Theoretical investigation of interstellar C–C–O and C–O–C bonding backbone molecules     

Emmanuel E. Etim  Prasanta Gorai  Ankan Das  Elangannan Arunan 《Astrophysics and Space Science》2018,363(1):6

There are numerous complex organic molecules containing carbon and oxygen atoms which show either C–C–O or C–O–C bonding backbone. This paper examines altogether 51 C–C–O and C–O–C bonding backbone molecules from ten different isomeric groups (C₂H₂O, C₃H₂O, C₂H₄O, C₂H₄O₂, C₃H₄O, C₂H₆O, C₂H₆O₂, C₃H₆O, C₃H₆O₂, C₃H₈O) to summarize the present astronomical status of these molecules. Accurate calculations of enthalpy of formation of these molecules show that the isomers with C–C–O backbone are more stable than the C–O–C backbone. Interestingly, a detailed analysis of relevant astromolecules indicates that most of the observed astromolecules have the C–C–O backbone. As a matter of fact, of all the molecules examined in this study, 80% of the astronomically observed species have the C–C–O backbone while only 20% have the C–O–C backbone. In general, interstellar abundance of a molecule is controlled by some factors such as kinetics, formation and destruction pathways,thermodynamics etc. A proper consideration of these factors could explain the observed abundances of these molecules. All these possible key factors are discussed in this paper.  相似文献   

Influence of food supply on the δ13C signature of mollusc shells: implications for palaeoenvironmental reconstitutions     

Franck Lartaud  Laurent Emmanuel  Marc de Rafelis  Stephane Pouvreau  Maurice Renard 《Geo-Marine Letters》2010,30(1):23-34

Compared to oxygen isotopes, the carbon isotope composition of biogenic carbonates is less commonly used as proxy for palaeoenvironmental reconstructions because shell δ¹³C is derived from both dissolved inorganic (seawater) and organic carbon sources (food), and interactions between these two pools make it difficult to unambiguously identify any independent effect of either. The main purpose of this study was to demonstrate any direct impact of variable food supply on bivalve shell δ¹³C signatures, using low/high rations of a ¹³C-light mixed algal diet fed to 14-month-old (adult) cultured Japanese Crassostrea gigas under otherwise essentially identical in vitro conditions during 3 summer months (May, June and July 2003, seawater temperature means at 16, 18 and 20 °C respectively) in experimental tanks at the Argenton laboratory along the Brittany Atlantic coast of France. At a daily ration of 12% (versus 4%) oyster dry weight, the newly grown part of the shells (hinge region) showed significantly lower δ¹³C values, by 3.5‰ (high ration: mean of −5.8  ± 1.1‰, n = 10; low ration: mean of −2.3  ± 0.7‰, n = 6; ANOVA Scheffe’s test, p < 0.0001). This can be explained by an enhanced metabolic activity at higher food supply, raising ¹³C-depleted respiratory CO₂ in the extrapallial cavity. Based on these δ¹³C values and data extracted from the literature, and assuming no carbon isotope fractionation between food and shell, the proportion of shell metabolic carbon would be 26  ± 7 and 5  ± 5% for the high- and low-ration C. gigas shells respectively; with carbon isotope fractionation (arguably more realistic), the corresponding values would be 69  ± 14 and 24  ± 9%. Both groups of cultured shells exhibited lower δ¹³C values than did wild oysters from Marennes-Ol éron Bay in the study region, which is not inconsistent with an independent influence of diet type. Although there was no significant difference between the two food regimes in terms of δ¹⁸O shell values (means of 0.1  ± 0.3 and 0.4  ± 0.2‰ at high and low rations respectively, non-significant Scheffe’s test), a positive δ¹³C vs. δ¹⁸O relationship recorded at high rations supports the interpretation of a progressive temperature-mediated rise in metabolic activity fuelled by higher food supply (in this case reflecting increased energy investment in reproduction), in terms not only of δ¹³C (metabolic signal) but also of δ¹⁸O (seawater temperature signal). Overall, whole-shell δ¹⁸O trends faithfully recorded summer/winter variations in seawater temperature experienced by the 17-month-old cultured oysters.  相似文献   

Single-element Anomaly Mapping from Stream Sediment Geochemical Landscapes Aided by Digital Terrain Analysis          下载免费PDF全文

XIANG Jie  XIA Peng  XIAO Keyan  Emmanuel John M. CARRANZA  CHEN Jianping 《《地质学报》英文版》2023,97(1):149-162

The identification of anomalies within stream sediment geochemical data is one of the fastest developing areas in mineral exploration. The various means used to achieve this objective make use of either continuous or discrete field models of stream sediment geochemical data. To map anomalies in a discrete field model of such data, two corrections are required: background correction and downstream dilution correction. Topography and geomorphology are important factors in variations of element con...  相似文献   

Exploring of the spatially varying completeness of a tsunami catalogue     

Ning  Li X.  Cheng  Chang X.  Cruz  Ana M.  Garnier  Emmanuel 《Natural Hazards》2022,110(1):191-205

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