The end of the Messinian Salinity Crisis in the western Mediterranean: Insights from the carbonate platforms of south-eastern Spain   总被引：1，自引：0，他引：1  

Raphaël Bourillot  Emmanuelle Vennin  Jean-Marie Rouchy  Marie-Madeleine Blanc-Valleron  Antonio Caruso 《Sedimentary Geology》2010,229(4):224-485

How the Messinian Salinity Crisis (MSC) ended is still a matter of intense debate. The Terminal Carbonate Complex (TCC) is a late Messinian carbonate platform system that recorded western Mediterranean hydrological changes from the final stages of evaporite deposition till the advent of Lago-Mare fresh- to brackish water conditions at the very end of Messinian times. A multidisciplinary study has been carried out in three localities in south-eastern Spain to reconstruct the history of TCC platforms and elucidate their significance in the MSC. Overall, this study provides evidence that the TCC formed following a regional 4th order water level rise and fall concomitant with an opening-restriction trend. It can be subdivided into four 5th order depositional sequences (DS1 to DS4) recording two phases: (1) from DS1 to DS3, a tide-dominated ooidic to oobioclastic system with stenohaline faunas developed as a result of a 70 m water level rise. During this period, the TCC developed in a shallow sea with close to normal marine salinity; (2) in depositional sequence 4, a microbialite-dominated platform system developed. This is indicative of a significant environmental change and is attributed to a 30 to 40 m water level fall in the basins under study. These restricted conditions were coeval with intense evaporite deformation and brine recycling. The syn-sedimentary deformation of evaporites had a major impact on platform architecture and carbonate production, affecting the Messinian series throughout south-eastern Spain at the end of the TCC history. At that time, the TCC developed in a lake with fluctuating, brackish- to hypersaline water. These findings suggest a temporary restoration of marine conditions in the western Mediterranean marginal basins due to Atlantic water influxes prompted by a global sea level rise around 5.6 Ma. Whether marine conditions extended to the entire western Mediterranean still needs to be investigated.  相似文献   

Multi-isotopic composition (δLi–δB–δD–δO) of rainwaters in France: Origin and spatio-temporal characterization     

Romain Millot  Emmanuelle Petelet-Giraud  Catherine Guerrot  Philippe Négrel 《Applied Geochemistry》2010

In the present work, the first results are reported for both Li and B isotope ratios in rainwater samples collected over a long time period (i.e. monthly rainfall events over 1 a) at a national scale (from coastal and inland locations). In addition, the stable isotopes of the water molecule (δD and δ¹⁸O) are also reported here for the same locations so that the Li and B isotope data can be discussed in the same context. The range of Li and B isotopic variations in these rainwaters were measured to enable the determination of the origin of these elements in rainwaters and the characterization of both the seasonal and spatio-temporal effects for δ⁷Li and δ¹¹B signatures in rainwaters. Lithium and B concentrations are low in rainwater samples, ranging from 0.004 to 0.292 μmol/L and from 0.029 to 6.184 μmol/L, respectively. δ⁷Li and δ¹¹B values in rainwaters also show a great range of variation between +3.2‰ and +95.6‰ and between −3.3‰ and +40.6‰ over a period of 1 a, respectively, clearly different from the signature of seawater. Seasonal effects (i.e. rainfall amount and month) are not the main factors controlling element concentrations and isotopic variations. δ⁷Li and δ¹¹B values in rainwaters are clearly different from one site to another, indicating the variable contribution of sea salts in the rainwater depending on the sampling site (coastal vs. inland: also called the distance-from-the-coast-effect). This is well illustrated when wind direction data (origin of air masses) is included. It was found that seawater is not the main supplier of dissolved atmospheric Li and B, and non-sea-salt sources (i.e. crustal, anthropogenic, biogenic) should also be taken into account when Li and B isotopes are considered in hydrogeochemistry as an input to surface waters and groundwater bodies as recharge. In parallel, the isotopic variations of the water molecule, vector of the dissolved B and Li, are also investigated and reported as a contour map for δ¹⁸O values based on compiled data including more than 400 δ¹⁸O values from throughout France. This δ¹⁸O map could be used as a reference for future studies dealing with δ¹⁸O recharge signature in relation to the characterization of surface waters and/or groundwater bodies.  相似文献   

Flank spreading and collapse of weak-cored volcanoes   总被引：1，自引：1，他引：0  

Emmanuelle?CecchiEmail author  Benjamin?van?Wyk de Vries  Jean-Marc?Lavest 《Bulletin of Volcanology》2004,67(1):72-91

Volcanoes subjected to hydrothermal activity develop weak cores as a result of alteration and due to elevated pore pressures. Edifices constructed at the angle of repose of volcanoclastics, or at even more gentle slopes, respond to internal weakening by initially deforming slowly, but may then collapse catastrophically. Such a process has so far been described for only a few volcanoes, such as Casita, Nicaragua; however, the conditions for flank spreading are widespread and many, if not most volcanoes should suffer some alteration-related flank spreading. We provide analogue models that characterise the structure — surface deformation fields and internal structures — of a spreading flank. Deformation creates a characteristic concave-convex-concave flank profile producing structures such as basal thrusts, summit normal faults, grabens and strike-slip relay faults. Three deformation regimes are found: a pit collapse regime is associated with very small volumes of ductile material located far from the edifice surface. This would not appear in nature, as time for deformation is greater than the lifetime of a volcano, unless very low rock viscosities are present. The other two regimes are flank spreading regimes, one symmetric and one asymmetric. The latter is the most common, as most volcanic structures are asymmetrical in form and in distribution of physical properties. The deformation is controlled by altered region dimensions, volume and position relative to the edifice, and to a lesser extent by its shape. As the flanks spread, landslides are created, initially on the steepened portion, but also from fault scarps. Major flank collapse may occur leading to explosive hydrothermal decompression and to a debris avalanche rich in hydrothermally altered material. We provide several new examples of volcanoes that have structures and morphologies compatible with flank spreading. We suggest that it is a common feature, important in the tectonics and hazards of many volcanoes.Editorial Responsibility: J. Gilbert  相似文献   

Dynamic scheme of water circulation in karstic aquifers as constrained by Sr and Pb isotopes. Application to the Hérault watershed,Southern France     

Emmanuelle?Petelet-GiraudEmail author  Jean-Marc?Luck  Dalila?Ben Othman  Philippe?Negrel 《Hydrogeology Journal》2003,11(5):560-573

This paper focuses on the relationship between the karst aquifers and the Hérault River (southern France) as a function of hydrologic conditions. The combination of major and trace element, and Sr and Pb isotopes determined on dissolved load in karstic springs makes it possible to identify a dynamic scheme of the hydrology of the karstic area.In the headwaters part of this area, the Sourcettes Spring is fed by an interrupted stream that infiltrates at the basement-sedimentary cover contact. Internal geochemical processes are also pointed out: (1) water–rock interactions during underground circulation, and (2) water originating from different layers of the aquifer may show different chemistry depending on the hydrological conditions. The Vernède Spring, is fed by a second water supply during high flows (previously considered as unconnected). Finally, the Cent-Fonts Springs have been confirmed to be fed by the Buège interrupted stream.Pb isotopes on the dissolved and particulate loads of the river samples make it possible to discriminate the natural (local rocks) versus anthropogenic (mining district and road traffic) Pb sources. The Pb isotope investigations on karstic water make it possible to differentiate between neighboring springs presenting identical Sr isotope and element ratios, and to point out different underground circulation.

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Resumen Este artículo trata de la relación río-acuífero kárstico en la cuenca de Hérault (Francia), en función de las condiciones hidrológicas. La combinación de elementos principales, elementos traza, e isótopos de estroncio y plomo en muestras de manantiales kársticos permite construir un esquema dinámico de la zona.El manantial de Sourcettes, en la parte alta de la región, está alimentado por una corriente interrumpida que se infiltra a través la cubierta sedimentaria del lecho. También, se apunta a los procesos internos geoquímicos: (1) interacciones roca-acuífero, (2) aguas procedentes de capas diferentes del acuífero, dependiendo de las condiciones hidrológicas. El manantial de Vernède, en el sector oriental de la cuenca, se nutre de una segunda fuente de agua en períodos de aguas altas, que anteriormente se consideraba desconenctada. Finalmente, se ha confirmado que los manantiales de Cent-Fonts captan las aguas del curso interrumpido del Buège.Los isótopos de plomo, tanto en fase disuelta como en suspensión de muestras de río, permiten discriminar entre orígenes naturales (rocas naturales) y antrópicos (minería y tráfico) de este elemento. Las investigaciones en aguas kársticas llevan a diferenciar entre manantiales vecinos que tienen relaciones de isótopos de estroncio idénticas, así como a proponer circulaciones distintas en el acuífero por drenaje o por mineralización no diseminada del plomo.

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Résumé Cet article s'intéresse à la relation entre le karst et une rivière dans le bassin de l'Hérault (France), en fonction des conditions hydrologiques. La combinaison des éléments majeurs, des traces et des isotopes de Sr et Pb déterminés dans la charge dissoute de sources karstiques permet de construire un schéma dynamique de la région karstique.Dans la partie la plus haute de cette région, la source des Sourcettes est alimentée par un cours d'eau qui s'infiltre au contact de la série sédimentaire sur le socle. Des processus géochimiques sont également mis en évidence: (1) des interactions eau-roche au cours du trajet souterrain, (2) de l'eau provenant de différents niveaux de l'aquifère en fonction des conditions hydrologiques. Dans la partie orientale du bassin, la source Vernède reçoit une seconde alimentation lors des fortes crues, précédemment considérée comme n'étant pas connectée. Finalement, on confirme que la source des Cent-Fonts est alimentée par les pertes de la rivière de la Buèges.Les isotopes du Pb dans les charges dissoute et solide des échantillons de rivières ont conduit à faire la distinction entre les sources naturelle (roches locales) et anthropique (mines et trafic routier). Les études sur les isotopes du Pb dans les eaux karstiques permettent de différencier les sources voisines présentant des rapports d'éléments et de signatures isotopiques du Sr identiques, et à distinguer différentes circulations souterraines drainant ou non des minéralisations disséminées de Pb.

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The Gibraltar Arc seismogenic zone (part 1): Constraints on a shallow east dipping fault plane source for the 1755 Lisbon earthquake provided by seismic data, gravity and thermal modeling   总被引：2，自引：0，他引：2  

Emmanuelle Thiebot  Marc-Andr Gutscher 《Tectonophysics》2006,426(1-2):135

The Great Lisbon earthquake of 1755 with an estimated magnitude of 8.5–9.0 is the most destructive earthquake in European history, yet the source region remains enigmatic. Recent geophysical data provide compelling evidence for an active east dipping subduction zone beneath the nearby Gibraltar Arc. Marine seismic data in the Gulf of Cadiz image active thrust faults in an accretionary wedge, above an east dipping decollement and an eastward dipping basement. Tomographic and other data support subduction and rollback of a narrow slab of oceanic lithosphere beneath the westward advancing Gibraltar block.Although, no instrumentally recorded seismicity has been documented for the subduction interface, we propose the hypothesis that this shallow east dipping fault plane is locked and capable of generating great earthquakes (like the Nankai or Cascadia seismogenic zones). We further propose this east dipping fault plane to be a candidate source for the Great Lisbon earthquake of 1755. In this paper we use all available geophysical data on the deep structure of the Gulf of Cadiz–Gibraltar region for the purpose of constraining the 3-D geometry of this potentially seismogenic fault plane. To this end, we use new depth processed seismic data, have interpreted all available published and unpublished time sections, examine the distribution of hypocenters and perform 2-D gravity modeling. Finally, a finite-element model of the forearc thermal structure is constructed to determine the temperature distribution along the fault interface and thus the thermally predicted updip and downdip limits of the seismogenic zone.  相似文献   

The dissolution kinetics of a granite and its minerals—Implications for comparison between laboratory and field dissolution rates     

Jiwchar Ganor  Emmanuelle Roueff  Joel D. Blum 《Geochimica et cosmochimica acta》2005,69(3):607-621

The present study compares the dissolution rates of plagioclase, microcline and biotite/chlorite from a bulk granite to the dissolution rates of the same minerals in mineral-rich fractions that were separated from the granite sample. The dissolution rate of plagioclase is enhanced with time as a result of exposure of its surface sites due to the removal of an iron oxide coating. Removal of the iron coating was slower in the experiment with the bulk granite than in the mineral-rich fractions due to a higher Fe concentration from biotite dissolution. As a result, the increase in plagioclase dissolution rate was initially slower in the experiment with the bulk granite. The measured steady state dissolution rates of both plagioclase (6.2 ± 1.2 × 10⁻¹¹ mol g⁻¹ s⁻¹) and microcline (1.6 ± 0.3 × 10⁻¹¹ mol g⁻¹ s⁻¹) were the same in experiments conducted with the plagioclase-rich fraction, the alkali feldspar-rich fraction and the bulk granite.Based on the observed release rates of the major elements, we suggest that the biotite/chlorite-rich fraction dissolved non-congruently under near-equilibrium conditions. In contrast, the biotite and chlorite within the bulk granite sample dissolved congruently under far from equilibrium conditions. These differences result from variations in the degree of saturation of the solutions with respect to both the dissolving biotite/chlorite and to nontronite, which probably was precipitating during dissolution of the biotite and chlorite-rich fraction. Following drying of the bulk granite, the dissolution rate of biotite was significantly enhanced, whereas the dissolution rate of plagioclase decreased.The presence of coatings, wetting and drying cycles and near equilibrium conditions all significantly affect mineral dissolution rates in the field in comparison to the dissolution rate of fully wetted clean minerals under far from equilibrium laboratory conditions. To bridge the gap between the field and the laboratory mineral dissolution rates, these effects on dissolution rate should be further studied.  相似文献   

Redox potential measurements and Mössbauer spectrometry of Fe adsorbed onto Fe (oxyhydr)oxides     

Ewen Silvester  Laurent Charlet  Antoine Géhin  Emmanuelle Liger 《Geochimica et cosmochimica acta》2005,69(20):4801-4815

The redox properties of Fe^II adsorbed onto a series of Fe^III (oxyhydr)oxides (goethite, lepidocrocite, nano-sized ferric oxide hydrate (nano-FOH), and hydrous ferric oxide (HFO)) have been investigated by rest potential measurements at a platinum electrode, as a function of pH (−log₁₀[H⁺]) and surface coverage. Using the constant capacitance surface complexation model to describe Fe^II adsorption onto these substrates, theoretical values of the suspension redox potential (E_H) have been computed, under the assumption that Fe^II adsorption occurs at crystal growth sites of the substrate surface. Good agreement between calculated and experimental E_H values is observed for nano-FOH and HFO, however the redox potentials measured for lepidocrocite and goethite are significantly more oxidizing than predicted. Mössbauer spectroscopic analysis of ⁵⁷Fe^II adsorbed onto HFO and goethite shows that in both cases the adsorbed ⁵⁷Fe^II is incorporated into the crystal structure of the substrate, in broad agreement with the thermodynamic model, but is almost completely oxidized to ⁵⁷Fe^III. The mechanism by which the adsorbed ⁵⁷Fe^II is oxidized is not resolved in this work, but is thought to be due to electron transfer to the substrate, rather than a net oxidation of the suspension. The disagreement between experimental and calculated rest potential measurements in the goethite and lepidocrocite systems is thought to be due to the poor electrochemical equilibration of these suspensions with the platinum electrode, rather than a failure of the thermodynamic model. The model developed for the redox potential of adsorbed Fe^II allows direct assessment of the reactivity of this species towards oxidized pollutants.  相似文献   

Distribution of silver in mussels and oysters along the French coasts: data from the national monitoring program     

Chiffoleau JF  Auger D  Roux N  Rozuel E  Santini A 《Marine pollution bulletin》2005,50(12):1719-1723

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Simulating the Holocene climate evolution at northern high latitudes using a coupled atmosphere-sea ice-ocean-vegetation model   总被引：1，自引：1，他引：0  

Hans Renssen  Hugues Goosse  Thierry Fichefet  Victor Brovkin  Emmanuelle Driesschaert  Frank Wolk 《Climate Dynamics》2005,24(1):23-43

The response of the climate at high northern latitudes to slowly changing external forcings was studied in a 9,000-year long simulation with the coupled atmosphere-sea ice-ocean-vegetation model ECBilt-CLIO-VECODE. Only long-term changes in insolation and atmospheric CO₂ and CH₄ content were prescribed. The experiment reveals an early optimum (9–8 kyr BP) in most regions, followed by a 1–3°C decrease in mean annual temperatures, a reduction in summer precipitation and an expansion of sea-ice cover. These results are in general agreement with proxy data. Over the continents, the timing of the largest temperature response in summer coincides with the maximum insolation difference, while over the oceans, the maximum response is delayed by a few months due to the thermal inertia of the oceans, placing the strongest cooling in the winter half year. Sea ice is involved in two positive feedbacks (ice-albedo and sea-ice insulation) that lead regionally to an amplification of the thermal response in our model (7°C cooling in Canadian Arctic). In some areas, the tundra-taiga feedback results in intensified cooling during summer, most notably in northern North America. The simulated sea-ice expansion leads in the Nordic Seas to less deep convection and local weakening of the overturning circulation, producing a maximum winter temperature reduction of 7°C. The enhanced interaction between sea ice and deep convection is accompanied by increasing interannual variability, including two marked decadal-scale cooling events. Deep convection intensifies in the Labrador Sea, keeping the overall strength of the thermohaline circulation stable throughout the experiment.  相似文献   

Impact of ocean optical properties on seasonal SST: results with a surface ocean model coupled to the LMD AGCM     

Emmanuelle Cohen-Solal  Hervé Le Treut 《Climate Dynamics》1996,12(6):417-433

As the accuracy of ocean models improves, determination of the solar irradiance within the ocean may become important to simulate precisely the seasonal evolution of the SST. As ocean optical properties are not well documented in space and time, we have undertaken a sensitivity study to measure the corresponding SST uncertainties at a global scale using a model coupling the LMD AGCM with an integral mixed layer model and a thermodynamic sea ice representation. The downwelling irradiance formulation is that of Paulson and Simpson which has been tuned for the five water types of the Jerlov classification. Two sensitivity, and academic, experiments corresponding to a uniformly clear ocean or turbid ocean are carried out. Turbid waters exhibit, in general, a stronger seasonal cycle of the SST of about 2°C. The sensitivity is far from uniform, with a maximum in the subtropics and the mid-latitudes of the summer hemisphere. It corresponds precisely to the area in which the observed optical properties present a large temporal variability which is therefore likely to have an action on the seasonal cycle of the ocean surface temperatures. We perform a decomposition of the model sensitivity in four terms, corresponding to the direct impact of the water type change, feedback due to the mixed layer change, feedback due to the surface solar irradiance change, and feedback due to the non solar heat fluxes change. The first two terms dominate the SST change. The direct effect tends to increase the warming of the mixed layer. In addition, the mixed layer depth diminishes because of a higher stabilizing effect of solar radiation on the TKE budget. This tends to increase further summer warming of the SST as well as their winter cooling.  相似文献