Enhanced production of stratospheric OH from methane oxidation at elevated reactive chlorine levels in northern midlatitudes   总被引：1，自引：0，他引：1  

Elizabeth B. Burnett  Clyde R. Burnett 《Journal of Atmospheric Chemistry》1995,21(1):13-41

Examination of odd-hydrogen production and loss processes in the lower stratosphere reveals that the large abundances of midlatitude ClO recently measured requires a reassessment of the OH yield from methane oxidation due to a more rapid initiation of the methane oxidation sequence by atomic chlorine. Using a steady state calculation for OH and an iterative procedure for evaluating odd-hydrogen production from the methane oxidation sequence, we demonstrate that both OH and reactive chlorine are amplified below 25 km. The amplified values of OH and ClO are found to be consistent with recent measurements of ClO concentrations and of OH column abundances.  相似文献   

The significance of mafic nodules in the ultra-potassic rocks from central Italy - reply     

O. Don Hermes  W.C. Cornell   《Journal of Volcanology and Geothermal Research》1983,16(1-2)

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Retention of ion-implanted-xenon in olivine: Dependence on implantation dose     

C.L. Melcher  T.A. Tombrello  D.S. Burnett 《Geochimica et cosmochimica acta》1983,47(10):1707-1712

The diffusion of Xe in olivine, a major mineral in both meteorites and lunar samples, was studied. Xe ions were implanted at 200 keV into single-crystal synthetic-forsterite targets and the depth profiles were measured by alpha particle backscattering before and after annealing for 1 hour at temperatures up to 1500°C. The fraction of implanted Xe retained following annealing was strongly dependent on the implantation dose. Maximum retention of 100% occurred for an implantion dose of 3 × 10¹⁵ Xe ions/cm². Retention was less at lower doses, with ≥ 50% loss at 1 × 10¹⁴ Xe ions/cm². Taking the diffusion coefficient at this dose as a lower limit, the minimum activation energy necessary for Xe retention in a 10 μm layer for 10⁷ years was calculated as a function of metamorphic temperature. For example, an activation energy of 50 kcal/mole implies Xe retention may be possible for metamorphic temperatures below 500°C.  相似文献   

A special issue honoring Bob Berner     

Don E. Canfield  Timothy W. Lyons  John W. Morse 《Geochimica et cosmochimica acta》2006,70(23):5651-5652

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MTBE Remediation Handbook - Edited by Ellen E. Moyer and Paul T. Kostecki     

Don H. Kampbell 《Ground water》2007,45(5):524-524

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Advancing the understanding of variations of Arctic sea ice optical and thermal behaviors through an international research and mobility project     

Marcel Nicolaus  Caixin Wang  Sebastian Gerland  LI Na  LI Zhijun  Bin Cheng  Don K Perovich  Mats A Granskog  SHI Liqiong  LEI Ruibo  LI Qun  LU Peng 《极地研究(英文版)》2015,(2)

In recent decades, significant changes of Arctic sea ice have taken place. These changes are expected to influence the surface energy balance of the ice-covered Arctic Ocean. To quantify this energy ba...  相似文献   

An assessment of uncertainties in VS profiles obtained from microtremor observations in the phased 2018 COSMOS blind trials     

Asten  Michael W.  Yong  Alan  Foti  Sebastiano  Hayashi  Koichi  Martin  Antony J.  Stephenson  William J.  Cassidy  John F.  Coleman  Jacie  Nigbor  Robert  Castellaro  Silvia  Chimoto  Kosuke  Cornou  Cécile  Cho  Ikuo  Hayashida  Takumi  Hobiger  Manuel  Kuo  Chun-Hsiang  Macau  Albert  Mercerat  E. Diego  Molnar  Sheri  Pananont  Passakorn  Pilz  Marco  Poovarodom  Nakhorn  Sáez  Esteban  Wathelet  Marc  Yamanaka  Hiroaki  Yokoi  Toshiaki  Zhao  Don 《Journal of Seismology》2022,26(4):757-780

Journal of Seismology - Site response is a critical consideration when assessing earthquake hazards. Site characterization is key to understanding site effects as influenced by seismic site...  相似文献   

“All the World's a Stage”: A GIS Framework for Recreating Personal Time‐Space from Qualitative and Quantitative Sources          下载免费PDF全文

Don Lafreniere  Jason Gilliland 《Transactions in GIS》2015,19(2):225-246

This article presents a methodological model for the study of the space‐time patterns of everyday life. The framework utilizes a wide range of qualitative and quantitative sources to create two environmental stages, social and built, which place and contextualize the daily mobilities of individuals as they traverse urban environments. Additionally, this study outlines a procedure to fully integrate narrative sources in a GIS. By placing qualitative sources, such as narratives, within a stage‐based GIS, researchers can begin to tell rich spatial stories about the lived experiences of segregation, social interaction, and environmental exposure. The article concludes with a case study utilizing the diary of a postal clerk to outline the wide applicability of this model for space‐time GIS research.  相似文献   

Liquidus Equilibria in the System K2O-Na2O-Al2O3-SiO2-F2O-1-H2O to 100 MPa: I. Silicate-Fluoride Liquid Immiscibility in Anhydrous Systems     

DolejS  David; Baker  Don R. 《Journal of Petrology》2007,48(4):785-806

Liquidus relations in the four-component system Na₂O–Al₂O₃–SiO₂–F₂O_–1were studied at 0· 1 and 100 MPa to define the locationof fluoride–silicate liquid immiscibility and outlinedifferentiation paths of fluorine-bearing silicic magmas. Thefluoride–silicate liquid immiscibility spans the silica–albite–cryoliteand silica–topaz–cryolite ternaries and the haplogranite-cryolitebinary at greater than 960°C and 0· 1–100 MPa.With increasing Al₂O₃ in the system and increasing aluminum/alkalication ratio, the two-liquid gap contracts and migrates fromthe silica liquidus to the cryolite liquidus. The gap does notextend to subaluminous and peraluminous melt compositions. Forall alkali feldspar–quartz-bearing systems, the miscibilitygap remains located on the cryolite liquidus and is thus inaccessibleto differentiating granitic and rhyolitic melts. In peralkalinesystems, the magmatic differentiation is terminated at the albite–quartz–cryoliteeutectic at 770°C, 100 MPa, 5 wt % F and cation Al/Na =0· 75. The addition of topaz, however, significantlylowers melting temperatures and allows strong fluorine enrichmentin subaluminous compositions. At 100 MPa, the binary topaz–cryoliteeutectic is located at 770°C, 39 wt % F, cation Al/Na 0·95, and the ternary quartz–topaz–cryolite eutecticis found at 740°C, 32 wt % F, 30 wt % SiO₂ and cation Al/Na 0· 95. Such location of both eutectics enables fractionationpaths of subaluminous quartz-saturated systems to produce fluorine-rich,SiO₂-depleted and nepheline-normative residual liquids. KEY WORDS: silicate melt; granite; rhyolite; fluorine; liquid immiscibility  相似文献   

Electron Microprobe/SIMS Determinations of Al in Olivine: Applications to Solar Wind,Pallasites and Trace Element Measurements     

Julie M. Paque  Amy E. Hofmann  Donald S. Burnett  Yunbin Guan  Amy J.G. Jurewicz  Dorothy S. Woolum  Chi Ma  George R. Rossman 《Geostandards and Geoanalytical Research》2020,44(3):473-484

Electron probe microanalyser measurements of trace elements with high accuracy are challenging. Accurate Al measurements in olivine are required to calibrate SIMS implant reference materials for measurement of Al in the solar wind. We adopt a combined EPMA/SIMS approach that is useful for producing SIMS reference materials as well as for EPMA at the ~ 100 µg g^?1 level. Even for mounts not polished with alumina photoelectron spectroscopy shows high levels of Al surface contamination. In order to minimise electron beam current density, a rastered 50 × 100 µm electron beam was adequate and minimised sensitivity to small Al‐rich contaminants. Reproducible analyses of eleven SIMS‐cleaned spots on San Carlos olivine agreed at 69.3 ± 1.0 µg g^?1. The known Al mass fraction was used to calibrate an Al implant into San Carlos. Accurate measurements of Al were made for olivines in the pallasites: Imilac, Eagle Station and Springwater. Our focus was on Al in olivine, but our technique could be refined to give accurate electron probe measurements for other contamination‐sensitive trace elements. For solar wind, it is projected that the Al/Mg abundance ratio can be determined to 6%, a factor of 2 more precise than the solar spectroscopic ratio.  相似文献