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21.
Observations of the tropical atmosphere are fundamental to the understanding of global changes in air quality, atmospheric oxidation capacity and climate, yet the tropics are under-populated with long-term measurements. The first three years (October 2006–September 2009) of meteorological, trace gas and particulate data from the global WMO/Global Atmospheric Watch (GAW) Cape Verde Atmospheric Observatory Humberto Duarte Fonseca (CVAO; 16° 51′ N, 24° 52′ W) are presented, along with a characterisation of the origin and pathways of air masses arriving at the station using the NAME dispersion model and simulations of dust deposition using the COSMO-MUSCAT dust model. The observations show a strong influence from Saharan dust in winter with a maximum in super-micron aerosol and particulate iron and aluminium. The dust model results match the magnitude and daily variations of dust events, but in the region of the CVAO underestimate the measured aerosol optical thickness (AOT) because of contributions from other aerosol. The NAME model also captured the dust events, giving confidence in its ability to correctly identify air mass origins and pathways in this region. Dissolution experiments on collected dust samples showed a strong correlation between soluble Fe and Al and measured solubilities were lower at high atmospheric dust concentrations. Fine mode aerosol at the CVAO contains a significant fraction of non-sea salt components including dicarboxylic acids, methanesulfonic acid and aliphatic amines, all believed to be of oceanic origin. A marine influence is also apparent in the year-round presence of iodine and bromine monoxide (IO and BrO), with IO suggested to be confined mainly to the surface few hundred metres but BrO well mixed in the boundary layer. Enhanced CO2 and CH4 and depleted oxygen concentrations are markers for air-sea exchange over the nearby northwest African coastal upwelling area. Long-range transport results in generally higher levels of O3 and anthropogenic non-methane hydrocarbons (NMHC) in air originating from North America. Ozone/CO ratios were highest (up to 0.42) in relatively fresh European air masses. In air heavily influenced by Saharan dust the O3/CO ratio was as low as 0.13, possibly indicating O3 uptake to dust. Nitrogen oxides (NOx and NOy) show generally higher concentrations in winter when air mass origins are predominantly from Africa. High photochemical activity at the site is shown by maximum spring/summer concentrations of OH and HO2 of 9?×?106 molecule cm?3 and 6?×?108 molecule cm?3, respectively. After the primary photolysis source, the most important controls on the HOx budget in this region are IO and BrO chemistry, the abundance of HCHO, and uptake of HOx to aerosol.  相似文献   
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23.
This study investigated the community structure and functional traits of the mollusk fauna associated with macroalgae with different thallus morphologies in a reef environment in Northeastern Brazil. A total of 15 individuals of each species of macroalgae adhered to natural substrate and 15 individuals of Padina gymnospora detached from the substrate were collected. The structural complexity of algal habitats was measured and the associated malacofauna screened and identified. All three macroalgae differed significantly in the complexity of their habitat, with Sargassum polyceratium being the most complex. A total of 823 specimens of mollusks belonging to 22 species and 11 families were recorded, of which Columbellidae was the most represented with six species. The functional trait “size” revealed that micromollusks smaller than 10 millimeters were predominant in the community; however, individuals of larger sizes (up to 24.54 millimeters) belonging to young stages of other species were also present. Eight functional trophic groups were identified, of which “carnivorous” stood out with seven species. Six functional groups of microhabitats were identified, with intra‐specific variation in habitats, while habitat expansion was documented for species not yet recorded in association with macroalgae. The structure of the molluskan community differed among the three algae species with the greatest richness, abundance, and diversity of mollusks and functional traits occurring with S. polyceratium. Community structure differed between algae adhered to natural substrate and detached algae, with the latter having lower mollusk richness and diversity, but with greater abundance of some species that remained on algal fronds after release from the reef environment. This study reinforces the importance of algal habitat for marine invertebrate fauna, especially for micromollusks that spend their entire life cycle, or part of it, in association with macroalgae.  相似文献   
24.
Urban development charges (UDC) are considered relevant taxation instruments that can improve the economic sustainability of urban areas and the financial health of the respective local governments. The economic formulation and justification based on the ‘direct benefit principle,’ the ‘accountability principle,’ and the ‘proportionality principle’ requires a methodology that can be supported by a geographic information system (GIS) application. This article presents the research output of a real case study – the municipality of Aljezur, Portugal – and the fundamentals of the GIS tool that was designed. This GIS-based methodology comprises a multi-annual infrastructure capital plan and an accurate zoning map for spatial differentiation of values combining municipal-wide and site-specific approaches, following ‘pay as the urban areas grow’ perspective applied to urban development and new buildings. It requires data integration of the urban planning process with infrastructure and urban growth data in order to manage and monitor the computation of this charge over time, thereby increasing the accuracy, the objectivity and the clarity of the process. The results obtained show that this UDC-GIS application seems well adapted to small municipalities. Its possible replication and use in other contexts require adaptations derived from different urban and taxation policy options and from different legal, organizational, technological, and informational local systems.  相似文献   
25.
The objective of this paper is to compare the spectral features of the recently derived Group Sunspot Numbers (R G) and the traditional Wolf Sunspot Numbers (R Z) for the 1700–1995 period. In order to study the spectral features of both time series, two methods were used, including: (a) the multitaper analysis and (b) the wavelet analysis. Well-known features of the solar variability, such as the 98.6-yr (Gleissberg cycle), 10–11-yr (Schwabe cycle) and 5-yr (second solar harmonic) periodicities were identified with high confidence using the multitaper analysis. Also observed was a larger amount of power spread in high frequencies for R Z than for R G spectra. Furthermore, a multitaper analysis of two subsets, A (1700–1850) and B (1851–1995), has indicated that the main differences occurred in the first subset and seem to be due to uncertainties in the early observations. The wavelet transform, which allows observing the spectra evolution of both series, showed a strong and persistent 10–11-yr signal that remained during the whole period. The Meyer Wavelet Transform was applied to both R Z and R G. This study indicates that the main spectral characteristics of both series are similar and that their long-term variability has the same behavior.  相似文献   
26.
Faria  H. H.  Echer  E.  Rigozo  N. R.  Vieira  L. E. A.  Nordemann  D. J. R.  Prestes  A. 《Solar physics》2004,223(1-2):305-318
The objective of this paper is to compare the spectral features of the recently derived Group Sunspot Numbers (R G) and the traditional Wolf Sunspot Numbers (R Z) for the 1700–1995 period. In order to study the spectral features of both time series, two methods were used, including: (a) the multitaper analysis and (b) the wavelet analysis. Well-known features of the solar variability, such as the 98.6-yr (Gleissberg cycle), 10–11-yr (Schwabe cycle) and 5-yr (second solar harmonic) periodicities were identified with high confidence using the multitaper analysis. Also observed was a larger amount of power spread in high frequencies for R Z than for R G spectra. Furthermore, a multitaper analysis of two subsets, A (1700–1850) and B (1851–1995), has indicated that the main differences occurred in the first subset and seem to be due to uncertainties in the early observations. The wavelet transform, which allows observing the spectra evolution of both series, showed a strong and persistent 10–11-yr signal that remained during the whole period. The Meyer Wavelet Transform was applied to both R Z and R G. This study indicates that the main spectral characteristics of both series are similar and that their long-term variability has the same behavior.  相似文献   
27.
28.
The ecological relevance of polychaetes coupled with their easy culture and maintenance in the laboratory, has led them to become increasingly used in marine ecotoxicological studies, raising the need to validate frequently applied monitoring tools at various biological levels. The present study was aimed to characterize the cholinesterases (ChE) activity in the polychaete Capitella teleta, using three substrates (acetylthiocholine iodide, propionylthiocholine iodide, and S-butyrylthiocholine iodide) and four known inhibitors (eserine hemisulfate, BW284c51, iso-OMPA and chlorpyrifos-oxon). Results showed that most of the measured cholinesterase activity was acetylcholinesterase (AChE). Inhibition of enzyme kinetic experiments denoted that sensitivity of C. teleta’s ChE to the organophosphorous metabolite chlorpyrifos-oxon (IC50 = 60.72 nM) was analogous to some fish species. This study highlights the relevance of ChE characterization before its use as a biomarker in ecotoxicology and biomonitoring studies.  相似文献   
29.
Natural Hazards - Process-based hydrological models are of great importance to understand hydrological processes and support decision making. The LImburg Soil Erosion Model (LISEM) requires...  相似文献   
30.
The palaeontological sites of Riba de Santiuste and Sienes (Riba de Santiuste area) are located in the province of Guadalajara, Spain. They include a stratigraphic interval in Muschelkalk facies belonging to the “Cuesta del Castillo Sandstones” Formation and “Royuela Dolostones, Marls and Mudstones” Formation. These sites include numerous fossil plants, direct vertebrate remains, and vertebrate swim traces. The vertebrate remains correspond to a multitude of anatomical elements of Sauropterygia (Nothosauroidea, Placodontia) and possible Archosauria (Rauisuchia) remains. The fossil material attributed to nothosaurs includes teeth, coracoids, a thoracic vertebra, some isolated vertebral centra, humerus, rib fragments, and some dorsal and caudal vertebrae. The remains attributed to placodonts correspond to fragments of skull, quadrate, teeth and osteoderms. Other undetermined sauropterygian remains, such as ulnas, fragments of long bones, fragments of ribs, and articular facets of ribs have been also recovered. Additionally, a fragment of mandible and an intervertebral disk of indeterminate reptiles whose size could be compatible with archosaurs are also described. These bones are exceptionally well-preserved because the fossilization processes have preserved the microstructure of the tissues. The sites also show vertebrate traces, with parallel scratch impressions interpreted as swim traces. The relative stratigraphic position and the palaeontological content of these sites suggest a Ladinian age (Middle Triassic). The interpretation of the sedimentary facies here described also suggests that the sites could correspond to detrital-carbonate mixed deposits of coastal intertidal to supratidal environments.  相似文献   
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