Electron paramagnetic resonance spectroscopy: A suggested approach to trace metal analysis in marine environments     

Bruce A. Burgess  N. Dennis Chasteen  Henri E. Gaudette 《Environmental Geology》1975,1(3):171-180

Electron paramagnetic resonance (EPR) spectroscopy analysis of marine samples from different environments appears to differentiate between adsorbed and structural Mn (II) and Fe (III) sites in the sediment. This suggests that EPR may provide a means of distinguishing different environmental influences on sediment. Acid extract solutions from sediment samples exhibit clearly defined EPR spectra due to Mn(II), Ti(III), Fe(III), and VO(IV), which are amenable to qualitative and quantitative analysis at concentrations below one part per million. Spectra of several shellfish vary considerably, both between species, and within a species, depending on sampling localities. Resonances from Mn(II), Mo(V), and Fe(III) can be obtained. Mn(II) is substituted for Ca(II) in the calcite structure of some shells. The low detection limits, small sample size, required and identification of oxidation states by EPR complement other analytical techniques and may prove useful in marine systems.  相似文献   

Mercury in fluvial bed sediments subsequent to contamination     

Dennis G. Waslenchuk 《Environmental Geology》1975,1(3):131-136

Once inputs of mercury-bearing effluents to a fluvial system are stopped, levels of contamination will decline slowly to background values. Crystalline mercury phases will dissolve in response to lowered aqueous mercury concentrations, and aqueous Hg(OH)₂ will desorb from ferric hydroxide grain coatings as the coatings age to more ordered phases. In the Ottawa River, mercury concentrations in bed sediments are declining by about 50 percent annually. Editor's note: Waslenchuk is now with the Georgia Institute of Technology School of Geophysical Sciences, Atlanta, Georgia 30332, U.S.A.  相似文献   

Seafloor spreading history of the Agulhas Basin     

John L. Labrecque  Dennis E. Hayes 《Earth and Planetary Science Letters》1979,45(2):411-428

Data gathered by recent “Islas Orcadas” cruises reveal the seafloor spreading pattern for a region south of the Agulhas/Falkland fracture zone system. The presence of a magnetic anomaly bight about the Agulhas Plateau indicates that the Agulhas Plateau may have developed at the site of a tectonic plate triple junction during the Late Cretaceous. A westward jump in the seafloor spreading center during the Late Maestrichtian (anomaly 34?31) reduced the offset across the Falkland/Agulhas fracture zone system and resulted in the formation of two conjugate aseismic ridges here described as the Meteor and Islas Orcadas Rises. The magnetic lineation pattern in the Agulhas Basin suggests that a tectonic plate (Malvinas Plate) existed during Campanian to Maestrichtian times. Relative rates of motion are calculated for Antarctica, South America, and Africa for the Late Cretaceous.  相似文献   

Antithethic and homothetic faults     

J. G. Dennis  V. C. Kelley 《International Journal of Earth Sciences》1980,69(1):186-193

Antithetic faults are dip slip faults that displace rocks so as to prevent or reduce structural relief, typically producing tilted fault blocks. They may or may not occur in conjugate systems with their opposites, homothetic faults, which serve to increase structural relief. Several examples serve to illustrate the concept and to correct current misunderstandings.

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Zusammenfassung Die Arbeit soll die Begriffe antithetisch und homothetisch klären helfen. Antithetische Verschiebungen wirken dem tektonischen Relief entgegen, homothetische Verwerfungen unterstützen es. Die Begriffe werden an einigen Beispielen erläutert.

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Résumé Ce travail constitue une tentative d'élucider les termes »antithétique« et »homothétique«. Le rejet des failles antithétiques s'oppose à la création d'un relief tectonique. Le rejet des failles homothétiques augmente ce relief. Quelques exemples sont discutés.

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Atmospheric effects in the remote sensing of phytoplankton pigments   总被引：3，自引：0，他引：3  

Howard R. Gordon  Dennis K. Clark 《Boundary-Layer Meteorology》1980,18(3):299-313

We investigate the accuracy with which relevant atmospheric parameters must be estimated to derive phytoplankton pigment concentrations (chlorophyll a plus phaeophytin a ) of a given accuracy from measurements of the ocean's apparent spectral radiance at satellite altitudes. The analysis is limited to an instrument having the characteristics of the Coastal Zone Color Scanner scheduled to orbit the Earth on NIMBUS-G. A phytoplankton pigment algorithm is developed which relates the pigment concentration (C) to the three ratios of upwelling radiance just beneath the sea surface which can be formed from the wavelengths () 440, 520 and 550 nm. The pigment algorithm explains from 94 to 98% of the variance in log₁₀ C over three orders of magnitude in pigment concentration. This is combined with solutions to the radiative transfer equation to simulate the ocean's apparent spectral radiance at satellite altitudes as a function of C and the optical properties of the aerosol, the optical depth of which is assumed to be proportioned to ^-n . A specific atmospheric correction algorithm, based on the assumption that the ocean is totally absorbing at 670 nm, is then applied to the simulated spectral radiance, from which the pigment concentration is derived. Comparison between the true and derived values of C show that: (1) n is considerably more important than the actual aerosol optical thickness; (2) for C 0299-1 0.2 g l^-1 acceptable concentrations can be determined as long as n is not overestimated; (3) as C increases, the accuracy with which n must be estimated, for a given relative accuracy in C, also increases; and (4) for C greater than about 0.5 g 1^-1, the radiance at 440 nm becomes essentially useless in determining C. The computations also suggest that if separate pigment algorithms are used for C 1gl^-1 and C 1 gl^-1, accuracies considerably better than ±± in log C can be obtained for C 1 g l^-1 with only a coarse estimate of n, while for C 10 gl^-1, this accuracy can be achieved only with very good estimates of n.Contribution No. 387 from the NOAA/ERL Pacific Environmental Laboratory.On leave from Department of Physics, University of Miami, Coral Gables, Florida.  相似文献   

Interpretation of temporal features in an unusual X-ray and microwave burst     

A. L. Mackinnon  J. E. R. Costa  P. Kaufmann  B. R. Dennis 《Solar physics》1986,104(1):191-198

Observations are briefly discussed of an event in which microwave and hard X-ray emissions were not correlated in the accepted way. Two impulsive peaks of roughly equal intensity were observed at three different microwave frequencies. The hard X-ray peaks accompanying these, however, differ in intensity by almost two orders of magnitude. Various possible interpretations of this burst are discussed, in the context of familiar models of these emissions. The most likely explanation is that the electron spectrum in the first burst has a break at about 350 keV. General implications for interpretation of X-rays and microwaves are discussed.Proceedings of the Workshop on Radio Continua during Solar Flares, held at Duino (Trieste), Italy, 27–31 May, 1985.  相似文献   

环境管制对佛山市污染密集型企业空间格局变化的影响——基于2004年、2008年、2013年经济普查数据的实证   总被引：2，自引：0，他引：2  

沈静  刘伟  魏也华 《地理科学》2019,39(12):1972-1981

以佛山市2004年、2008年和2013年3次经济普查数据库中的污染密集型企业为研究对象,采用格数据空间回归模型,研究了佛山市污染密集型企业空间格局变化特征,并探究了环境管制对污染密集型企业及不同行业的企业空间格局变化的影响。研究发现:① 环境管制严格程度的变化使其从影响企业区位变动次要因素逐渐成为推动企业空间格局变化的重要因素,说明了环境管制变化会引起其对污染密集型企业区位变动作用程度的变化。② 在城市内部尺度,地方政府权衡污染行业整治利弊后,针对不同区域不同行业制定的差异化环境管制力度和模式,形成了不同行业空间格局响应的差异。研究结果对理解环境管制影响污染行业空间格局变化提供更微观的视角,对环境管制政策实现企业更替和产业升级具有一定启示,也对政府产业和环境政策制定具有借鉴意义。  相似文献   

A MEXICAN CORPORATE CAMPAIGN IN CONSERVATION     

Ernst Griffin  Howard W. Dennis 《The Professional geographer》1969,21(5):358-359

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Nutrient flux into an intense deep chlorophyll layer in a mode-water eddy     

James R. Ledwell  Dennis J. McGillicuddy Jr.  Laurence A. Anderson   《Deep Sea Research Part II: Topical Studies in Oceanography》2008,55(10-13):1139

An intense deep chlorophyll layer in the Sargasso Sea was reported near the center of an anticyclonic mode-water eddy by McGillicuddy et al. [2007. Eddy–wind interactions stimulate extraordinary mid-ocean plankton blooms, Science, accepted]. The high chlorophyll was associated with anomalously high concentrations of diatoms and with a maximum in the vertical profile of ¹⁴C primary productivity. Here we report tracer measurements of the vertical advection and turbulent diffusion of deep-water nutrients into this chlorophyll layer. Tracer released in the chlorophyll layer revealed upward motion relative to isopycnal surfaces of about 0.4 m/d, due to solar heating and mixing. The density surfaces themselves shoaled by about 0.1 m/d. The upward flux of dissolved inorganic nitrogen, averaged over 36 days, was approximately 0.6 mmol/m²/d due to both upwelling and mixing. This flux is about 40% of the basin wide, annually averaged, nitrogen flux required to drive the annual new production in the Sargasso Sea, estimated from the oxygen cycle in the euphotic zone, the oxygen demand below the euphotic zone, and from the ³He excess in the mixed layer. The observed upwelling of the fluid was consistent with theoretical models [Dewar, W.K., Flierl, G.R., 1987. Some effects of wind on rings. Journal of Physical Oceanography 17, 1653–1667; Martin, A.P., Richards, K.J., 2001. Mechanisms for vertical nutrient transport within a North Atlantic mesoscale eddy. Deep-Sea Research II 48, 757–773] in which eddy surface currents cause spatial variations in surface stress. The diapycnal diffusivity at the base of the euphotic zone was 3.5±0.5×10⁻⁵ m²/s. Diapycnal mixing was probably enhanced over more typical values by the series of storms passing over the eddy during the experiment and may have been enhanced further by the trapping of near-inertial waves generated within the eddy.  相似文献   

The oxygen isotope composition of water masses within the North Sea     

Andrew J.P. Harwood  Paul F. Dennis  Alina D. Marca  Graham M. Pilling  Richard S. Millner 《Estuarine, Coastal and Shelf Science》2008

Based on measurements of the ¹⁸O isotope composition of 247 samples collected over a 3-year period we have assessed the oxygen isotope composition of water masses in the North Sea. This is the first δ¹⁸O data set that covers the entire North Sea basin. The waters lie on a mixing line: δ¹⁸O (‰_VSMOW) = −9.300 + 0.274(S) with North Atlantic sub-polar mode water (SPMW) and surface waters, and Baltic Sea water representing the saline and freshwater end members respectively. Patterns exhibited in surface and bottom water δ¹⁸O distributions are representative of the general circulation of the North Sea. Oxygen-18 enriched waters from the North Atlantic enter the North Sea between Scotland and Norway and to a lesser extent through the English Channel. In contrast, oxygen-18 depleted waters mainly inflow from the Baltic Sea, the rivers Rhine and Elbe, and to a lesser degree, the Norwegian Fjords and other river sources. Locally the δ¹⁸O–salinity relationship will be controlled by the isotopic composition of the freshwater inputs. However, the range of local freshwater compositions around the North Sea basin is too narrow to characterise the relative contributions of individual sources to the overall seawater composition. This dataset provides important information for a number of related disciplines including biogeochemical research and oceanographic studies.  相似文献