ratios showed large interannual variations. NP_a was usually higher in the western than in the eastern subarctic. However, values of 84 gC m⁻²yr⁻¹ were found in the Alaska Gyre in 2000 which is similar to that in the most productive provinces of the northern North Pacific. There were also large increases in NP_a around the Alaska Peninsula in 1997 and 1998. Finally, the net removal of carbon by the biological pump was estimated as 0.72 Gt C yr⁻¹ in the North Pacific (>30°N). This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

The Swift gamma-ray burst GRB 050422     

A. P. Beardmore  K. L. Page  P. T. O'Brien  J. P. Osborne  S. Kobayashi  B. Zhang  D. N. Burrows  M. Capalbi  M. R. Goad  O. Godet  J. E. Hill  V. La Parola  F. Marshall  A. A. Wells 《Monthly notices of the Royal Astronomical Society》2007,374(4):1473-1478

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A hierarchical approach measures the aerial extent and concentration levels of PAH-contaminated shoreline sediments at historic industrial sites in Prince William Sound, Alaska     

Page DS  Brown JS  Boehm PD  Bence AE  Neff JM 《Marine pollution bulletin》2006,52(4):367-379

A field study was conducted in 2003 to estimate the areal distribution and concentrations of polycyclic aromatic hydrocarbons (PAH) in intertidal sediments at sites of past human and industrial activity (HA sites) in Prince William Sound (PWS), Alaska, the site of the 1989 Exxon Valdez oil spill. More than 50 HA sites, primarily in western PWS, were identified through analysis of historic records and prior field studies, and nine sites were selected for detailed surveys. The areal assessment process consisted of seven steps: (1) identify site from historic records and field surveys; (2) locate visual evidence of surface oil/tar at a site; (3) prepare a site map and lay out a sampling grid over the entire site with 10-m grid spacing; (4) excavate pits to 50 cm depth on the grid; (5) perform a field colorimetric test to estimate total PAH (TPAH) in sediments from the wall of each pit and record the results in the ranges <1 ppm; 1-10 ppm; >10 ppm TPAH; (6) expand grid size if necessary if elevated PAH levels are detected colorimetrically; (7) select 20 samples from each site for same-day shipboard PAH analysis by immunoassay (SDI RaPID PAH) and, based on these results, select sediment samples from each site for full PAH analysis in the laboratory to identify PAH sources. A total of 416 pits were dug at the nine sites. Nine acres of sediments with TPAH >2500 ppb dry wt. were mapped at the nine sites. TPAH concentrations obtained by immunochemical analysis of 181 samples from the nine sites ranged from 20 to 1,320,000 ppb (wet wt.). The contaminants are mixtures of petroleum products (2-3 ring PAH) and combustion products (4-6 ring PAH) unrelated to the 1989 Exxon Valdez oil spill. Mussels and clams collected at these sites have elevated levels of PAH that are compositionally similar to the PAH in the sediments. These findings indicate that at least a portion of the sediment PAH is bioavailable. The PAH sources at these historic industrial sites are chronic. They include relict fuel oil tanks and works located above and within the intertidal zone, with contamination at some locations extending into nearshore sub-tidal sediments. This study shows how a hierarchical approach can be used to quickly and successfully map, quantify, and subsequently, identify sources of PAH in shoreline sediments.  相似文献   

Methods and results of an automatic analysis of a complete sample of Swift-XRT observations of GRBs     

P. A. Evans  A. P. Beardmore  K. L. Page  J. P. Osborne  P. T. O'Brien  R. Willingale  R. L. C. Starling  D. N. Burrows  O. Godet  L. Vetere  J. Racusin  M. R. Goad  K. Wiersema  L. Angelini  M. Capalbi  G. Chincarini  N. Gehrels  J. A. Kennea  R. Margutti  D. C. Morris  C. J. Mountford  C. Pagani  M. Perri  P. Romano  N. Tanvir 《Monthly notices of the Royal Astronomical Society》2009,397(3):1177-1201

We present a homogeneous X-ray analysis of all 318 gamma-ray bursts detected by the X-ray telescope (XRT) on the Swift satellite up to 2008 July 23; this represents the largest sample of X-ray GRB data published to date. In Sections 2–3 , we detail the methods which the Swift -XRT team has developed to produce the enhanced positions, light curves, hardness ratios and spectra presented in this paper. Software using these methods continues to create such products for all new GRBs observed by the Swift -XRT. We also detail web-based tools allowing users to create these products for any object observed by the XRT, not just GRBs. In Sections 4–6 , we present the results of our analysis of GRBs, including probability distribution functions of the temporal and spectral properties of the sample. We demonstrate evidence for a consistent underlying behaviour which can produce a range of light-curve morphologies, and attempt to interpret this behaviour in the framework of external forward shock emission. We find several difficulties, in particular that reconciliation of our data with the forward shock model requires energy injection to continue for days to weeks.  相似文献