The diffusion kinetics of CO2 in cordierite: an HT-FTIR microspectroscopy study     

Francesco Radica  Giancarlo Della Ventura  Fabio Bellatreccia  Gianfelice Cinque  Augusto Marcelli  Mariangela Cestelli Guidi 《Contributions to Mineralogy and Petrology》2016,171(2):12

  相似文献   

Iron release in aqueous environment by fresh volcanic ash from Mount Etna (Italy) and Popocatépetl (Mexico) volcanoes     

Giancarlo Capitani  Nobuyoshi Miyajima  Roberto Sulpizio  Maria D’Addabbo  Lucia Galimberti  Massimo Guidi  Giovanni B. Andreozzi 《Environmental Earth Sciences》2018,77(13):521

In this study, we performed leaching experiments for timescales of hours-to-months in deionized water on fresh volcanic ash from Mt. Etna (Italy) and Popocatépetl (Mexico) volcanos to monitor Fe release as a function of ash mineral chemistry and size, with the aim of clarifying Fe release mechanisms and eventually evaluating the impact of volcanic ash on marine and lacustrine environments. To define sample mineralogy and Fe speciation, inclusive characterization was obtained by means of XRF, SEM, XRPD, EELS and Mössbauer spectroscopies. For Etna and Popocatépetl samples, glass proportions were quantified at 73 and 40%, Fe₂O₃ total contents at 11.6–13.2 and 5.8 wt%, and Fe³⁺/Fe_Tot ratios at 0.33 and 0.23, respectively. Leaching experiments showed that significant amounts of iron, ~?30 to 150 and ~?750 nmol g^?1 l^?1 for pristine Etna and Popocatépetl samples, respectively, are released within the first 30 min as a function of decreasing particle size (from 1 to 0.125 mm). The Popocatépetl sample showed a very sustained Fe release (up to 10 times Etna samples) all along the first week, with lowest values never below 400 nmol g^?1 l^?1 and a maximum of 1672 nmol g^?1 l^?1 recorded after 5 days. This sample, being composed of very small particles (average particle size 0.125 mm) with large surface area, likely accumulated large quantities of Fe-bearing sublimates that quickly dissolved during leaching tests, determining high Fe release and local pH decrease (that contributed to release more Fe from the glass) at short timescale (hours-to-days). The fractional Fe solubility (Fe_S) was 0.004–0.011 and 0.23% for Etna and Popocatépetl samples, respectively, but no correlation was found between Fe released in solution and either ash Fe content, glass/mineral ratio or mineral assemblage. Results obtained suggest that volcanic ash chemistry, mineralogy and particle size assume a relevant role on Fe release mostly in the medium-to-long timescale, while Fe release in the short timescale is dominated by dissolution of surface sublimates (formed by physicochemical processes occurring within the eruption plume and volcanic cloud) and the effects of such a dissolution on the local pH conditions. For all samples, a moderate to sustained Fe release occurred for leaching times comparable with their residence time within the euphotic zone of marine and lacustrine environments (variable from few minutes to few hours), revealing their possible contribution to increase Fe bioavailability.  相似文献   

A Reliable Method for Determining the Oxidation State of Manganese at the Microscale in Mn Oxides via Raman Spectroscopy     

Simone Bernardini  Fabio Bellatreccia  Giancarlo Della Ventura  Armida Sodo 《Geostandards and Geoanalytical Research》2021,45(1):223-244

Manganese oxides are important geomaterials, widespread in terrestrial and Martian environments. Characterisation of the oxidation state of Mn is a central issue in science; this task has been addressed up to the present by X‐ray spectroscopy or diffraction techniques. The former, however, requires access to synchrotron facilities, while the latter does not provide crystal‐chemical information at the local scale. In this work, we compare a large set of Raman data from well‐characterised samples, already published by the same authors of this paper or as found in the literature. We show a clear correlation between the oxidation state of Mn and the wavenumber of peculiar bands; octahedrally co‐ordinated Mn²⁺ is recognised by a band around 530 cm^?1, Mn³⁺ by a band around 580 cm^?1 and Mn⁴⁺ by a band around 630 cm^?1, while tetrahedrally co‐ordinated Mn²⁺ is recognisable by a band around 650 cm^?1. Strongly distorted Mn³⁺ octahedra are indicated by the appearance of Jahn–Teller modes. Our method allows a reliable, easily accessible tool to characterise the oxidation states of Mn in oxides, also suitable for microscale mapping. It provides a robust analytical basis for the use of these minerals as redox indicators in geology/geochemistry, in exoplanetary research or for monitoring technological processes.  相似文献   

Intra‐messinian gypsum palaeokarst in the Northern Apennines and its palaeogeographic implications     

Jo De Waele  Giancarlo Pasini 《地学学报》2013,25(3):199-205

A short intra‐Messinian continental period has been recognised in some North Italian gypsum areas, mostly under the form of palaeokarst deposits. This emersion appears to have occurred only locally, and is explained as caused by the intra‐Messinian tectonic phase and a major sea level lowering. Evidences of this palaeokarst are mostly small, although at some places the palaeontological content of its fillings is of great importance. The discovery near Zola Predosa (Bologna) of a new intra‐Messinian extensive karst system and of its infilling sheds new light on the importance of this karst episode.  相似文献   

Human influence on seagrass habitat fragmentation in NW Mediterranean Sea     

Monica Montefalcone  Valeriano ParraviciniMatteo Vacchi  Giancarlo AlbertelliMarco Ferrari  Carla MorriCarlo Nike Bianchi 《Estuarine, Coastal and Shelf Science》2010

Habitat fragmentation in meadows of Posidonia oceanica, the most important and abundant seagrass in the Mediterranean Sea, was investigated at a region-wide spatial scale using a synthetic ecological index, the Patchiness Index (PI). We tested the hypothesis that human impacts are the major factor responsible for habitat fragmentation in P. oceanica meadows contrasting fragmentation of meadows located in “anthropized” areas with that of meadows located in areas with low anthropization and considered as virtually “natural”. We also related fragmentation of meadow with the morphodynamic state of the submerged beach (i.e. distinctive types of beach produced by the topography, the wave climate and the sediment composition) in order to investigate the influence of one natural component on the seagrass meadow seascape. Results demonstrated that fragmentation in the P. oceanica meadows is strongly influenced by the human component, being lower in natural meadows than in anthropized ones, and that it is little influenced by the morphodynamic state of the coast. The use of landscape approaches to discriminate natural disturbance from human impacts that affect seagrass meadows is thus recommended for the proper management of coastal zones.  相似文献   

The Monte Orfano Conglomerate revisited: stratigraphic constraints on Cenozoic tectonic uplift of the Southern Alps (Lombardy, northern Italy)   总被引：1，自引：0，他引：1  

Dario Sciunnach  Giancarlo Scardia  Fabrizio Tremolada  Isabella Premoli Silva 《International Journal of Earth Sciences》2010,99(6):1335-1355

The Monte Orfano Conglomerate (MOC), exposed in the foothills of the Southern Alps (northern Italy), is one of the few outcrops of sediments documenting the Cenozoic tectonic evolution of the Alpine retrowedge. Calcareous nannofossil biostratigraphy allowed us to constrain the upper part of the MOC, formerly attributed to the Early-Middle Miocene in the type-locality, to the earliest Miocene (Neogene part of the NN1 nannofossil zone). A likely latest Oligocene age is therefore suggested for the bulk of the underlying conglomerates, whose base is not exposed. Deposition of the MOC can be placed within the post-collisional tectonic uplift of the Alps, documented in the Lake Como area by the Como Conglomerate (CC) at the base of the Gonfolite Lombarda Group, and supports the correlation with Upper Oligocene clastic sediments cropping out further to the East, in the Lake Garda and in the Veneto-Friuli areas (“molassa”). The remarkable difference in petrographic composition between the western (CC) and eastern (MOC) clastics deposited in the Alpine retro-foreland basin highlights the synchronous tectonic activity of two structural domains involving different crustal levels. Whilst the bulk of the CC, that straddles the Oligocene/Miocene boundary, records largely the tectonic exhumation of the Alpine axial chain crystalline complexes, the coeval MOC consists of detritus derived from the superficial crustal section (Triassic to Paleogene sedimentary rocks) of the Alpine retrowedge and constrains the onset of the post-collisional deformation phase of the Southern Alps as not younger than the Late Oligocene.  相似文献   

An approximate F.E. analysis of seepage with a free surface     

Annamaria Cividini  Giancarlo Gioda 《国际地质力学数值与分析法杂志》1984,8(6):549-566

An approximate step-by-step procedure is presented for the finite element analysis of transient unconfined flow problems. At each step the free surface is modelled by means of segments coinciding with sides of the elements. This leads to an approximate but extremely simple solution scheme which can be readily incorporated into standard codes for confined analysis. The solutions of some significant problems are presented and compared with other non-approximate solutions. They show that the technique, in spite of its approximation, is capable of giving meaningful results from an engineering viewpoint.  相似文献   

Assessment of toxicological status of a SW Mediterranean segment population of striped dolphin (Stenella coeruleoalba) using skin biopsy     

Fossi MC  Marsili L  Lauriano G  Fortuna C  Canese S  Ancora S  Leonzio C  Romeo T  Merino R  Abad E  Jiménez B 《Marine environmental research》2004,58(2-5):269-274

Various studies have revealed high concentrations of contaminants such as organochlorines (OCs) and heavy metals in Mediterranean cetaceans. A geographical trend of contamination (PCBs and DDTs) has been found for striped dolphin (Stenella coeruleoalba). In this study we used a non-lethal approach (skin biopsy) to investigate bioaccumulation of OCs, including polychlorobiphenyls (PCBs), DDTs, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), trace elements (Hg, Cd, Pb) and CYP1A activity (BPMO) in nine striped dolphins sampled in the Aeolian area (Sicily - Italy) in summer 2002. The arithmetic mean value of BPMO activity in this group was 43.46 AUF/g tissue/h. This value is approximately 3 times and 5 times lower, respectively, than the value found in the Ionian and in the Ligurian groups. Skin biopsies of striped dolphins emerged as a suitable material for assessing the toxicological status of the various Mediterranean groups.  相似文献   

Hillslope scale soil moisture variability in a steep alpine terrain   总被引：1，自引：0，他引：1  

Daniele Penna  Marco Borga  Daniele Norbiato  Giancarlo Dalla Fontana 《Journal of Hydrology》2009,364(3-4):311-327

  相似文献   

Vibrios in association with sedimentary crustaceans in three beaches of the northern Adriatic Sea (Italy)   总被引：3，自引：0，他引：3  

Covazzi Harriague A  Brino MD  Zampini M  Albertelli G  Pruzzo C  Misic C 《Marine pollution bulletin》2008,56(3):574-579

In the marine environment, vibrios adhere to a number of substrates including chitin-rich organisms such as crustaceans. Their wide diffusion in coastal waters and pathogenic potential require knowledge of the lifestyle and environmental reservoirs of these bacteria. To test the presence of culturable vibrios in coastal areas and their association with benthic crustaceans, vibrios were isolated from water, sediments and crustaceans (copepods and anphipods) at three stations placed in front of heavily used tourist beaches of the Adriatic Sea. We observed significant correlations between vibrios and temperature. Benthic and planktonic copepods harboured vibrios in summer, while benthic amphipods harboured these bacteria in spring and autumn. Vibrio alginolyticus and Vibrio parahaemolyticus strains gave positive results using primers for Vibrio cholerae toxR and toxS. Sedimentary crustaceans may extend Vibrio persistence in seawater and may represent an additional aquatic reservoir of these bacteria.  相似文献