Adsorption of Brilliant Green from Aqueous Solutions onto Crosslinked Chitosan Graft Copolymers     

Bengi Özkahraman  Ayça Bal  Işıl Acar  Gamze Güçlü 《洁净——土壤、空气、水》2011,39(11):1001-1006

In this study, graft copolymerization of itaconic acid (IA) and crotonic acid (CA) onto the crosslinked chitosan beads were carried out using ammonium persulfate as initiator. Grafted chitosan beads were characterized by FT‐IR analysis and grafting percentage determination. Grafting efficiency and add‐on percentages values of grafted chitosan beads were determined as 23–29 and 32–47%, respectively. Then, equilibrium isotherms and kinetics of brilliant green adsorption onto grafted chitosan beads were investigated. The results indicated that the pseudo‐second‐order kinetic model fitted better than the data obtained from pseudo‐first‐order model for the adsorption of brilliant green onto grafted chitosan beads. The fit of data for brilliant green (BG) adsorption onto grafted chitosan beads suggested that the Langmuir model gave closer fittings than the Freundlich model.  相似文献   

Onshore record of the subduction of a crustal salient: example of the NW Borneo Wedge   总被引：1，自引：0，他引：1  

François Sapin  Manuel Pubellier  Abdeltif Lahfid  Dominik Janots  Charles Aubourg  Jean‐Claude Ringenbach 《地学学报》2011,23(4):232-240

  相似文献   

Determination of chemical weathering rates from U series nuclides in soils and weathering profiles: Principles,applications and limitations     

François Chabaux  Lin Ma  Peter Stille  Eric Pelt  Mathieu Granet  Damien Lemarchand  Raphael di Chiara Roupert  Susan L. Brantley 《Applied Geochemistry》2011

The development of U-series nuclides for investigating weathering processes has been significantly stimulated by the analytical improvement made over the last decades in measuring the ²³⁸U series with intermediate half-lives (i.e., ²³⁴U–²³⁰Th–²²⁶Ra). It is proposed in this paper to present principles and methods that are now being developed to determine weathering rates from the study of U-series nuclides in soils and weathering profiles. Mathematical approaches, developed to calculate such rates, are based on some implicit assumptions that are also presented and must be kept in mind if one wants to correctly interpret the obtained ages.  相似文献   

What shapes mesoscale wind anomalies in coastal upwelling zones?   总被引：1，自引：1，他引：0  

Julien Bo��  Alex Hall  Fran?ois Colas  James C. McWilliams  Xin Qu  Jaison Kurian  Sarah B. Kapnick 《Climate Dynamics》2011,36(11-12):2037-2049

Observational studies have shown that mesoscale variations in sea surface temperature may induce mesoscale variations in wind. In eastern subtropical upwelling regions such as the California coast, this mechanism could be of great importance for the mean state and variability of the climate system. In coastal regions orography also creates mesoscale variations in wind, and the orographic effect may extend more than 100?km offshore. The respective roles of SST/wind links and coastal orography in shaping mesoscale wind variations in nearshore regions is not clear. We address this question in the context of the California Upwelling System, using a high-resolution regional numerical modeling system coupling the WRF atmospheric model to the ROMS oceanic model, as well as additional uncoupled experiments to quantify and separate the effects of SST/wind links and coastal orography on mesoscale wind variations. After taking into account potential biases in the representation of the strength of SST/wind links by the model, our results suggest that the magnitude of mesoscale wind variations arising from the orographic effects is roughly twice that of wind variations associated with mesoscale SST anomalies. This indicates that even in this region where coastal orography is complex and leaves a strong imprint on coastal winds, the role of SST/winds links in shaping coastal circulation and climate cannot be neglected.  相似文献   

Conflicts over industrial tree plantations in the South: Who, how and why?     

Julien-Franois Gerber 《Global Environmental Change》2011,21(1):165-176

Industrial tree plantations for wood, palm oil and rubber production are among the fastest growing monocultures and are currently being promoted as carbon sinks and energy producers. Such plantations are causing a large number of conflicts between companies and local populations, mostly in the tropics and subtropics. Within a political ecology framework, the present paper investigates the nature of such conflicts as related to the alleged impacts of the plantations, the protesters involved, and the modalities of the conflicts with a special emphasis on their outcomes. Relying on the most comprehensive literature review to date, corresponding to 58 conflict cases, I find that the prominent cause of resistance is related to corporate control over land resulting in displacements and the end of local uses of ecosystems as they are replaced by monocultures. Resistance includes the “weapons of the weak” and ranges from dialogue to direct confrontation and from local to international. It often involves NGOs, especially for legal issues. Demonstrations, lawsuits, road blockades and tree uprooting have been reported in several countries. Authorities have responded by repression in about half of the cases analysed, while popular struggles have been able to stop plantations in about one fifth, mainly through winning lawsuits or massive social unrest. While these movements can be regarded as classical land conflicts, they usually also have an ecological content, corresponding to forms of the “environmentalism of the poor”. The documented large number of such conflicts suggests that policies promoting large-scale tree plantations should be reappraised.  相似文献   

Estimating baselines for climate change for less developed countries: the case of the Sahel     

Mohammed H.I. Dore  Jean François Lamarche 《Climate Policy》2013,13(2):231-240

Abstract

The UN Framework Convention on Climate Change (UNFCCC) and the Kyoto Protocol provide mechanisms for assisting less developed countries that are adversely affected by climate change. Such assistance would need a baseline, which ideally would set a precise date for specific impacts of climate change. This article presents the results of statistical tests that we carried out and, for the African region of the Sahel, finds that for precipitation (affecting food supply), impacts due to climate change can be ‘dated’ to the year 1967, when precipitation fell drastically, affecting the local food supply. Such a statistically robust benchmark would be useful to the Subsidiary Body for Scientific and Technological Advice (SBSTA) of the UNFCCC. The method illustrates how other baselines may be established for the important work of the SBSTA.  相似文献   

Climate change adaptation cost in the US: what do we know?     

Fran Sussman  Nisha Krishnan  Kathryn Maher  Rawlings Miller  Charlotte Mack  Paul Stewart 《Climate Policy》2013,13(2):242-282

Researchers and policy makers increasingly recognize the need to adapt to future changes in climate, given that past emissions of greenhouse gases have already committed the world to some level of climate change. However, the current understanding of the costs and benefits of adaptation measures is still fairly rudimentary, and far from comprehensive. An assessment is presented of the current state of knowledge on the magnitude of adaptation costs in the United States. While incomplete, the studies suggest that adaptation cost could be as high as tens or hundreds of billions of dollars per year by the middle of this century. Key studies are identified in each sector, and the cost estimates and approaches to cost estimation are surveyed. Methodological issues are highlighted in interpreting, comparing, and aggregating adaptation cost estimates. Policy recommendations are made along with appropriate steps to make future adaptation cost studies more comparable within and across sectors and more accessible and relevant to policy and decision makers.

Policy relevance

Designing and implementing climate change adaptation policy requires good information about the effectiveness and cost of available adaptive options. The current state of knowledge on adaptation costs in the United States is assessed and significant gaps in the literature are highlighted – particularly in terms of sectoral and geographic coverage – as well as inconsistencies in methodologies and assumptions that hamper comparison across studies. Critical steps are identified that can be taken to make adaptation cost studies more accessible and useful to decision makers. The findings and recommendations are relevant to adaptation cost studies globally, not just in the United States.  相似文献   

Warm brine lakes in craters of active mud volcanoes,Menes caldera off NW Egypt: evidence for deep-rooted thermogenic processes     

Stéphanie Dupré  Jean Mascle  Jean-Paul Foucher  François Harmegnies  John Woodside  Catherine Pierre 《Geo-Marine Letters》2014,34(2-3):153-168

The Menes caldera is a fault-controlled depression (~8 km in diameter) at ~3,000 m water depth in the western province of the Nile deep-sea fan off NW Egypt, comprising seven mud volcanoes (MVs) of which two are active. Based on multichannel and chirp seismic data, temperature profiles, and high-resolution bathymetric data collected during the 2000 Fanil, 2004 Mimes and 2007 Medeco2 expeditions, the present study investigates factors controlling MV morphology, the geometry of feeder channels, and the origin of emitted fluids. The active Cheops and Chephren MVs are 1,500 m wide with subcircular craters at their summits, about 250 m in diameter, generally a few tens of metres deep, and filled with methane-rich muddy brines with temperatures reaching 42 °C and 57 °C respectively. Deployments of CTDs and corers with attached temperature sensors tracked these warm temperatures down to almost 0.5 km depth below the brine lake surface at the Cheops MV, in a feeder channel probably only a few tens of metres wide. Thermogenic processes involve the dissolution of Messinian evaporites by warm fluids likely sourced even deeper, i.e. 1.7 and 2.6 km below the seabed at the Cheops and Chephren MVs respectively, and which ascend along listric faults. Seepage activity appears broadly persistent since the initiation of mud volcanism in the Early Pliocene, possibly accompanied by lateral migration of feeder channels.  相似文献   

Oxygen isotope variability in calcite shells of the ostracod Cyprideis torosa in Akyatan Lagoon,Turkey     

Anne-Marie Bodergat  Christophe Lécuyer  François Martineau  Atike Nazik  Kemal Gürbüz  Serge Legendre 《Journal of Paleolimnology》2014,52(1-2):43-59

The euryhaline ostracod Cyprideis torosa lives in Akyatan Lagoon, Turkey, which is exposed to large spatial and seasonal variations in water salinity, δ¹⁸O, and temperature. Hydrogen and oxygen isotope measurements of waters reveal that the large range of salinity (15–80 g L^?1) in the lagoon results from a combination of evaporation and mixing between Mediterranean seawater and Seyhan River input. Round sieve-pore relative abundance in C. torosa provides a robust proxy for water salinity (S) from 15 to 80 g L^?1, according to the equation: S = 161.41 (±4.52) * log₁₀(% rounded pores) ? 94.04 (±3.44) (R² = 0.937; p = 10^?31). Seasonal sampling and isotope analysis of C. torosa in waters of known δ¹⁸O values (?4.7 to +6.9 ‰ V-PDB) and temperatures (15–35 °C) yielded a weak positive correlation (r = 0.71) between 1000 lnα_{(calcite–water)} ‰ V-SMOW) and 10³ * T^?1. Specimens of C. torosa collected during the mild and warm seasons have oxygen isotope compositions close to those of inorganic calcite precipitated in equilibrium with ambient water. The large oxygen-isotope variability observed during any season of the year most likely results from shell calcification in water bodies of highly variable salinity, alkalinity, Mg/Ca and water saturation relative to calcite. Indeed, distinct water bodies in the Akyatan Lagoon are generated by mixing of fresh and marine waters, which are exposed to different evaporation rates at the seasonal scale.  相似文献   

Projections of temperature and precipitation extremes in the North Western Mediterranean Basin by dynamical downscaling of climate scenarios at high resolution (1971–2050)     

A. Barrera-Escoda  M. Gonçalves  D. Guerreiro  J. Cunillera  J. M. Baldasano 《Climatic change》2014,122(4):567-582

The North Western Mediterranean basin (NWMB) is characterised by a highly complex topography and an important variability of temperature and precipitation patterns. Downscaling techniques are required to capture these features, identify the most vulnerable areas to extreme changes and help decision makers to design strategies of mitigation and adaptation to climate change. A Regional Climate Model, WRF-ARW, is used to downscale the IPCC-AR4 ECHAM5/MPI-OM General Circulation Model results with high resolution (10 km), considering three different emissions scenarios (B1, A1B and A2) for 2001–2050. Model skills to reproduce observed extremes are assessed for a control period, 1971–2000, using the ERA40 reanalysis to drive the WRF-ARW simulations. A representative set of indices for temperature and precipitation extremes is projected. The modelling system correctly reproduces amplitude and frequency of extremes and provides a high degree of detail on variability over neighbouring areas. However, it tends to overestimate the persistence of wet events and consequently slightly underestimate the length of dry periods. Drier and hotter conditions are generally projected for the NWMB, with significant increases in the duration of droughts and the occurrence of heavy precipitation events. The projected increase in the number of tropical nights and extreme temperatures could have a negative effect on human health and comfort conditions. Simulations allow defining specifically vulnerable areas, such as the Ebro Valley or the Pyrenees, and foreseeing impacts on socio-economic activities in the region.  相似文献