The qualitative zoning record of minerals. A method for determining the duration of metamorphic events?     

K. Stüwe  K. Ehlers 《Mineralogy and Petrology》1996,56(3-4):171-184

Summary The efficacy of ion exchange in petrological systems, for example the Fe-Mg exchange between garnet and biotite, is a function of grainsize, temperature, rates of temperature change and diffusion parameters. The combination of these variables determines the final zoning profile of minerals. Therefore, zoning profiles may be used to derive one of these variables if the others are known. For example, a mineral grain that experienced a short thermal event may still preserve a zoning profile characteristic of the heating path. In contrast, if that grain experienced a long thermal event it may develop a zoning profile typical of the cooling path. Conversely, for the same temperature-time cycle, large grains may not completely equilibrate at the metamorphic peak, and in smaller grains any previous record may have been erased. This is commonly observed in natural rocks where different grains within one thin section preserve often qualitatively different zoning profiles. Thus, a critical grainsize,l _crit, may exist that separates grains with qualitatively different zoning profiles so that grains of sizel > l _crit still retain zoning information about the heating path and grains of sizel <l _crit contain only information about the cooling path. If the critical grainsize can be measured and an independent estimate for the peak metamorphic temperature exists, the duration of the thermal event may, in principle, be estimated.The applicability of this method to natural garnets is hampered by a range of uncertainties. However, a parameterisation of the critical grain size may be used to illustrate the relative importance of grain size, temperature and event duration to the equilibration of minerals. In this paper, the critical grainsize is parameterized for various temperature-time cycles and its dependence on diffusion parameters is discussed. It is shown that, for Barrovian conditions,l _crit between 0.1 and 1 mm separates garnets retaining prograde information from garnets retaining cooling path information. For illustration, we compare the results with the critical grainsize of garnets from two metamorphic terranes, the Prydz Bay region (Antarctica) and the Koralm complex (Eastern Alps). Despite the large range of uncertainties attached to the method, it is shown that the critical grainsize of garnets in both terranes is consistent with a very short duration of the last thermal event that affected the two regions.

---

Die qualitative Form von Zonierungsprofilen in Mineralen. Information über die Dauer metamorpher Ereignisse?

Zusammenfassung Zonierungsprofile von Paragenesen im Ionenaustausch, zum Beispiel das Fe-Mg Austauschsgleichgewicht zwischen Granat und Biotit, sind eine Funktion von (i) Korngröße, (ii) Temperatur, (iii) Kühl- und Heizgeschwindigkeit sowie (iv) den Diffusionskonstanen. Es sollte daher möglich sein, Zonierungsprofile dazu zu verwenden, einen dieser Parameter zu bestimmen, wenn die anderen bekannt sind. Zonierungsprofile von Kristallen die ein kurzes thermisches Ereignis erfahren haben, mögen daher prograde Information beinhalten, wogegen derselbe Kristall ein retrogrades Profil aufweisen mag, wenn er einem langlebigen thermischen Ereignis unterlag (prograd und retrograd ist hier als: bei ansteigender Temperatur und bei abfallender Temperatur definiert). In Kristallen die dem gleichen Temperatur-Zeitpfad unterworfen waren, könnten kleine Körner nur die Kühlgeschichte dokumentieren, wogegen große noch Zonierungsinformation vom Heizpfad aufweisen. In natürlichen Gesteinen wird das oft dadurch beobachtet, daß verschiedene Körner auseinem Dünnschliff qualitativ verschiedene Zonierungsprofile aufweisen. Es ist daher möglich eine kritische Korngöße,l _crit, zu definieren, die Korngrößen mit qualitativ verschiedenen Zonierungsprofilen voneinander trennt. Körner mit einem Durchmesserl > l _crit haben, zumindest teilweise, noch prograde Profile, wogegen Körner mitl <l _crit nur retrograde Information dokumentieren. Wenn man diese kritische Korngröße messen kann, sollte sie dazu benutzt werden können, etwas über die Dauer des thermischen Ereignisses auszusagen.Die Anwendbarkeit dieser Methode ist durch eine Reihe von Fehlern limitiert. Nichtsdestotrotz, ist eine Parameterisierung der kritischen Korngröße nützlich um die relative Wichtigkeit von Korngröße, Temperatur und Zeit, für die Entwicklung von Zonierungsprofilen, zu illustrieren. Unser Modell kann dazu benutzt werden, um die Größenordnung von Granaten abzuschätzen, die noch prograde Information dokumentieren können. Die Abhängigkeit der kritischen Korngröße von Diffusionsparametern und der Form des Temperatur-Zeit Pfades wird ebenfalls diskutiert. Es wird gezeigt, daß für Metamorphose in der mittleren Grünschiefer und Amphibolit fazies,l _crit zwischen 0.1 and 1 mm prograd zonierte von retrograd zonierten Granaten trennt. Um das Modell zu illustrieren, werden die Ergebnisse auf die Prydz Bay Region (Antarktis) und den Koralm Komplex (Ostalpen) angewendet. Trotz der großen Fehlergrenzen der Methode glauben wir zeigen zu können, daß die kritische Korngröße beider Terrains andeutet, daß das letzte thermische Ereignis in beiden Gebieten kurzlebig war.

---

---

With 5 Figures  相似文献   

A window to the operation of microplate tectonics in the Tethys Ocean: the geochemistry of the Samothrace granite,Aegean Sea     

K. St. Seymour  V. Tsikouras  K. Kotopouli  K. Hatzipanayiotou  G. Pe-Piper 《Mineralogy and Petrology》1996,56(3-4):251-272

Summary The island of Samothrace, northeastern Aegean Sea, consists of five main geological units: (i) A basement unit consisting of low grade metamorphic rocks (metapelites, marbles, metavolcanic rocks, and a metaconglomerate); (ii) an ophiolitic complex with K-Ar hornblende date of 154 ± 7 and 155 ± 7 Ma; (iii) A granite intrusion with biotite K-Ar dates of 14.5 ± 0.3 and 14.5 ± 0.5 Ma, and a contact metamorphic event dated at 40.9 + 2.2 Ma; (iv) a unit of Cenozoic volcanic rocks: orogenic volcanism apparently occurred in two cycles with Upper Eocene tholeiitic to calc-alkaline volcanic rocks and post-Eocene high-K andesites to trachytes. (v) Quaternary clastic sedimentary rocks which occur around the peripheral parts of the island. The granitic intrusion is predominantly a hornblende-biotite granite, granodiorite or quartz monzonite, with porphyritic variants and mafic enclaves. The pluton is cut by granophyre, aplite and rare granodioritic veins. All lithological units of the Samothrace intrusion show smooth and continuous major element trends and similar chondrite- and Ocean Ridge Granite-normalized incompatible element profiles. ORG-normalized incompatible element contents of Hf, Zr, Sm are explained with fractionation close to the normalizing values Y and Yb contents combined with high K/Yb ratios; Rb and Th are significantly enriched relative to Nb and Ta. In Y-Nb and Rb-SiO₂ space most samples of the Samothrace granite, plot in the volcanic arc and the syn-collisional granite fields. In Y + Nb-Rb space they are equally distributed within and transgress these two domains. The geochemical and regional data suggest a subduction or collision environment but biotite mineral data do not support a collisional setting for magma genesis. The Samothrace granite was probaby associated with a post-collisional domain after the closure of the Axios section of the Tethys Ocean.

---

Ein Einblick in das Wirken von Mikroplattentektonik in der Tethys—Die Geochemie des Samothrake Granites, Agäisches Meer

Zusammenfassung Die Insel Samothrake in der nordöstlichen Ägäis besteht aus fünf geologischen Haupteinheiten: (i) einem schwach metamorphen Basement (Metapelite, Marmore, Metavulkanite und Metakonglomerate); (ii) einem ophiolithischem Komplex, der mit K-Ar Datierungen an Hornblende ein Alter von 154 ± 7 und 155 ± 7 Ma ergab; (iii) ein granitischer Intrusionskörper mit K-Ar Altern an Biotit von 14.0 ± 0.3 und 14.5 ± 0.5 Ma und einem kontaktmetamorphen Ereignis, das mit 40.9 ± 2.2 Ma datiert ist; (iv) eine Abfolge känozoischer Vulkanite, wobei der orogene Vulkanismus offensichtlich in zwei Zyklen ablief mit tholeiitischen bis kalkalkalischen Vulkaniten im oberen Eozän und high-K Andesiten bis Trachyten im post-Eozän; (v) quartären klastischen Sedimentgesteinen, die im Randbereich der Insel auftreten. Die Granitintrusion setzt sich hauptsächlich aus Hornblende-Biotitgraniten, Granodioriten oder Quarzmonzoniten mit teilweise porphyrischen und mafischen Enklaven enthaltenden Varietäten zusammen. Der Pluton wird von Granophyren, Apliten und seltener von granodioritischen Gängen durchschlagen. Alle lithologischen Einheiten der Samothrake Intrusion zeigen kontinuierliche Hauptelementtrends und ähnliche Chondrit und ORG-normalisierte inkompatible Elementprofile. Die Gehalte an den inkompatiblen Elementen Hf, Zr, Sm sind sehr ähnlich denen von ozeanischen Graniten (ORG). Die niedrigen Y und Yb-Gehalte und die hohen K/Yb Verhältnisse werden durch Fraktionierung erklärt. Rb und Th sind signifikant angereichert im Vergleich zu Nb und Ta. In Y-Nb und Rb-SiO₂ Diagrammen plotten die meisten Proben des Samothrake Granites im Feld der vulkanischen Inselbogen- und Synkollisionsgranite. Im Y + Nb-Rb Diagramm zeigt sich eine gleichmäßige und überlappende Verteilung. Die geochemischen und regionalen Daten weisen auf einen Subduktions- oder Kollisionsbereich hin, obwohl die Biotitzusammensetzungen nicht für eine Bildung der Magmen in einem Kollisionsbereich sprechen. Die Bildung des Samothrake Granites steht möglicherweise mit post-Kollisionstektonik nach dem Schließen der Axioszone in der Tethys in Zusammenhang.

---

---

With 7 Figures  相似文献   

Bayesian estimation of seismic hazard for two sites in Switzerland     

Erik Rüttener  Juan José Egozcue  Dieter Mayer-Rosa  Stephan Mueller 《Natural Hazards》1996,14(2-3):165-178

Seismic hazard analysis is based on data and models, which both are imprecise and uncertain. Especially the interpretation of historical information into earthquake parameters, e.g. earthquake size and location, yields ambiguous and imprecise data. Models based on probability distributions have been developed in order to quantify and represent these uncertainties. Nevertheless, the majority of the procedures applied in seismic hazard assessment do not take into account these uncertainties, nor do they show the variance of the results. Therefore, a procedure based on Bayesian statistics was developed to estimate return periods for different ground motion intensities (MSK scale).Bayesian techniques provide a mathematical model to estimate the distribution of random variables in presence of uncertainties. The developed method estimates the probability distribution of the number of occurrences in a Poisson process described by the parameter . The input data are the historical occurrences of intensities for a particular site, represented by a discrete probability distribution for each earthquake. The calculation of these historical occurrences requires a careful preparation of all input parameters, i.e. a modelling of their uncertainties. The obtained results show that the variance of the recurrence rate is smaller in regions with higher seismic activity than in less active regions. It can also be demonstrated that long return periods cannot be estimated with confidence, because the time period of observation is too short. This indicates that the long return periods obtained by seismic source methods only reflects the delineated seismic sources and the chosen earthquake size distribution law.  相似文献   

Thermodynamic data from redox reactions at high temperatures. IV. Calibration of the Re-ReO2 oxygen buffer from EMF and NiO+Ni-Pd redox sensor measurements     

Mark I. Pownceby  Hugh St. C. O'Neill 《Contributions to Mineralogy and Petrology》1994,118(2):130-137

The chemical potential of oxygen defined by the equilibrium:

相似文献    25. Thermodynamic data from redox reactions at high temperatures. II. The MnO-0Mn3O4 oxygen buffer,and implications for the thermodynamic properties of MnO and Mn3O4      Hugh St. C. O'Neill  Mark I. Pownceby 《Contributions to Mineralogy and Petrology》1993,114(3):315-320 The \(\mu _{O_2 } \) defined by the reaction 6 MnO+O2 =2 Mn3O4 has been determined from 917 to 1,433 K using electrochemical cells (with calcia-stabilized zirconta, CSZ) of the type: Steady emfs were achieved rapidly at all temperatures on both increasing and decreasing temperature, indicating that the MnO-Mn3O4 oxygen buffer equilibrates relatively easily. It therefore makes a useful alternative choice in experimental petrology to Fe2O3-Fe3O4 for buffering oxygen potentials at oxidized values. The results are (in J/mol, temperature in K, reference pressure 1 bar); \(\mu _{O_2 } \) (±200)=-563,241+1,761.758T-220.490T inT+0.101819T 2 with an uncertainty of ±200 J/mol. Third law analysis of these data, including a correction for the deviations in stoichiometry of MnO, impliesS 298.15 for Mn3O4 of 166.6 J/K · mol, which is 2.5 J/K · mol higher than the calorimetric determination of Robie and Hemingway (1985). The low value of the calorimetric entropy may be due to incomplete ordering of the magnetic spins. The third law value of Δ r H 298.15 0 is-450.09 kJ/mol, which is significantly different from the calorimetric value of-457.5±3.4 kJ/mol, calculated from Δ f H 298.15 0 of MnO and Mn3O4, implying a small error in one or both of these latter.  相似文献    26. Ozone production due to emissions from vegetation burning      Günter Helas  Jürgen Lobert  Dieter Scharffe  Luise Schäfer  Johann Goldammer  Jean Baudet  Brou Ahoua  Ayité-Lô Ajavon  Jean-Pierre Lacaux  Robert Delmas  Meinrat O. Andreae 《Journal of Atmospheric Chemistry》1995,22(1-2):163-174 Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input.  相似文献    27. Geochemistry of the Grenville Dyke Swarm: role of plume-source mantle in magma genesis      Karen St. Seymour  P. Stephen Kumarapeli 《Contributions to Mineralogy and Petrology》1995,120(1):29-41 Major and trace element data of samples from the approximately 590 Ma Grenville dyke swarm, in the southeastern parts of the Canadian Shield, were used to evaluate the extent of crustal contamination of the dyke magma and to model its probable mantle source. The dyke rocks are mostly saturated, quartz tholeiites. A few samples represent transitional basalts. Their overall chemistries are similar to those of continental flood basalts. Their compositions resemble those of liquids initially produced in the garnet peridotite mantle zone and then subjected to polybaric fractionation. However, fractionation models fail to mass-balance Ti, Fe, K, and P. Geochemical and isotopic criteria indicate that crustal contamination was minimal. The incompatible elements Zr, Y, K, Rb, Nb, V, Ta, Hf, and Th show hyperbolic elemental ratio-ratio distributions indicative of mixing between two end-members. One end-member has elemental ratios similar to those of a depleted N-MORB source and the second of a P-MORB i.e. ertile or plume MORB source. The more enriched dyke compositions can be successfully reproduced by mixing models in the ratio of 6:1 between the most depleted MORB-like dyke magma and a liquid composition similar to metasomatic glass veinlets coexisting with mica peridotite mantle xenoliths, and subsequent crystal fractionation. The Grenville dykes are probably a synrift swarm that was emplaced along a rift arm related to an Iapetan rrr triple junction that is thought to have formed over a mantle plume. The chemistry of the dyke swarm is consistent with its derivation from a plume head, in that the minor enriched source can be identified with plume-source mantle and the major depleted source with entrained mantle. The magma probably originated in the upper cooler parts of the plume head.  相似文献    28. Some remarks on certain special BDT-FRW solutions      Dieter Lorenz-Perzold 《Astrophysics and Space Science》1984,106(2):415-417 We wish to point out that the BDT-FRW (k=1) special dust solution obtained by Dehnen and Obregón (1971) and the BDT-FRW (k=1) radiation solution given by Obregón and Chauvet (1978) are contained as special cases in the special perfect fluid Jordan-Brans-Dicke solution first given by Brill (1962). In addition we give a simple proof that the special BDT-FRW (k=1) vacuum solution given by Dehnen and Obregón (1972) does not exist. We finally consider the special case =0 and present some new solutions.  相似文献    29. Comment on the LRS-BDT-Bianchi type-V vacuum solution      Dieter Lorenz-Petzold 《Astrophysics and Space Science》1984,103(2):395-396 We wish to point out that the anisotropic LRS-BDT-Bianchi type-V vacuum solution recently given by Ram and Singh is wrong. Moreover, the correct solution is nothing but an isotropic FRW (k=–1) solution given by us previously.  相似文献    30. The main problem of lunar theory solved by the method of Brown      Dieter S. Schmidt 《Earth, Moon, and Planets》1980,23(2):135-164 Brown's method for solving the main problem of lunar theory has been adapted for the computation by machine with the help of an algebraic processor. Brown's results are first recovered and refined. The solution is then expanded to include most terms of order nine. The terms in the series for the longitude and latitude are listed with an accuracy of 0.000 01 and of 0.000 001 for the parallax.This research was supported in parts by the National Science Foundation grant MCS 78-01425.  相似文献    [首页] « 上一页 [1] [2] 3 [4] [5] [6] [7] [8] [9] [10] [11] 下一页 » 末  页»