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261.
A key requirement for any model of mantle evolution is accounting for the high 3He/4He ratios of many ocean island basalts compared to those of mid-ocean ridge basalts. The early, popular paradigm of primitive, undegassed mantle stored in a convectively isolated lower mantle is incompatible with geophysical constraints that imply whole mantle convection. Thus it has been suggested more recently that domains with high 3He/U ratios have been created continuously from the bulk mantle throughout Earth history. Such models require that the 3He/4He ratio of the convecting mantle was at least as high as the highest values seen in OIB at the time the OIB source was generated. These domains must also be created with sufficient He to impart distinctive He isotopic signatures to ocean island basalts. However, the He isotope evolution of the mantle has not been consistently quantified to determine if such scenarios are plausible.

Here a simple model of the He evolution of the whole mantle is examined. Using a wide range of possible histories of continental extraction and He degassing, the bulk convecting mantle was found to have had 3He/4He ratios as high as those seen in the Iceland hotspot only prior to 3 Ga. Such high 3He/4He ratios can only be preserved if located in domains that are not modified by convective mixing or diffusive homogenisation since that time. Further, there are difficulties in producing, with commonly invoked magmatic processes, domains with sufficiently high 3He/U ratios and enough 3He to be able to impart this signature to ocean island basalts. The results are consistent with models that store such He signatures in the core or a deep layer in the mantle, but are hard to reconcile with models that continuously generate high 3He/4He domains within the mantle.  相似文献   

262.
We propose that the fluid mechanics of magma chamber replenishment leads to a novel process whereby silicic magmas can acquire an important part of their chemical signatures. When flows of basaltic magma enter silicic magma chambers, they assume a ‘fingered' morphology that creates a large surface area of contact between the two magmas. This large surface area provides an opportunity for significant chemical exchange between the magmas by diffusion that is enhanced by continuous flow of silicic liquid traversing the basalt through thin veins. A quantitative analysis shows that a basaltic magma may thereby impart its trace-element and isotopic characteristics to a silicic magma. Depending on concentration differences and diffusion coefficients for the given components, this new mechanism may be as important as crystal fractionation and assimilation in producing the compositional diversity of silicic magmas. It may explain concentration gradients in silicic ash-flow tuffs and should be considered when interpreting the isotopic signatures of silicic rocks, even in the overt absence of mixing. For example, we show that, for several well studied, compositionally graded ash-flow tuffs, the concentrations and isotopic ratios of important geochemical tracers such as strontium could be largely due to this flow-enhanced diffusion process.  相似文献   
263.
Wireline logs and vertical seismic profile data were acquired in two boreholes intersecting the main mineralized zone at the Cu–Au New Afton porphyry deposit, Canada, with the objectives of imaging lithological contacts, fault zones that may have acted as conduits that channelled the mineralization, and alteration zones. Log data provide physical rock properties for the main lithologies and alteration zones. Calliper logs reveal many faults and caved-in zones generally indicating rocks with low integrity at the borehole wall. The preponderance of these zones, as indicated by the logs, suggests that their response may dominate the seismic-reflection wavefield. Outside fault zones, compressional and shear-wave velocities exhibit significant variability due to porosity, the heterogeneity of volcanic fragmental rocks and alteration. Distributed acoustic sensing was used to acquire vertical seismic profiling data in the two boreholes surveyed with wireline logs. Straight and helically wound fibre-optic cables housed standard fibres and a fibre engineered to increase the intensity of backscattering at the distributed acoustic sensing interrogator. Standard and engineered optical fibres placed in the two boreholes were daisy-chained together to form two 5-km-long continuous fibres that were interrogated at once with two interrogators. A new generation of interrogator connected to the engineered fibres provided field data with lower noise level and higher signal-to-noise ratio. These data with higher signal-to-noise ratio from straight fibre-optic cable were processed and used for depth imaging. Depth images benefitted from new migration weights that account for the directional sensitivity of the straight fibre-optic cable and limit the extent of migration artefacts. Migration results show several reflectors with shallow dips to the northwest, some explained by faults intersecting the surveyed boreholes. The main sub-vertical lithological and alteration contacts at New Afton generated downgoing reflections that were not considered in the migration.  相似文献   
264.
正Introduction The International Conference on Asian and Pacific Coasts(APAC)is an international conference to promote academic and technical exchange on coastal related studies that include coastal engineering and coastal environmental problems,among the Asian and Pacific countries/regions.APAC  相似文献   
265.
Solar abundances are important to planetary science since the prevalent model assumes that the composition of the solar photosphere is that of the solar nebula from which planetary materials formed. Thus, solar abundances are a baseline for planetary science. Previously, solar abundances have only been available through spectroscopy or by proxy (CI). The Genesis spacecraft collected and returned samples of the solar wind for laboratory analyses. Elemental and isotopic abundances in solar wind from Genesis samples have been successfully measured despite the crash of the re‐entry capsule. Here we present science rationales for a set of 12 important (and feasible postcrash) Science and Measurement Objectives as goals for the future (Table 1). We also review progress in Genesis sample analyses since the last major review (Burnett 2013 ). Considerable progress has been made toward understanding elemental fractionation during the extraction of the solar wind from the photosphere, a necessary step in determining true solar abundances from solar wind composition. The suitability of Genesis collectors for specific analyses is also assessed. Thus far, the prevalent model remains viable despite large isotopic variations in a number of volatile elements, but its validity and limitations can be further checked by several Objectives.  相似文献   
266.
The natural flux of groundwater into coastal water bodies has recently been shown to contribute significant quantities of nutrients and trace metals to the coastal ocean. Groundwater discharge and hyporheic exchange to estuaries and rivers, however, is frequently overlooked though it often carries a distinctly different chemical signature than surface waters. Most studies that attempt to quantify this input to rivers use multiple geochemical tracers. However, these studies are often limited in their spatial and temporal extents because of the labor-intensive nature of integrating multiple measurement techniques. We describe here a method of using a single tracer, 222Rn, to rapidly characterize groundwater discharge into tidally-influenced rivers and streams. In less than one week of fieldwork, we determined that of six streams that empty into the Indian River Lagoon (IRL), Florida, three (Eau Gallie River, Turkey Creek, and Main Canal) did not receive substantial groundwater inputs, one canal (C-25 Canal) was dominated by groundwater exchange, and the remaining two (Sebastian River system and Crane Creek) fell somewhere in between. For more detailed discharge assessments, we focused on the Sebastian River system, a stratified tidal river estuary, during a relatively dry period (June) and a wet period (July) in 2008. Using time-series 222Rn and current velocity measurements we found that groundwater discharge into all three branches of the Sebastian River increased by 1–2 orders of magnitude during the wetter period. The estimated groundwater flow rates were higher than those reported into the adjacent IRL, suggesting that discharge into these rivers can be more important than direct discharge into the IRL. The techniques employed here should work equally well in other river/stream systems that experience significant groundwater discharge. Such assessments would allow area managers to quickly assess the distribution and magnitude of groundwater discharge nature into rivers over large spatial ranges.  相似文献   
267.
We determined groundwater flow rates shortly after the wet season into an embayment near Ubatuba, Brazil as part of an international intercomparison experiment for submarine groundwater discharge (SGD) assessment techniques. Our estimated rates were determined by the combined use of continuous radon measurements and assessment of radium isotope patterns. The spatial distribution of the short-lived radium isotopes (223Ra and 224Ra) provided the means for independent evaluations of radon losses by mixing and atmospheric evasion. We were thus able to construct a well-constrained mass balance for radon that included a groundwater flux term. Our results showed that the groundwater discharge into this embayment from the fractured crystalline rock aquifer is not steady-state but varies with tidal modulation and rain-induced forcing. Tidally modulated and rain-induced flow rates were comparable during this period. The SGD rates estimated from radon ranged from 1 cm/day to 29 cm/day (cm3/cm2 day) with a mean and standard deviation of 13 ± 6 cm/day. These estimates were mostly similar to a dye-dilution automatic seepage meter (15 ± 19 cm/day) and were within the broad ranges estimated by manual and continuous heat seepage meters but lower than indicated by an artificial tracer test performed nearshore.  相似文献   
268.
269.
The chromophores responsible for coloring the jovian atmosphere are embedded within Jupiter’s vertical aerosol structure. Sunlight propagates through this vertical distribution of aerosol particles, whose colors are defined by ?0(λ), and we remotely observe the culmination of the radiative transfer as I/F(λ). In this study, we employed a radiative transfer code to retrieve ?0(λ) for particles in Jupiter’s tropospheric haze at seven wavelengths in the near-UV and visible regimes. The data consisted of images of the 2008 passage of Oval BA to the south of the Great Red Spot obtained by the Wide Field Planetary Camera 2 on-board the Hubble Space Telescope. We present derived particle colors for locations that were selected from 14 weather regions, which spanned a large range of observed colors. All ?0(λ) curves were absorbing in the blue, and ?0(λ) increased monotonically to approximately unity as wavelength increased. We found accurate fits to all ?0(λ) curves using an empirically derived functional form: ?0(λ) = 1 − A exp(−). The best-fit parameters for the mean ?0(λ) curve were A = 25.4 and B = 0.0149 for λ in units of nm. We performed a principal component analysis (PCA) on our ?0(λ) results and found that one or two independent chromophores were sufficient to produce the variations in ?0(λ). A PCA of I/F(λ) for the same jovian locations resulted in principal components (PCs) with roughly the same variances as the ?0(λ) PCA, but they did not result in a one-to-one mapping of PC amplitudes between the ?0(λ) PCA and I/F(λ) PCA. We suggest that statistical analyses performed on I/F(λ) image cubes have limited applicability to the characterization of chromophores in the jovian atmosphere due to the sensitivity of I/F(λ) to horizontal variations in the vertical aerosol distribution.  相似文献   
270.
Abstract– Coordinated in situ transmission electron microscopy and isotopic measurements of carbonaceous phases in interplanetary dust particles were performed to determine their origins. Five different types of carbonaceous materials were identified based on their morphology and texture, observed by transmission electron microscopy: globular, vesicular, dirty, spongy, and smooth. Flash heating experiments were performed to explore whether some of these morphologies are the result of atmospheric entry processes. Each of these morphologies was found to have isotopically anomalous H and N. Rare C isotopic anomalies were also observed. The isotopic and morphological properties of several of these phases, particularly the organic globules, are remarkably similar to those observed in other extraterrestrial materials including carbonaceous chondrites, comet 81P/Wild 2 particles collected by the Stardust spacecraft, and Antarctic micrometeorites, indicating that they were widespread in the early solar system. The ubiquitous nature and the isotopic anomalies of the nanoglobules and some other morphologies strongly suggest that these are very primitive phases. Given that some of the isotopic anomalies (D and 15N excesses) are indicative of mass fractionation chemical reactions in a very cold environment, and some others (13C and 15N depletions) have other origins, these carbonaceous phases come from different reservoirs. Whatever their origins, these materials probably reflect the first stages of the evolution of solar system organic matter, having originated in the outermost regions of the protosolar disk and/or interstellar cold molecular clouds.  相似文献   
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