Bowing of thin marble slabs is a phenomenon affecting both historic monuments and modern buildings. In spite of the ubiquity and destructiveness of this phenomenon, no fully satisfactory treatment is currently available to arrest and/or prevent bowing. In this study, a treatment based on formation of hydroxyapatite (HAP) was investigated as a possible route to arrest and possibly prevent bowing of Carrara marble slabs. Four different formulations of the HAP treatment were tested and compared to ammonium oxalate and ethyl silicate (widely used in the practice of marble conservation). The treatments were applied onto pre-weathered and unweathered specimens to investigate their ability to arrest and prevent bowing, respectively. Marble behavior was studied in terms of residual strain and bowing after thermal cycles up to 90 °C in dry and wet conditions. Marble cohesion was assessed before and after the thermal cycles by ultrasound. The HAP treatments exhibited promising results, as the residual strain and the bowing after the cycles were always lower or equal to the untreated references, while marble cohesion was always higher. Surprisingly, ammonium oxalate caused marked worsening of marble thermal behavior. In the case of ethyl silicate, most of the initial benefit after consolidation was lost after the thermal cycles. In general, the results of the study point out the importance of evaluating marble thermal behavior to assess the suitability of any conservation treatment and suggest that treatments able to strengthen marble without causing excessive pore occlusion and stiffening are preferable to enhance durability to thermal cycles. 相似文献
International Journal of Earth Sciences - We report a study integrating 13 new U–Pb LA-MC-ICP-MS zircon ages and Hf-isotope data from dated magmatic zircons together with complete... 相似文献
We consider flow and upscaling of flow properties from pore scale to Darcy scale, when the pore-scale geometry is changing. The idea is to avoid having to solve for the pore evolution at the pore scale, because this results in unmanageable complexity. We propose to use stochastic modeling to parametrize plausible modifications of the pore geometry and to construct distributions of permeability parametrized by Darcy-scale variables. To localize the effects of, e.g., clogging, we introduce an intermediate scale of pore-network models. We use local Stokes solvers to calibrate the throat permeability. 相似文献
On 15 February 2010, a landslide of great dimensions occurred at Maierato (Calabria, Southern Italy) after a long rainy period. Although the zone was continuously affected by ground movements especially during the wet seasons, no monitoring system was installed before the occurrence of the landslide. However, many photos and two videos were taken during the failure process of the slope. In the present study, the available images are used to reconstruct the kinematics of the landslide. In addition, a finite element analysis is performed to define the main factors of triggering and to interpret the failure mechanism of the slope. This analysis is also based on the data from a site investigation carried out after the landslide to characterise the involved soils from a geotechnical viewpoint. The analysis also accounts for the strain-softening behaviour of some soils. The results have shown that the Maierato landslide was the reactivation of a pre-existing landslide body, which was caused by a significant increase in groundwater level. 相似文献
The intertidal environment of the Ponzos beach (NW Iberian Peninsula) hosts a sedimentary sequence (including large wood fragments) deposited during the first half of the Holocene in a hygrophilous continental wetland. Pollen and macrofossil data alongside radiocarbon dating allow reconstruction of the changes that occurred during the Early and Middle Holocene in the landscape of the NW Iberia coastal lowlands, as well as the local wetland plant communities, in response to the climate variations and the eustatic sea-level oscillations. The sequence represents the evolution of a coastal wetland from its initial phases as a hygrophilous wetland towards the subsequent installation of a freshwater lagoon. Pollen data show the dominant role of Atlantic (mainly deciduous) woody taxa, the scarcity of conifers and the lack of Mediterranean elements in the coastal landscapes around the Ponzos site. The presence and abundance of some taxa such as deciduous Quercus, Castanea, Fagus, Tilia and Ulmus during the Early Holocene provides further support for the occurrence of glacial refuges in the Cantabrian-Atlantic area during the Last Glaciation. The diverse vegetation that characterizes the modern landscapes in this territory established later, spreading from these glacial reservoirs of biodiversity. In this sense, the notable and early presence of Fagus at the beginning of the Holocene, a tree also previously recorded during several phases of the Last Glacial Cycle on the NW Iberia coasts, is noteworthy. In addition, during the Early and Middle Holocene are recorded other trees that are currently extirpated as natural taxa in the area, such as Pinus, Tilia and Carpinus. 相似文献
Arsenic (As), iron (Fe), and manganese (Mn) contents were measured in sediment nodules and associated pore waters obtained from sediment cores collected from a salt marsh on Pólvora Island (southern Brazil). Sediment cores were obtained when brackish water dominated the estuary, at two different environments: an unvegetated mudflat colonized by crabs (Neohelice granulata), and a low intertidal stand vegetated by Spartina alterniflora. We determined the percentage of nodules in each depth interval of the cores, along with redox potential, and As, Fe, and Mn contents of the nodules. The mineralogy of the nodules was investigated, and results showed they are mainly composed by quartz, phyllosilicates, and amorphous Fe–Mn oxides/oxyhydroxides. Pore water results showed that bioturbation by local crabs supports oxygen penetration to depths of ca. 25 cm below the salt marsh surface, with lower Fe contents in pore water associated with the brackish period. However, S. alterniflora growth appears to have a greater impact on sediment geochemistry of Fe, Mn, and possibly As due to sulfate reduction and the associated decrease in pore water pH. Higher Fe concentrations were observed in the pore waters during the period of brackish water dominance, which also corresponded to the S. alterniflora growth season. The study demonstrates that differences in geochemical conditions (e.g., Fe content) that can develop in salt marsh sediments owing to different types of bioirrigation processes (i.e., bioirrigation driven by crabs versus that related to the growth of S. alterniflora) play important roles in the biogeochemical cycling of As.
Conventional hydrogeological practice is to formulate a conceptual model, which is often the basis of a numerical model. The numerical model is then used to test groundwater management strategies. A workflow is proposed, employing the numerically enhanced conceptual model (NECoM) of the Mean Sea Level Aquifer (MSLA) on the island of Malta. The Malta MSLA is overexploited and under threat of salinization. Data (heads, chloride concentrations, electrical conductivity logs, tidal tests and qualitative analyses) were assimilated into a fast-running numerical model. Simultaneously, strategies for optimal acquisition of further data were examined through the modelling process. The model was delivered through the Energy and Water Agency, with suggestions for flexible model deployment. These workflows will, hopefully, spawn model improvements through further revision of the base concepts. The model allows the agency to make predictions, which have uncertainties that are quantified and reduced through data assimilation as new data become available. Contemplated management plans can therefore be properly assessed before implementation. The proposed NECoM approach can be generalized since it bases model usage on the premise that modelling should make maximum use of existing data by assimilating its information content, thereby highlighting the uncertainties of decision-critical predictions that remain because of data insufficiency. Thus, the presently disjointed process of modelling on the one hand, and data acquisition on the other, can be better aligned. Conceptual and numerical model development become parallel, rather than sequential, activities. Together, they enable predictions of future system behaviour for which bias is reduced and uncertainties quantified.
Hydrogeology Journal - Geological and hydrogeological conceptualizations of the five main aquifers of Malta were performed by means of characterization of the groundwater bodies’ geometries... 相似文献
With this paper we demonstrate, using the example of the Segara Anakan lagoon in south Java, Indonesia, that exploring the environmental history of an area may provide important information for the understanding of present day problems and their possible solutions. The lagoon is seriously affected by sedimentation. Management measures aiming at its preservation were rather ineffective. Until now, most scholars have treated sedimentation of the lagoon as a short-term phenomenon. We found evidence that sedimentation is a long-term driver of ecosystem changes in Segara Anakan. Ecosystem changes are also obvious in the disappearance of species from the lagoon, like pearl oysters.We recommend that preconditions for the development of adequate management decisions regarding the lagoon's sedimentation problem are (1) a distinction between natural and anthropogenic causes of sedimentation and (2) an understanding of changes in species composition. 相似文献
The radiation-resistant bacterium Deinococcus radiodurans was exposed to a simulated interplanetary UV radiation at the Brazilian Synchrotron Light Laboratory (LNLS). Bacterial samples were irradiated on different substrates to investigate the influence of surface relief on cell survival. The effects of cell multi-layers were also investigated. The ratio of viable microorganisms remained virtually the same (average 2%) for integrated doses from 1.2 to 12 kJ m−2, corresponding to 16 h of irradiation at most. The asymptotic profiles of the curves, clearly connected to a shielding effect provided by multi-layering cells on a cavitary substrate (carbon tape), means that the inactivation rate may not change significantly along extended periods of exposure to radiation. Such high survival rates reinforce the possibility of an interplanetary transfer of viable microbes. 相似文献
