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11.
Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a PT liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively.  相似文献   
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13C/12C and 18O/16O ratios of aragonite shells of modern land snails from the southern Great Plains of North America were measured for samples from twelve localities in a narrow east-west corridor that extended from the Flint Hills in North Central Oklahoma to the foothills of the Sangre de Cristo Mountains in Northern New Mexico, USA. Across the study area, shell δ18O values (PDB scale) ranged from −4.1‰ to 1.2‰, while δ13C values ranged from −13.2‰ to 0.0‰. δ18O values of the shell aragonite were predicted with a published, steady state, evaporative flux balance model. The predicted values differed (with one exception) by less than 1‰ from locality averages of measured δ18O values. This similarity suggests that relative humidity at the time of snail activity is an important control on the δ18O values of the aragonite and emphasizes the seasonal nature of the climatic information preserved in the shells. Correlated δ13C values of coexisting Vallonia and Gastrocopta suggest similar feeding habits and imply that these genera can provide information on variations in southern Great Plains plant ecology. Although there is considerable scatter, multispecies, transect average δ13C values of the modern aragonite shells are related to variations in the type of photosynthesis (i.e., C3, C4) in the local plant communities. The results of this study emphasize the desirability of obtaining isotope ratios representing averages of many shells in a locale to reduce possible biases associated with local variations among individuals, species, etc., and thus better represent the “neighborhood” scale temporal and/or spatial environmental variations of interest in studies of modern and ancient systems.  相似文献   
15.
Abstract

Laboratory experiments concerning azimuthal jets in two-layer rotating systems in the absence and presence of bottom topography aligned along the jets have been conducted. The jets were forced by the selective withdrawal of fluid from the upper layer of a two-fluid system contained in a circular dishpan geometry. The principal parameters measured in the experiments were the jet Rossby number, Ro, and a stratification parameter F = r 1/(λ1λ2)1/2 where r 1 is the radius of the circular disc used for the selective withdrawal (i.e., r 1 is the approximate radius of curvature of the jet) and λ12 are the internal Rossby radii of deformation in the upper and lower fluids, respectively.

The no-topography experiments show that for a sufficiently small F, the particular value depending on Ro, the jet is stable for the duration of the experiment. For sufficiently large F, again as a function of Ro, the jet becomes unstable, exhibiting horizontal wave disturbances from modes three to seven. An Ro against F flow regime diagram is presented.

Experiments are then conducted in the presence of a bottom topography having constant cross-section and extending around a mid-radius of the dishpan. The axis of the topography is in the vicinity of the jet axis forced in the no-topography experiments and the crest of the topography is in the vicinity of the interface between the two fluids (i.e., the front associated with the jet). The experiments show that in all cases investigated the jet tends to be stabilized by the bottom topography. Experiments with the topography in place, but with the interface between the fluids being above the topography crest, are shown to be unstable but more irregular than their no-topography counterparts.

Various quantitative measurements of the jet are presented. It is shown, for example, that the jet Rossby number defined in terms of the fluid withdrawal rate from the tank. Q, can be well correlated with a dimensionless vorticity gradient, VG , across the upper layer jet. This allows for an assessment of the stability characteristics of a jet based on a knowledge of VG (which can be estimated given a jet profile) and F.  相似文献   
16.
The suitability of geologic frameworks for extrapolating hydraulic conductivity (K) to length scales commensurate with hydraulic data is difficult to assess. A novel method is presented for evaluating assumed relations between K and geologic interpretations for regional-scale groundwater modeling. The approach relies on simultaneous interpretation of multiple aquifer tests using alternative geologic frameworks of variable complexity, where each framework is incorporated as prior information that assumes homogeneous K within each model unit. This approach is tested at Pahute Mesa within the Nevada National Security Site (USA), where observed drawdowns from eight aquifer tests in complex, highly faulted volcanic rocks provide the necessary hydraulic constraints. The investigated volume encompasses 40 mi3 (167 km3) where drawdowns traversed major fault structures and were detected more than 2 mi (3.2 km) from pumping wells. Complexity of the five frameworks assessed ranges from an undifferentiated mass of rock with a single unit to 14 distinct geologic units. Results show that only four geologic units can be justified as hydraulically unique for this location. The approach qualitatively evaluates the consistency of hydraulic property estimates within extents of investigation and effects of geologic frameworks on extrapolation. Distributions of transmissivity are similar within the investigated extents irrespective of the geologic framework. In contrast, the extrapolation of hydraulic properties beyond the volume investigated with interfering aquifer tests is strongly affected by the complexity of a given framework. Testing at Pahute Mesa illustrates how this method can be employed to determine the appropriate level of geologic complexity for large-scale groundwater modeling.  相似文献   
17.
Mount Bulusan, the Philippines’ fourth most active volcano, erupted in February 21, 2011, sending volcanic ash and pyroclastic materials to its surrounding rivers. The waters drained into the estuary of harmful algal blooms plagued Sorsogon Bay. We aim to determine the impact of the 2011 volcanic eruption and the preceding volcanic ash emissions to the dissolved silica concentration of rivers draining the flanks of Mt. Bulusan and its possible implications to the phytoplankton assemblage of the bay. Six river water sampling periods from August 2010 to October 2012 overlapped with Mt. Bulusan’s active phase of volcanism. Our data shows that mean river silica from pre-eruption levels of ~?500 μM increased by more than 200% during and post-eruption. Highest Si concentration of 2270 μM was measured from Cadacan River in August 2011. Here, we argue that the sustained general increase of dissolved silica is due to the silica-containing materials from Mt. Bulusan’s eruption and that their concentration in river waters is also a function of watershed lithology and precipitation. Increase in dissolved silica and other nutrients caused a shift to diatom domination and, possibly, termination of Pyrodinium bahamense var. compressum blooms. Silica load increase in embayments is a natural process that controls the dominance of algae. Our study also highlights the importance of Philippine rivers to the global ocean silica budget as a function of high precipitation, tectonics in general, and volcanism in particular.  相似文献   
18.
Water samples were collected from 18 natural springs within the West Fork of the Obey River watershed. Overton County, Tennessee, to determine if groundwater was adversely affected by runoff from abandoned surface coal mines Six springs were found to be affected severely and deemed unfit as a source of potable water Water quality of the remaining springs was essentially unaffected it appeared that proximity to surface mines, elevation at the outflow, and geology of the surrounding strata determined the quality of the groundwater The unit is jointly supported by Tennessee Technological University, the Tennessee Wildlife Resource Agency, and the US. Fish and Wildlife Service  相似文献   
19.
Thermal Impact of Residential Ground-Water Heat Pumps   总被引:3,自引:0,他引:3  
A computer simulation study was conducted to quantify the potential thermal impact of residential water-source heat pump usage on ground-water aquifers. In a first phase of the study, weather data for nine locations throughout the country were used to estimate the energy requirements for heating and air conditioning a typical residence. These energy requirements were then translated into the volumetric water demands for a selected heat pump at each location. A representative model aquifer was then defined and its characteristics used, along with the heat pump water requirements and design ΔT's (difference between inlet and outlet water temperature) to identify the important parameters that contribute to heat transfer and to model the movement of the thermal front resulting from injection of heat pump discharge water at the nine locations. The major factor that determines the heat pump thermal impact was found to be the net amount of heat injected into, or removed from an aquifer. Other significant factors included well design, heat pump design ΔT, and physical properties of the aquifer such as thickness, porosity and dispersivity. The study showed that, in climates where winter heating demand is very nearly equal to summer cooling demands, the injection of heat pump discharge water did not cause any significant modification of the ambient model aquifer temperature. However, in hot or cold climates where air conditioning or heating demand dominates, measurable thermal changes occurred in the model aquifer. In most cases, the maximum temperature  相似文献   
20.
Long period Rayleigh wave and Love wave dispersion data, particularly for oceanic areas, have not been simultaneously satisfied by an isotropic structure. In this paper available phase and group velocity data are inverted by a procedure which includes the effects of transverse anisotropy, anelastic dispersion, sphericity, and gravity. We assume that the surface wave data represents an azimuthal average of actual velocities. Thus, we can treat the mantle as transversely isotropic. The resulting models for average Earth, average ocean, and oceanic regions divided according to the age of the ocean floor, are quite different from previous results which ignore the above effects. The models show a low-velocity zone with age dependent anisotropy and velocities higher than derived in previous surface wave studies. The correspondence between the anisotropy variation with age and a physical model based on flow aligned olivine is suggestive. For most of the Earth SH > SV in the vicinity of the low-velocity zone. Neat the East Pacific Rise, however, SV > SH at depth, consistent with ascending flow. Anisotropy is as important as temperature in causing radial and lateral variations in velocity. The models have a high velocity nearly isotropic layer at the top of the mantle that thickens with age. This layer defines the LID, or seismic lithosphere. In the Pacific, the LID thickens with age to a maximum thickness of ~50 km. This thickness is comparable to the thickness of the elastic lithosphere. The LID thickness is thinner than derived using isotropic or pseudo-isotropic procedures. A new model for average Earth is obtained which includes a thin LID. This model extends the fit of a PREM, type model to shorter period surface waves.  相似文献   
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