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101.
Microbial activity has the potential to alter all cultural heritage in mining and metallurgy, due to metal mobilization by leaching. This communication shows the consequences of the bioleaching ability of two natural enrichments on copper slag samples from a historic ore smelting site in Sangerhausen (Mansfeld, Südharz, Saxony-Anhalt, Germany). Enrichment cultures gained from mine drainage were dominated by either the iron and sulfur-oxidizing Acidithiobacillus ferrivorans, or by the iron-oxidizing Leptospirillum. During 35 days of bioleaching in media containing copper slag pulp, inoculated with these enrichments, the change in pH and solubilized metal concentrations of the systems were monitored. Both bacterial strains were completely different from each other in their pattern of pH variation and rates of metal solubilization. The maximum removal of Cu (1725 mg/l) and Zn (715 mg/l) from copper slag substrate was achieved with enrichment culture of A. ferrivorans SCUT-1. However, maximum Mn (207 mg/l), Pb (86 mg/l), and Ni (75 mg/l) removal was observed with enrichment culture of Leptospirillum strain YQP-1. Implications for metal mobilization along with alteration of artifacts from not only historic mining areas but also aspects of decontamination and remediation are discussed.  相似文献   
102.
The availability of a robust and efficient routine for calculating light curves of a finite source magnified due to bending of its light by the gravitational field of an intervening binary lens is essential for determining the characteristics of planets in such microlensing events, as well as for modelling stellar lens binaries and resolving the brightness profile of the source star. However, the presence of extended caustics, and the fact that the images of the source star cannot be determined analytically while their number depends on the source position (relative to the lens system), makes such a task difficult in general. Combining the advantages of several earlier approaches, an adaptive contouring algorithm is presented, which only relies on a small number of simple rules and operations on the adaptive search grid. By using the parametric representation of critical curves and caustics found by Erdl & Schneider, seed solutions to the adaptive grid are found, which ensures that no images or holes are missed.  相似文献   
103.
104.
Peatland of the eastern Qinghai–Tibetan Plateau lies at the convergence of the East Asian and Indian monsoon systems in eastern Asia. To understand the evolution of this peatland and its potential to provide new insights into the Holocene evolution of the East Asian monsoon a 6 m peat core was collected from the undisturbed central part of a peat deposit near Hongyuan. The age-depth profile was determined using 16 14C-AMS age dates, the peat analysed for a range of environmental variables including carbon, nitrogen and hydrogen concentration, bulk density, δ13C and the associated spring water analysed for hydrogen and oxygen isotopes. The age-depth profile of the recovered peat sequence covers the period from 9.6 to 0.3 kyr BP and is linear indicating that the conditions governing productivity and decay varied little over the Holocene. Using changes in carbon density, organic carbon content and its δ13C, cold dry periods of permafrost characterised by low density and impeded surface drainage were identified. The low δ18O and δD values of the spring water emanating around the peat deposit, down to ?13.8 and ?102‰ (VSMOW), respectively, with an inverse relationship between electrical conductivity and isotopic composition indicate precipitation under colder and drier conditions relative to the present day. In view of the current annual mean air temperature of 1 °C this suggests conditions in the past have been conducive to permafrost. Inferred periods of permafrost correspond to independently recognised cold periods in other Holocene records from across China at 8.6, 8.2–7.8, 5.6–4.2, 3.1 and 1.8–1.5 kyr BP. The transition to a cold dry climate appears to be more rapid than the subsequent recovery and cold dry periods at Hongyuan are of longer duration than equivalent cold dry periods over central and eastern China. Light–dark banding peat on a scale of 15–30 years from 9.6 to 5.5 kyr BP may indicate a strong influence of decadal oscillations possibly the Pacific Decadal Oscillation and a potential link between near simultaneous climatic changes in the northwest Pacific, ENSO, movement of the Intertropical Convergence Zone and the East Asian Monsoon.  相似文献   
105.
Although the electron microprobe has become the standard microanalytical tool in modern geosciences, conventional electron microprobe analysis does not allow determination of the valence states of elements such as Fe. The correct classification of minerals and interpretation of reaction microfabrics and grain zonation require high-quality information on ferric/ferrous ratios on a scale of micrometers. The flank method developed by Höfer et?al. (1994, Eur J Mineral 6:407–418) has revived new interest in electron-induced X-ray-spectroscopy to resolve oxidation states in minerals with high spatial resolution. We have recharacterized well-documented sodic amphiboles of the glaucophane–ferroglaucophane–riebeckite–magnesioriebeckite series by electron probe microanalysis and combined the microanalytical data with ferric/ferrous ratios from Mössbauer spectroscopy, Li data from bulk ICP-AES analysis and H2O data from bulk Karl–Fischer titration. The combination of microanalysis and high-quality analysis on the bulk materials results in a data set that allows comparison of model-based stoichiometric calculations and the calibration of the high-resolution flank method. The calibration obtained allows ferric/ferrous ratios to be determined within an error of ±5%. We have found it necessary to apply an empirical correction for absorption phenomena. The advantages of the method must be weighed against the complex calibration procedures necessary and thus the flank method will probably not find use as a routine method. However, in cases where high-resolution data in terms of valence state are needed, the flank method will provide useful data on ferric/ferrous ratios down to minimum FeOtotal content of 6–8 wt%.  相似文献   
106.
New photoelectric photometry of TW Cam is presented. Fourier analysis of the light curve shows a group of peaks at 43d. The first return maps of the primary and secondary minima differ remarkably, that of the secondary minima showing significantly larger scatter. This difference implies that the pulsation period of the star is the formal period (i.e., the distance between two primary minima).  相似文献   
107.
108.
Six stations along the Rhône River from the Rhône Glacier to Lake Geneva were sampled by continuous flow centrifuge for recovery of suspended sediment. The samples were taken four times in the year in both 1982 and 1983. In addition, the mouth of the river was sampled in a like manner every two weeks during 1982 until August 1983. Concentration of sediment and composition did not vary as a function of depth or location across the river. Concentrations varied in time and as a function of flow and samples showed both increasing concentration in suspension and an increase in the proportion of finer particles moving downstream from source to mouth. Only slight variations in texture could be observed down the river as a function of time and appeared to relate to freezing and melting of the Rhône and other headwater glaciers as the primary sediment source. Little variation was observed annually in the texture and composition of the sediment at the river mouth despite large changes in concentration between the high flow summer and low flow winter discharges. These findings are consistent with a well-mixed system in which the suspended sediments are directly related to the primary supply of material from the glaciers.  相似文献   
109.
Abstract The Chervettaz meteorite was an observed fall on 1901 November 30. Our study confirms the previous classification as an L5 chondrite. Weak deformations indicate stage S3 of shock deformations.  相似文献   
110.
Six stations along the Upper Rhone River above Lake Geneva were sampled by continuous flow centrifuge for recovery of suspended sediment. The samples were taken four times, once in 1982 and three times in 1983. In addition the mouth of the river was sampled in a like manner every two weeks during 1982 until August 1983. Samples were analysed for the major elements SiO2, Al2O3, K2O, MgO, Na2O, CaO, and Fe2O3; for trace elements, Zn, Cu, Ni, Mn, and Cr; for Org. C and Kjeldahl N; and the forms of phosphorus bound as Organic P (OP), Apatite P (AP), and Non Apatite Inorganic P (NAIP). The major elements and trace metals confirmed that there is virtually no change in the major geochemical characteristics of the suspended solids in the Rhone, spatially or temporally, indicating that this river is a well-mixed sedimentary system. AP also remained consistent in concentration throughout the year. Sediment recovered during the winter low flow, low turbidity period has been designated SED 1 whereas sediment from the high flow, high turbidity summer condition of the river has been designated SED 2. Org C, OP, and NAIP show a dramatic decrease in concentration from SED 1 to SED 2. The decline is ascribed to dilution of a relatively constant supply of organic matter and phosphorus derived mainly from point source sewage treatment plants to the Rhone. This results in variable partitioning of the OP/NAIP and Org C under the different turbidity condition in the river between winter and summer. This interpretation is confirmed by a low and consistent C-N ratio which except for March remains below 10. Higher values in March may be indicative of soil erosion during spring melt in the agricultural lands of the Rhone Valley. The estimated proportion of particulate bio-available phosphorus is 14 per cent for SED 1 and 7 per cent for SED 2. These low values would suggest that there would be no observable direct effect on the primary production of the receiving waters of Lake Geneva, which would thus respond only to the cumulative loading of phosphorus from the Rhone River.  相似文献   
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