Compositional limits and analogs of monoclinic triple-chain silicates     

David M. Jenkins  Geoffrey J. Gilleaudeau  Cynthia Kawa  Jaclyn M. Dibiase  Maria Fokin 《Contributions to Mineralogy and Petrology》2012,164(2):229-244

Growing recognition of triple-chain silicates in nature has prompted experimental research into the conditions under which they can form and the extent of solid solution that is feasible for some key chemical substitutions. Experiments were done primarily in the range of 0.1–0.5 GPa and 200–850 °C for durations of 18–1,034 h. A wide range of bulk compositions were explored in this study that can be classified broadly into two groups: those that are Na free and involve various possible chemical substitutions into jimthompsonite (Mg₁₀Si₁₂O₃₂(OH)₄), and those that are Na bearing and involve chemical substitutions into the ideal end-member Na₄Mg₈Si₁₂O₃₂(OH)₄. Numerous attempts to synthesize jimthompsonite or clinojimthompsonite were unsuccessful despite the type of starting material used (reagent oxides, magnesite + SiO₂, talc + enstatite, or anthophyllite). Similarly, the chemical substitutions of F⁻ for OH⁻, Mn²⁺, Ca²⁺, or Fe²⁺ for Mg²⁺, and 2Li⁺ for Mg²⁺ and a vacancy were unsuccessful at nucleating triple-chain silicates. Conversely, nearly pure yields of monoclinic triple-chain silicate could be made at temperatures of 440–630 °C and 0.2 GPa from the composition Na₄Mg₈Si₁₂O₃₂(OH)₄, as found in previous studies, though its composition is most likely depleted in Na as evidenced by electron microprobe and FTIR analysis. Pure yields of triple-chain silicate were also obtained for the F-analog composition Na₄Mg₈Si₁₂O₃₂F₄ at 550–750 °C and 0.2–0.5 GPa if a flux consisting of Na-halide salt and water in a 2:1 ratio by weight was used. In addition, limited chemical substitution could be documented for the substitutions of 2 Na⁺ for Na⁺ + H⁺ and of Mg²⁺ + vacancy for 2Na⁺. For the former, the Na content appears to be limited to 2.5 cations giving the ideal composition of Na_2.5Mg₈Si₁₂O_30.5(OH)_5.5, while for the latter substitution the Na content may go as low as 1.1 cations giving the composition Na_1.1Mg_9.4Si₁₂O_31.9(OH)_4.1 based on a fixed number of Si cations. Further investigation involving Mg for Na cation exchange may provide a pathway for the synthesis of Na-free clinojimthompsonite. Fairly extensive solid solution was also observed for triple-chain silicates made along the compositional join Na₄Mg₈Si₁₂O₃₂(OH)₄–Ca₂Mg₈Si₁₂O₃₂(OH)₄ where the limit of Ca substitution at 450 °C and 0.2 GPa corresponds to Na_0.7Ca_1.8Mg_7.8Si₁₂O_31.9(OH)_4.1 (with the OH content adjusted to achieve charge balance). Aside from the Na content, this composition is similar to that observed as wide-chain lamellae in host actinolite. The relative ease with which Na-rich triple chains can be made experimentally suggests that these phases might exist in nature; this study provides additional insights into the range of compositions and formation conditions at which they might occur.  相似文献   

Assessing drought threats to agricultural water supplies under climate change by combining the SWAT and MODSIM models for the Geum River basin,South Korea     

So Ra Ahn  Jae Hak Jeong 《水文科学杂志》2013,58(15):2740-2753

ABSTRACT

The impacts of future climate change on the agricultural water supply capacities of irrigation facilities in the Geum River basin (9645.5 km²) of South Korea were investigated using an integrated modeling framework that included a water balance network model (MODSIM) and a watershed-scale hydrologic model (Soil and Water Assessment Tool, SWAT). The discharges and baseflows from upland drainage areas were estimated using SWAT, and the predicted flow was used to feed agricultural reservoirs and multipurpose dams in subwatersheds. Using a split sampling method, we calibrated the daily streamflows and dam inflows at three locations using data from 6 years, including 3 years of calibration data (2005–2007) followed by 3 years of validation data (2008–2010). In the MODSIM model, the entire basin was divided into 14 subwatersheds in which various agricultural irrigation facilities such as agricultural reservoirs, pumping stations, diversions, culverts and groundwater wells were defined as a network of hydraulic structures within each subwatershed. These hydraulic networks between subwatersheds were inter-connected to allow watershed-scale analysis and were further connected to municipal and industrial water supplies under various hydrologic conditions. Projected climate data from the HadGEM3-RA RCP 4.5 and 8.5 scenarios for the period of 2006–2099 were imported to SWAT to calculate the water yield, and the output was transferred to MODSIM in the form of time-series boundary conditions. The maximum shortage rate of agricultural water was estimated as 38.2% for the 2040s and 2080s under the RCP 4.5 scenario but was lower under the RCP 8.5 scenario (21.3% in the 2040s and 22.1% in the 2080s). Under the RCP 4.5 scenario, the projected shortage rate was higher than that during the measured baseline period (1982–2011) of 25.6% and the RCP historical period (1982–2005) of 30.1%. The future elevated drought levels are primarily attributed to the increasingly concentrated rainfall distribution throughout the year under a monsoonal climate, as projected by the IPCC climate scenarios.