Petrogenesis of Al-rich chondrules: Evidence from bulk compositions and phase equilibria   总被引：1，自引：0，他引：1  

Glenn J. MacPherson  Gary R. Huss 《Geochimica et cosmochimica acta》2005,69(12):3099-3127

We measured major, minor, and trace-element compositions for eleven Al-rich chondrules from unequilibrated ordinary chondrites to investigate the relationships between Al-rich chondrules, ferromagnesian chondrules, Ca-, Al-rich inclusions (CAIs), and amoeboid olivine aggregates (AOAs). Phase equilibrium considerations show that, for the most part, mineral assemblages in Al-rich chondrules are those expected from melts of the observed compositions. The diversity of mineral assemblages and Al-rich chondrule types arises mainly from the fact that the array of compositions spans both the spinel-saturated anorthite-forsterite reaction curve and a thermal divide defined by where the anorthite-forsterite join crosses the reaction curve. The reaction curve accounts for the two principal varieties of Al-rich chondrule, plagioclase-phyric and olivine-phyric, with or without aluminous spinel. The thermal divide influences the subsequent evolution of each variety. A third variety of Al-rich chondrule contains abundant sodium-rich glass; trace-element fractionation patterns suggest that these glassy Al-rich chondrules could have been derived from the other two by extensive alteration of plagioclase to nepheline followed by remelting. The bulk compositions of Al-rich chondrules (except sodium-rich ones) are intermediate in a volatility sense between ferromagnesian chondrules and type C CAIs. The combined trend of bulk compositions for CAIs, Al-rich chondrules, and ferromagnesian chondrules mirrors, but does not exactly match, the trend predicted from equilibrium condensation at P_T ∼ 10^-3 atm; the observed trend does not match the trend found for evaporation from a liquid of chondritic composition. We thus infer that the bulk compositions of the precursors to CAIs, Al-rich chondrules, were ferromagnesian chondrules were controlled primarily by vapor-solid reactions (condensation or sublimation) in the solar nebula. Some Al-rich chondrules are consistent with an origin by melting of a compound CAI-ferromagnesian chondrule hybrid; others cannot be so explained. Any hybrid model is restricted by the constraint that the CAI precursor consisted dominantly of pyroxene + plagioclase + spinel; melilite cannot have been a significant component. Amoeboid olivine aggregates also have the inferred mineralogical characteristics of Al-rich chondrule precursors—they are mixtures of olivine with plagioclase-spinel-pyroxene-rich CAIs—but the few measured bulk compositions are more olivine-rich than those of Al-rich chondrules.  相似文献   

Attenuation of photosynthetically available radiation (PAR) in Florida Bay: Potential for light limitation of primary producers     

Christopher R. Kelble  Peter B. Ortner  Gary L. Hitchcock  Joseph N. Boyer 《Estuaries and Coasts》2005,28(4):560-571

Light attenuation in marine ecosystems can limit primary production and determine the species composition and abundance of primary producers. In Florida Bay, the importance of understanding the present light environment has heightened as major upstream water management restoration projects have been proposed and some are already being implemented. We analyzed a 2-yr (2001–2003) data set of the light attenuation coefficient (K_t) and its principal components (water, chromophoric dissolved organic matter [CDOM], tripton, phytoplankton) obtained at 40 stations within Florida Bay, calibrated synoptic underway data to produce high spatial resolution maps, examined the potential for light limitation, and quantified the individual effect of each component upon light attenuation. Tripton was the dominant component controlling light attenuation throughout Florida Bay, whereas the contribution of chlorophylla and CDOM to K_t was much smaller in all regions of Florida Bay. It was possible to accurately estimate the light attenuation coefficient from component concentrations, using either a mechanistic or a statistical model with root mean square errors of 0.252 or 0.193 m⁻¹, respectively. Compared to other estuaries, Florida Bay had the lowest overall K_t and the greatest relative contribution from tripton. Comparing the recent data to a study of Florida Bay’s light environment conducted in 1993–1994, we found that overall water clarity in the Bay increased significantly, indicated by a nearly 3-fold decrease in K_v as a result of lower tripton concentrations, although the percent contribution of each of the components to K_t is unchanged. Only the northwest corner of Florida Bay, an area comprised of approximately 8% of the Bay’s total area, was found on average to have sufficient light attenuation to limit the growth of seagrasses. This is much less extensive than in 1993–1994, when seagrass growth was potentially limited by light at over 50% of the stations sampled.  相似文献   

P波随时间衰减:以两条加利福尼亚地震破裂带为例   总被引：1，自引：0，他引：1       下载免费PDF全文

ChunKin-Yip GaryAHenderson 《地球物理学报》2005,48(4):851-860

地震预测是地震学研究一个基本目标,而理解地震周期是地震预测的重要环节.遗憾的是,由于地震断层带不但结构复杂,大地震前后短时间内的震源过程更是随时间迅速变化,这些复杂因素使得常规研究方法不再适用.一类特殊的微震成群地发生在主震断层几乎同一地点上,震源系数几乎相同,近年来地震学界通称其为震群(earthquakemultiplet).本文论证如何将这类特殊的微震作为一组人工震源来阐述美国西部两次大地震(LomaPrieta和MorganHill)的震后弛豫过程.在加利福尼亚LomaPrieta(1989年9月18日,M7.0)及MorganHill(1984年4月24日,M6.2)附近的主震破裂带中就发生了此类震群.其中有两组各包含11个重复地震的震群,分别位于这两个破裂带中,其波形资料质量高,波形及震级变化极小,因而可与实验室条件下的人工震源相比.这些震群地震资料可直接用于计算P波沿波程衰减(即t)的时间性变化,其方法的简单性及结果的精确性都与实验室水平相当.我们的结果显示,每个震群周围分别存在一个异常体,在其各自主震之后的10个月中,该异常体中的P波衰减迅速上升并降落.衰减峰值发生在LomaPrieta地震后2～3周,其震群深度为10.2km.此峰值在MorganHill地震后5～6个月发生,其震群中心深度为2.6km.这两个事例中,t波动峰值都超过此前获得的加利福尼亚大致同一地区t绝对值的100%[1].此结果显示了因同震裂隙张开和震后弛豫过程(如流体移动、裂隙复原及岩石压缩),以及孔隙度和流体饱和度在主震源体部分区域发生的变化.衰减达峰值的时间之显著差异则提示我们,裂隙闭合及伴随的流体移动是负载敏感的,深度越大达峰值越快,反之亦然.如将此方法应用于主震前多重地震的资料,将有望更好地理解最终导致主震断层带大破裂的震前微破裂的物理过程.  相似文献   

In Situ Biotransformation of BTEX Compounds Under Methanogenic Conditions   总被引：3，自引：0，他引：3  

Martin Reinhard  Gary D. Hopkins  Eva Steinle-Darling  Carmen A. LeBron 《Ground Water Monitoring & Remediation》2005,25(4):50-59

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Targets of opportunity in two landscapes of financial globalization     

Gary A. Dymski 《Geoforum》2006,37(3):307-311

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Hydrogen from coal gasification: An economical pathway to a sustainable energy future   总被引：2，自引：0，他引：2  

Gary J. Stiegel  Massood Ramezan   《International Journal of Coal Geology》2006,65(3-4):173-190

Although hydrogen is the most abundant element in the universe, it does not occur naturally in large quantities or high concentrations on Earth. Hydrogen must be produced from other compounds such as fossil fuels, biomass, or water and is therefore considered an energy carrier like electricity. Gasification of carbonaceous, hydrogen-containing fuels is an effective method of thermal hydrogen production and is considered to be a key technology in the transition to a hydrogen economy. However, for gasification to play a major role during the transition period, capital and operating cost must be reduced and reliability and performance must be improved.Analyses show that hydrogen produced from coal-based gasification can be competitive with production from natural gas provided the cost of natural gas remains above $4/10⁶ Btu and the high reliability of gasification-based processes can be demonstrated. But for coal to be considered in a carbon-constrained environment, the cost of natural gas would have to be greater than $5.50/10⁶ Btu. The development of advanced technologies, however, offers the potential for significant reductions in capital costs, improved thermal efficiencies, and increased reliability. If these advanced technologies are capable of achieving their goals, the cost of producing hydrogen from coal could be reduced by 25–50%, even with the capture and sequestration of CO₂. With these reductions, the cost of natural gas would have to be less than $2.50/10⁶ Btu to compete, a scenario that is very unlikely to occur in the future. This potential cost reduction provides considerable impetus for continuing research and development in the production of hydrogen from coal.  相似文献   

Landscape connectivity: the geographic basis of geomorphic applications   总被引：7，自引：0，他引：7  

Gary Brierley  Kirstie Fryirs  Vikrant Jain 《Area》2006,38(2):165-174

Geographic concerns for spatial relationships lie at the heart of geomorphic applications in environmental management. The way in which landscape compartments fit together in a catchment influences the operation of biophysical fluxes, and hence the ways in which disturbance responses are mediated over time. These relationships reflect the connectivity of the landscape. A nested hierarchical framework that emphasizes differing forms of (dis)connectivity in catchments is proposed. This field-based geomorphic tool can be used to ground the application of modelling techniques in analysis of catchment-scale biophysical fluxes.  相似文献   

Indirect approach to invariant point determination for SLR and VLBI systems: an assessment     

John Dawson  Pierguido Sarti  Gary M. Johnston  Luca Vittuari 《Journal of Geodesy》2007,81(6-8):433-441

We assess the accuracy of some indirect approaches to invariant point (IVP), or system reference point, determination of satellite laser ranging (SLR) and very long baseline interferometry (VLBI) systems using both observed and simulated survey data sets. Indirect IVP determination involves the observation of targets located on these systems during specific rotational sequences and by application of geometrical models that describe the target motion during these sequences. Of concern is that most SLR and VLBI systems have limited rotational freedom thereby placing constraint on the reliability of parameter estimation, including the IVP position. We assess two current approaches to IVP analysis using survey data observed at the Yarragadee (Australia) SLR and the Medicina (Italy) VLBI sites and also simulated data of a large rotationally constrained (azimuth-elevation) VLBI system. To improve reliability we introduce and assess some new geometric conditions, including inter-axis, inter-circle and inter-target conditions, to existing IVP analysis strategies. The error component of a local tie specifically associated with the indirect determination of SLR and VLBI IVP is less than 0.5 mm. For systems with significant rotational limits we find that the inter-axis and inter-circle conditions are critical to the computation of unbiased IVP coordinates at the sub-millimetre level. When the inter-axis and inter-circle geometric conditions are not imposed, we retrieve biased vertical coordinates of the IVP (in our simulated VLBI system) in the range of 1.2–3.4 mm. Using the new geometric conditions we also find that the axis-offset estimates can be recovered at the sub- millimetre accuracy (0.5 mm).  相似文献   

Constraining recycled detritus in quartz‐rich sandstones: Insights from a multi‐proxy provenance study of the Mid‐Carboniferous,Clare Basin,western Ireland     

Martin Nauton‐Fourteu  Shane Tyrrell  Andrew Morton  Chris Mark  Gary J. O&#x;Sullivan  David M. Chew 《Basin Research》2021,33(1):342-363

Quartz‐rich sandstones can be produced through multiple sedimentary processes, potentially acting in combination, such as extensive sedimentary recycling or intense chemical weathering. Determining the provenance of such sedimentary rocks can be challenging due to low amounts of accessory minerals, the fact that the primary mineralogy may have been altered during transport, storage or burial and difficulties in the recognition of polycyclic components. This study uses zircon and apatite U‐Pb geochronology, apatite trace elements, zircon‐tourmaline‐rutile indices and petrographic observations to investigate the sedimentary history of mineralogically mature mid‐Carboniferous sandstones of the Tullig Cyclothem, Clare Basin, western Ireland. The provenance data show that the sandstones have been dominantly and ultimately sourced from three basement terranes: older Laurentian‐ associated rocks (ca. 900–2500 Ma) which lay to the north of the basin, peri‐Gondwanan terranes (ca. 500–700 Ma) to the south and igneous intrusive rocks associated with the Caledonian Orogenic Cycle (ca. 380–500 Ma). However, the multi‐proxy approach also helps constrain the sedimentary history and suggests that not all grain populations were derived directly from their original source. Grains with a Laurentian or a Caledonian affinity have likely been recycled through Devonian basins to the south. Grains with a peri‐Gondwanan affinity appear to be first cycle and are potentially derived from south/southwest of the basin. Taken as a whole, these data are consistent with input into the basin from the south and southwest, with the reworking of older sedimentary rocks, rather than intensive first‐cycle chemical weathering, likely explaining the compositional maturity of the sandstones. This study highlights the need for a multi‐proxy provenance approach to constrain sedimentary recycling, particularly in compositionally mature sandstones, as the use of zircon geochronology alone would have led to erroneous provenance interpretations. Zircon, together with U‐Pb geochronology from more labile phases such as apatite, can help distinguish first‐cycle versus polycyclic detritus.  相似文献   

Coalification of organic matter in coal balls of the Pennsylvanian (upper Carboniferous) of the Illinois Basin, United States     

Paul C. Lyons  Carolyn L. Thompson  Patrick G. Hatcher  Floyd W. Brown  Michael A. Millay  Nikolaus Szeverenyi  Gary E. Maciel 《Organic Geochemistry》1984,5(4):227-239

An evaluation was made of the degree of coalification of two coal balls from the Illinois Basin of the Pennsylvanian (upper Carboniferous) of the United States. Previous interpretations are mainly misleading and contradictory, primarily because of the assumption that the brown color and exceptional cellular and subcellular preservation typical of American coal balls imply chemical preservation of cellulose and lignin, the primary components of peat. Xylem tissue from a medullosan seed fern contained in a coal ball and the coal attached to the coal ball from the Calhoun coal bed, Mattoon Formation, Illinois, was analyzed by elemental, petrographic, and nuclear magnetic resonance (NMR) techniques to determine the degree of coalification. The NMR and elemental data indicate the lack of cellulose and lignin and a probable rank of high-volatile C bituminous coal. These data corroborate data for a coal ball from the Herrin (No. 6) coal bed (Carbondale Formation, Middle Pennsylvanian) and support our hypothesis that the organic matter in coal balls of the Pennsylvanian strata of the United States is coalified to about the same degree as the surrounding coal. Data presented show a range of lower reflectances for xylem tissue and vitrinite in the analyzed coal balls compared with vitrinite in the attached coal.The data reported indicate that physical preservation of organic matter in coal balls does not imply chemical preservation. Also our study supports the hypothesis that compactional (static load) pressure is not a prerequisite for coalification up to a rank of high-volatile C bituminous coal.A whole-rock analysis of the Calhoun coal ball indicates a similarity to other carbonate coal balls from the United States. It consists primarily of calcium carbonate and 1–2% organic matter; silica and alumina together make up less than 0.5%, indicating the lack of minerals such as quartz and clays.  相似文献