Hydrothermal dolomitization in platform and basin carbonate successions during thrusting: A hydrocarbon reservoir analogue (Mesozoic of Venetian Southern Alps,Italy)     

Paola Ronchi  Daniele Masetti  Stefano Tassan  Davide Camocino 《Marine and Petroleum Geology》2012,29(1):68-89

The Early Jurassic dolomitized carbonates in the Venetian Alp, represent a surface analogue of the hydrocarbon exploration targets in Adriatic offshore and Po Plain, Italy. Dolomitization affected the carbonate platform of Monte Zugna Formation (Lower Jurassic) and the Neptunian dikes breccia in the pelagic Maiolica Formation (Uppermost Jurassic–Lower Cretaceous) improving the poro-perm characteristics. Petrography, stable isotope, strontium isotope ratio, trace element and fluid inclusion analyses were carried out on samples from the Monte Grappa Anticline, which is the direct analogue for subsurface. The petrographic analyses showed a first pervasive, replacement dolomitization phase (D1) followed by volumetrically less important dolomite cement precipitation phases (D2, D3, DS). The same, quite wide range of oxygen isotope (?9 to ?2‰ V-PDB) is observed in all dolomite types. The δ¹³C range is in the positive field of marine derived carbonate (from +0.5 to +3.2‰ PDB). The trace element analysis showed a slight enrichment in Fe and Mn contents in the Monte Zugna dolostones with respect the original limestone. The same dolomite precipitation temperature (up to 105 °C Th) was observed in the replacement and cement dolomites, suggesting a unique dolomitization event. This temperature, largely higher than the maximum burial temperature (about 50 °C), supports a hydrothermal origin of the dolomitizing fluids, which had a seawater to brackish composition. The data collected suggest a hydrothermal dolomitization occurring during to the South Alpine thrusting according to the “squeegee model”. The interpretation is consistent with the dolomitization model proposed for similar Jurassic successions in the Central Southern Alps. This study indicates that the deformed foreland and thrust fold belts carbonates in Po Plain and Adriatic offshore are suitable to be dolomitized, and therefore reflect an efficient hydrocarbon exploration play.  相似文献   

Crystal chemical and 57Fe Mössbauer study of chromite from the Nuggihalli schist belt (India)     

D. Lenaz  G. B. Andreozzi  S. Mitra  M. Bidyananda  F. Princivalle 《Mineralogy and Petrology》2004,80(1-2):45-57

Summary In the Nuggihalli schist belt (India), chromite bodies were affected by intense serpentinization followed by weathering. In spite of the strong oxidation of the chromite grains, some unaltered cores were preserved, and they were characterised using electron probe microanalysis, single-crystal X-ray diffraction and low temperature ⁵⁷Fe Mössbauer spectroscopy. Results of such investigations revealed that chromite cores from the Nuggihalli schist belt are effectively not oxidised, and their study revealed that chromite was not affected by greenschist-facies metamorphism. The apparently highly ordered cation distribution of the chromites, which would suggest low equilibration temperature, is just caused by the very high Cr contents, which prevent Mg–Al exchange between T and M sites. Using Fabries (1979) geothermometer a temperature of about 1180°C was retrieved (Mitra and Bidyananda, 2003), which therefore corresponds to the quenched-in igneous equilibrium.  相似文献   

Seismic attenuation,normal moveout stretch,and low‐frequency shadows underlying bottom simulating reflector events          下载免费PDF全文

José M. Carcione  Ayman N. Qadrouh  Hervé Perroud  Davide Gei  Jing Ba  Stefano Picotti 《Geophysical Prospecting》2018,66(5):857-871

In many cases, the seismic response of bottom‐simulating reflectors is characterised by low frequencies called “low‐frequency shadow”. Generally, this phenomenon is interpreted as attenuation due to partial saturation with free gas. Actually, this frequency loss may have multiple causes, with a normal moveout stretch as a possible candidate. To analyse this phenomenon, we compute synthetic seismograms by assuming a lossy bottom‐simulating layer, with varying quality factor and thickness, bounded by the upper hydrate‐brine/gas‐brine and lower gas‐brine/brine interfaces. First, we estimate the shift of the centroid frequency of the power spectrum as a function of the travelled distance of the seismic pulse. Then, we perform one‐dimensional numerical experiments to quantify the loss of frequency of the seismic event below the bottom‐simulating reflector as a function of the quality factor of the bottom‐simulating layer and its thickness (due to wave interference). Then, we compute shot gathers to obtain the stacked section, with and without the normal moveout stretch correction and with and without the presence of wave attenuation in the bottom‐simulating layer. The results indicate that the low‐frequency shadow due to the normal moveout stretch is stronger than that due to attenuation and may constitute a false indicator of the presence of gas. In fact, often, the low‐frequency shadow overlies events with higher frequencies, in contradiction with the physics of wave propagation. This is particularly evident when the low‐frequency shadow is so extensive that the presence of high frequencies below cannot be justified by the acquisition geometry.  相似文献   

Recent progress in study on calcareous algae and algal sediments          下载免费PDF全文

Yasufumi Iryu  Davide Bassi 《Island Arc》2017,26(3)

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A Bayesian hierarchical approach for spatial analysis of climate model bias in multi-model ensembles     

Maeregu?Woldeyes?ArisidoEmail author  Carlo?Gaetan  Davide?Zanchettin  Angelo?Rubino 《Stochastic Environmental Research and Risk Assessment (SERRA)》2017,31(10):2645-2657

Coupled atmosphere–ocean general circulation models are key tools to investigate climate dynamics and the climatic response to external forcings, to predict climate evolution and to generate future climate projections. Current general circulation models are, however, undisputedly affected by substantial systematic errors in their outputs compared to observations. The assessment of these so-called biases, both individually and collectively, is crucial for the models’ evaluation prior to their predictive use. We present a Bayesian hierarchical model for a unified assessment of spatially referenced climate model biases in a multi-model framework. A key feature of our approach is that the model quantifies an overall common bias that is obtained by synthesizing bias across the different climate models in the ensemble, further determining the contribution of each model to the overall bias. Moreover, we determine model-specific individual bias components by characterizing them as non-stationary spatial fields. The approach is illustrated based on the case of near-surface air temperature bias in the tropical Atlantic and bordering regions from a multi-model ensemble of historical simulations from the fifth phase of the Coupled Model Intercomparison Project. The results demonstrate the improved quantification of the bias and interpretative advantages allowed by the posterior distributions derived from the proposed Bayesian hierarchical framework, whose generality favors its broader application within climate model assessment.  相似文献   

Dust deposition in the central Mediterranean (Tyrrhenian and Adriatic Seas): Relationships with marine sediments and riverine input     

A. Correggiari  S. Guerzoni  R. Lenaz  G. Quarantotto  G. Rampazzo 《地学学报》1989,1(6):549-558

Major (Al, Ca, Fe, Mg, Mn, Si) and minor (Cd, Pb, Zn) elements of aeolian dust samples collected onboard ship around Italy were analysed, and the concentrations of metal in the dusts were in good agreement with previously published data from the Mediterranean Sea.
The elemental composition of dust samples collected in four subareas (Adriatic, Ionian, Tyrrhenian, and Sicily Channel) was compared with the composition of marine deep sediments obtained in the same regions: Mn, Al, Cd and Zn contents differentiated between the four areas in both sets of samples, suggesting a possible 'geochemical signature' of the atmospheric crustal contribution in marine deep sediments.
An estimate of the relative contribution of atmospheric dry deposition of Cd, Pb and Zn and riverine discharge indicates that: (a) the metals deposited from the atmosphere to the Adriatic basin are a small fraction (2–5%) of those discharged by the Po and Adige rivers; (b) almost the same amounts of Cd, Pb and Zn are delivered to the Tyrrhenian Sea by the atmosphere and by the Arno and Tiber Rivers.  相似文献   

Crystal chemistry of clinopyroxenes from Oligo-Miocene volcanics of Montresta (Sardinia, Italy)     

D. Lenaz  F. Princivalle 《Mineralogy and Petrology》2007,90(3-4):157-166

Summary Augite and diopside crystals from the Oligo-Miocene high-Mg and high-Al basalts, basaltic andesites and andesites of Montresta (Sardinia, Italy) have been analysed by means of X-ray single crystal diffraction and electron microprobe. It has been found that crystallization or equilibration processes took place within the crust at pressures below 5 kbar. In particular, samples from high-Al basalts, basaltic andesites and andesites crystallised at pressures below one kbar while those from high-Mg basalts crystallised in a range from about 1.5 to 4.5 kbar. The intracrystalline temperatures range between about 550 °C for high-Mg basalts and 750 °C for andesites. The M2′ site is occupied in each of the studied crystals, which implies slow cooling rates.  相似文献   

Attenuation tomography: An application to gas-hydrate and free-gas detection   总被引：1，自引：0，他引：1  

Giuliana Rossi  Davide Gei  Gualtiero Böhm  Gianni Madrussani  José M. Carcione 《Geophysical Prospecting》2007,55(5):655-669

We estimate the quality factor (Q) from seismic reflections by using a tomographic inversion algorithm based on the frequency‐shift method. The algorithm is verified with a synthetic case and is applied to offshore data, acquired at western Svalbard, to detect the presence of bottom‐simulating reflectors (BSR) and gas hydrates. An array of 20 ocean‐bottom seismographs has been used. The combined use of traveltime and attenuation tomography provides a 3D velocity–Q cube, which can be used to map the spatial distribution of the gas‐hydrate concentration and free‐gas saturation. In general, high P‐wave velocity and quality factor indicate the presence of solid hydrates and low P‐wave velocity and quality factor correspond to free‐gas bearing sediments. The Q‐values vary between 200 and 25, with higher values (150–200) above the BSR and lower values below the BSR (25–40). These results seem to confirm that hydrates cement the grains, and attenuation decreases with increasing hydrate concentration.  相似文献   

Imposex levels and concentrations of organotin compounds (TBT and its metabolites) in Nassarius nitidus from the Lagoon of Venice     

Bruno Pavoni  Elena Centanni  Sara Valcanover  Marco Fasolato  Silvia Ceccato  Davide Tagliapietra 《Marine pollution bulletin》2007,55(10-12):505

Specimens of Nassarius nitidus were collected in seven stations of the Venice Lagoon to assess the levels of tributyltin (TBT) and its metabolites monobutyltin and dibutyltin in the tissues and monitor their effect on organisms, in particular the phenomenon of imposex (superimposition of male sexual characteristics on females). The following values of population indices were found: vas deferens sequence: 1.2 ± 0.7–4.0 ± 0.5; relative penis length: 6–47%. The least impacted station was situated in the northern part of the Lagoon, where females without imposex were found and Butyltin (BuTs) concentrations in the organisms (average sum of BuTs = 43 ± 14 ng Sn g⁻¹ w.) were significantly lower than in the other stations (range of average sum of BuTs: 101 ± 22–217 ± 27 ng Sn g⁻¹ d.w.). Population indices were found to be related to the TBT content in the tissues. In particular VDSI had a significant logarithmic correlation: r = 0.95, n = 8, p < 0.05.  相似文献   

Melt inclusions in detrital spinel from the SE Alps (Italy–Slovenia): a new approach to provenance studies of sedimentary basins     

Davide Lenaz  Vadim S. Kamenetsky  Anthony J. Crawford  Francesco Princivalle 《Contributions to Mineralogy and Petrology》2000,139(6):748-758

Detrital spinel is a widespread heavy mineral in sandstones from the Maastrichtian–Middle Eocene sedimentary basins in the SE Alps. Chemistry of detrital spinels from the Claut/Clauzetto and Julian Basins (N Italy and NW Slovenia) is used to constrain petrological and geochemical affinities and tectonic provenance of the source rocks. In addition, we have analysed melt inclusion compositions in the detrital volcanic spinels to better constrain the nature of their parental magmas. This is the first study of melt inclusions in detrital spinels. Two principal compositional groups of detrital spinels are recognised based on their TiO₂ and Fe²⁺/Fe³⁺; one derived from peridotites, the other from basaltic volcanics. Peridotitic spinels are more abundant and have TiO₂ < 0.2 wt% and high Cr/Cr + Al (40–90), characteristic of suprasubduction zone harzburgites. Significant chemical variations among volcanic spinels (TiO₂ up to 3 wt%, Al₂O₃ 12–44 wt%) suggest multiple sources, with geochemically distinct characteristics, including MORB-type and backarc basin basalts, subduction-related magmas and tholeiites produced during early continental rifting. Compositions of homogenised melt inclusions in spinels with TiO₂ > 0.2 better distinguish the differences between the compositions of their host spinels and help to further clarify the geodynamic provenance of extrusive source rocks. Several compositional groups of melt inclusions have been recognised and represent diverse magmatism of marginal basins, including MORB- and subduction-related geochemical types, as well as magmas characteristic of early continental rifting. These results, combined with the data on regional ophiolitic complexes and tectonic reconstructions favour the Internal Dinarides of Yugoslavia as a possible source area for the SE Alps sediments. Received: 20 January 2000 / Accepted: 25 April 2000  相似文献