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51.
The membrane interface probe (MIP) is widely used to characterize the subsurface distribution of volatile organic compounds (VOCs). One problem that arises during MIP application is that disproportionately high MIP signals are obtained after passing source zones which contain mobile or residual phases. This serious problem occurs because of a carry-over effect, in particular caused by compound-specific retention times in the conventional unheated transfer line, commonly used during such an investigation. The objective of this study was to perform a qualitative methodical field evaluation of the carry-over effect of a conventional MIP system with a conventional unheated transfer line. This was achieved by coupling a mobile mass spectrometer to the MIP device. Results obtained were then further compared with those achieved using a laser induced fluorescence (LIF) system. Because of this coupling, time- and depth-dependent signals for different substances became known. Field evaluation data obtained showed complex superpositions of compounds with MIP system results. As a result of this superposition, MIP signals from the saturated zone beneath the source zone (zone with free and/or residual phase) are blurred and are therefore not representative of particular depths. However, utilizing multidirectional probing alongside conventional MIP probing (forwards and backwards), it was possible to detect the upper and lower phase boundary of the source zone. These MIP results correlated excellently with the LIF results. An important conclusion that can be drawn from the field investigation is that coupling a mobile mass spectrometer to the MIP system enables advanced MIP signal interpretation to be successfully achieved.  相似文献   
52.
53.
Environmental changes of the last 9,300 years were reconstructed by geochemical and pollen analyses of a 14-m-long, laminated sediment core from Lago Aleixo, south-eastern Brazil. Fossil pollen assemblages indicate open savannah vegetation (campo cerrado) and gallery forests until approximately 6,900 cal. BP. During that time, siderite laminae were deposited under anoxic conditions at the lake bottom. Then, increased rainfall and a shorter annual dry period allowed gallery forests and semi-deciduous forests to expand, leading to more closed cerrado vegetation. High-intensity rainfall events during this period are recorded as peaks in K and Ti concentrations. The sediment facies during this period consists of alternating layers of diatoms and minerogenic matter. C/N ratios imply that algae and perhaps soils, too, were the main contributors to sediment organic matter. Biogenic silica and δ13Corg variations indicate increasing primary productivity, which was related to higher nutrient flux from intensified leaching of soils, as shown by rising K/Al ratios. Around 800 cal. BP, a closed, semi-deciduous forest developed under present-day climate conditions. Slope stabilization diminished erosion processes in the catchment and caused reduced input of minerogenic matter into the basin. Human impact is evident in the topmost homogeneous sediments, as removal of the stabilizing forest cover amplified soil erosion. The continuous trend to more humid conditions during the Holocene probably reflects increased influence of the Amazon Basin as a moisture source. We conclude that the Lago Aleixo sediment archive was a sensitive recorder of environmental dynamics in tropical South America, which were mainly controlled by changes in precipitation patterns.  相似文献   
54.
Temporal shifts in phenology or vegetation period of plants are seen as indicators of global warming with potentially severe impacts on ecosystem functioning. In spite of increasing knowledge on drivers, it is of utmost importance to disentangle the relationship between air temperatures, phenological events, potential temporal lags (phase shifts) and time scale for certain plant species. Assessing the phase shifts as well as the scale-dependent relationship between temperature and vegetation phenology requires the development of a nonlinear temporal model. Therefore, we use wavelet analysis and present a framework for identifying scale-dependent cross-phase coupling of bivariate time series. It allows the calculation of (a) scale-dependent decompositions of time series, (b) phase shifts of seasonal components in relation to the annual cycle, and (c) inter-annual phase differences between seasonal phases of different time series. The model is applied to air temperature data and remote sensing phenology data of a beech forest in Germany. Our study reveals that certain seasonal changes in amplitude and phase with respect to the normal annual rhythm of temperature and beech phenology are coupled time-delayed components, which are characterized by a time shift of about one year.  相似文献   
55.
The M w 6.2 Baladeh earthquake occurred on 28 May 2004 in the Alborz Mountains, northern Iran. This earthquake was the first strong shock in this intracontinental orogen for which digital regional broadband data are available. The Baladeh event provides a rare opportunity to study fault geometry and ongoing deformation processes using modern seismological methods. A joint inversion for hypocentres and a velocity model plus a surface-wave group dispersion curve analysis were used to obtain an adapted velocity model, customised for mid- and long-period waveform modelling. Based on the new velocity model, regional waveform data of the mainshock and larger aftershocks (M w ?≥3.3) were inverted for moment tensors. For the Baladeh mainshock, this included inversion for kinematic parameters. All analysed earthquakes show dominant thrust mechanisms at depths between 14 and 26 km, with NW–SE striking fault planes. The mainshock ruptured a 28° south-dipping area of 24 × 21 km along a north-easterly direction. The rupture plane of the mainshock does not coincide with the aftershock distribution, neither in map view nor with respect to depth. The considered aftershocks form two main clusters. The eastern cluster is associated with the mainshock. The western cluster does not appear to be connected with the rupture plane of the mainshock but, instead, indicates a second activated fault plane dipping at 85° towards the north.  相似文献   
56.
The objective of this study is to analyse adaptable debris-flow impact models, which are very important for mitigation measurements and buildings using their sphere of influence. For this reason, 16 debris-flow experiments, on a small-scale modelling approach, were performed. Impact forces were measured with a force plate panel, consisting of 24 aluminium devices, coaxially mounted with resistance strain gauges. Flow velocities, flow heights as well as horizontal impact forces were sampled with a frequency of 2.4 kHz. Sub datasets of sampled raw force data were defined by applying an average median filter, a low-pass filter routine. Further, estimated peak pressure values as well as empirical coefficients of hydraulic impact models were compared, and the influence of signal processing is discussed.  相似文献   
57.
In laboratory experiments, the cold-water coral Lophelia pertusa was exposed to settling particles. The effects of reef sediment, petroleum drill cuttings and a mix of both, on the development of anoxia at the coral surface were studied using O2, pH and H2S microsensors and by assessing coral polyp mortality. Due to the branching morphology of L. pertusa and the release of coral mucus, accumulation rates of settling material on coral branches were low. Microsensors detected H2S production in only a few samples, and sulfate reduction rates of natural reef sediment slurries were low (<0.3 nmol S cm−3 d−1). While the exposure to sediment clearly reduced the coral’s accessibility to oxygen, L. pertusa tolerated both partial low-oxygen and anoxic conditions without any visible detrimental short-term effect, such as tissue damage or death. However, complete burial of coral branches for >24 h in reef sediment resulted in suffocation.  相似文献   
58.
Various flow visualization techniques are briefly reviewed, most significantly those using flow streamers and tracers. Special consideration is then given to the dust deposition techniques method that is seldom used but is of particular interest and utility to the physical geographer concerned with fluid flow phenomena. Several examples are provided, using Belgian loess as a tracer, and the advantages and disadvantages of the system are evaluated. The method may also be used in the field. [Key words: geomorphology, fluid dynamics, flow visualization, dust deposition.]  相似文献   
59.
Reaction textures and fluid inclusions in the~2.0 Ga pyroxene-bearing dehydration zones within the Sand River biotite-hornblende orthogneisses(Central Zone of the Limpopo Complex) suggest that the formation of these zones is a result of close interplay between dehydration process along ductile shear zones triggered by H2O-CO2-salt fluids at 750—800℃and 5.5—6.2 kbar.partial melting,and later exsolution of residual brine and H2O-CO2 fluids during melt crystallization at 650—700℃.These processes caused local variations of water and alkali activity in the fluids,resulting in various mineral assemblages within the dehydration zone.The petrological observations are substantiated by experiments on the interaction of the Sand River gneiss with the H2O-CO-2-(K,Na)Cl fluids at 750 and 800℃and 5.5 kbar.It follows that the interaction of biotite-amphibole gneiss with H2O-CO2-(K.Na)Cl fluids is accompanied by partial melting at 750—800℃.Orthopyroxene-bearing assemblages are characteristic for temperature 800℃and are stable in equilibrium with fluids with low salt concentrations,while salt-rich fluids produce clinopyroxene-bearing assemblages.These observations arc in good agreement with the petrological data on the dehydration zones within the Sand River orthoeneisses.  相似文献   
60.
The influence of varying groundwater flow velocities on DNAPL infiltration and spreading behaviour was investigated by multiphase modelling using TMVOC and PetraSim. The multiphase models were calibrated by results of previously conducted laboratory experiments for the complete spatio-temporal range of the experiments. The small scale 2D scenario modelling was applied to qualify and quantify changes in position, architecture, geometry and dissolution of a TCE body in a fully saturated homogeneous sandy medium. The applied flow velocities ranging from 0.05 up to 40.00 m/day exhibited that the DNAPL TCE is affected even at the lowest flow velocity in its position, its size and its architecture. Additionally, several impermeable lenses with simple geometry were assumed in the model, to investigate the influence of stratified subsoil. In the experimental set-ups, the DNAPL body reacts more sensitive to the applied groundwater flow velocities than to the geometrical set-up of the scenarios. A possible consequence can be the transportation and displacement of a DNAPL pool due to natural or anthropogenic induced high groundwater flow velocities, as by Pump and Treat facilities, complicating site investigation process and planning of remediation activities.  相似文献   
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