Stability of Titanium Dioxide Nanoparticle Agglomerates in Transitional Waters and Their Effects Towards Plankton from Lagoon of Venice (Italy)     

Clémentine Perstrimaux  Séverine Le Faucheur  Monika Mortimer  Serge Stoll  Fabrizio Bernardi Aubry  Margherita Botter  Roberto Zonta  Vera I. Slaveykova 《Aquatic Geochemistry》2015,21(2-4):343-362

The present study explores the effect of salinity and dissolved organic carbon (DOC) gradients on the stability and reactivity of titanium dioxide nanoparticle (TiO₂-NP) agglomerates in ambient water from the Lagoon of Venice and their possible effect on nauplii sampled at the same locations. In all ambient water samples, TiO₂-NPs formed rapidly micrometre-sized agglomerates. The increase in the salinity and concomitant decrease in DOC content induced the formation of larger agglomerates, with z-average hydrodynamic diameter increasing with TiO₂-NP concentration and exposure duration. Under the studied conditions, ζ-potential exhibited negative values. In line with agglomeration results, enhancement of the salinity and lower DOC resulted in less negative ζ-potential with close to 0 values in the dispersions of 100 mg L^?1 TiO₂-NPs in sea water. Two-hour exposure to micrometre-sized agglomerates of TiO₂-NPs resulted in an increase in the fluorescence of propidium iodide (PI) stained nauplii in comparison with unexposed controls, but had no effect at 24-h exposure. The increase in nauplii-associated PI fluorescence was more noticeable in dispersions containing 100 mg L^?1 than those containing 10 mg L^?1 TiO₂-NPs, suggesting membrane permeability alteration in a concentration-dependent manner. However, the PI staining results have to be interpreted with caution because of the possible dye binding to the nauplii surface without penetration of cellular membrane. The effect of TiO₂-NPs on nauplii was more pronounced at higher salinity and decreased with increasing DOC concentrations at 2 h, while no trends were found at 24-h exposure, as well as exposure to 100 mg L^?1 TiO₂-NPs.  相似文献   

On the Use of Interferometric Synthetic Aperture Radar Data for Monitoring and Forecasting Natural Hazards     

Bernardi  Mara S.  Africa  Pasquale C.  de Falco  Carlo  Formaggia  Luca  Menafoglio  Alessandra  Vantini  Simone 《Mathematical Geosciences》2021,53(8):1781-1812

Mathematical Geosciences - Recent advances in satellite technologies, statistical and mathematical models, and computational resources have paved the way for operational use of satellite data in...  相似文献   

Conditional risk based on multivariate hazard scenarios   总被引：1，自引：1，他引：0  

Mauro?Bernardi  Fabrizio?DuranteEmail authorView author&#;s OrcID profile  Piotr?Jaworski  Lea?Petrella  Gianfausto?Salvadori 《Stochastic Environmental Research and Risk Assessment (SERRA)》2018,32(1):203-211

We present a novel methodology to compute conditional risk measures when the conditioning event depends on a number of random variables. Specifically, given a random vector \((\mathbf {X},Y)\), we consider risk measures that express the risk of Y given that \(\mathbf {X}\) assumes values in an extreme multidimensional region. In particular, the considered risky regions are related to the AND, OR, Kendall and Survival Kendall hazard scenarios that are commonly used in environmental literature. Several closed formulas are considered (especially in the AND and OR scenarios). An application to spatial risk analysis involving real data is discussed.  相似文献   

Chemistry and sulfur isotopic composition of precipitation at Bologna, Italy   总被引：2，自引：0，他引：2  

Pasquale Panettiere  Gianni Cortecci  Enrico Dinelli  Alberto Bencini  Massimo Guidi 《Applied Geochemistry》2000,15(10):2127

Individual and monthly precipitation samples from the polluted atmosphere of Bologna (Emilia-Romagna province) were collected during March 1996 to May 1997 and analyzed for major ions in solution and S isotopes in dissolved SO₄.Weighted mean enrichment factors relative to seawater are found to be 1.0 for Na, 15.2 for K, 105 for Ca, 3.3 for Mg, 17.3 for SO₄ and 663 for HCO⁻₃. Very good positive correlations are observed for the Ca²⁺–Mg²⁺–HCO⁻₃–SO²⁻₄–NO⁻₃ system, indicating that dissolution of Ca (±Mg)-carbonate particles by H₂SO₄ and HNO₃ from combustion of oil and gas is a major process controlling the chemical composition of rain and snow. Na⁺ and Cl⁻ in monthly precipitation derive essentially from sea spray, but the contribution of Na⁺ from continental sources is appreciable in a number of individual rains. NH⁺₄ appears to be on average more abundant in spring and summer precipitation, its main sources being microbial activity in soils and application of fertilizers. K⁺ is probably of continental origin from soil dust.The S isotopic composition of SO₄ is systematically positive, with mean δ³⁴S values of +3.2±1.6‰ (n=40) in individual precipitation and +2.8±1.4‰ (n=12) in monthly precipitation. These isotopic compositions are interpreted in terms of a dominant contribution of S from anthropogenic emissions and subordinate contributions from biogenic and marine sources. Pollutant SO₄ is estimated to have a δ³⁴S value in the range +2.5 to +4.5‰, whereas a distinctive δ³⁴S of −4.5‰ or lower indicates SO₄ from oxidation of biogenic gases.The isotopic and chemical compositions of SO₄ do not depend on wind direction, thus testifying to a mostly local source for pollutant S in the Bologna atmosphere.  相似文献   

Hydrological and biogeochemical features of the Northern Adriatic Sea in the period 2003–2006     

Giorgio Socal  Francesco Acri  Mauro Bastianini  Fabrizio Bernardi Aubry  Franco Bianchi  Daniele Cassin  Joan Coppola  Amelia De Lazzari  Vinko Bandelj  Gianpiero Cossarini  Cosimo Solidoro 《Marine Ecology》2008,29(4):449-468

This paper reports on the main biogeochemical properties of the Northern Adriatic Sea in the period May 2003–November 2006 within the framework of the European program INTERREG III Italy‐Slovenia. Spatial and temporal distributions of water density, dissolved oxygen, nutrients (nitrogen, phosphorous and silicon) and chlorophyll a are presented. Multivariate methods such as fuzzy k‐means, self‐organising maps and cluster analysis were used to identify the different water masses and to characterise the temporal and spatial variability of the main biogeochemical features present in the area. The results confirm that the Po River outflows and the meteorological forcing factors are the main components triggering the alternation of stratification and mixing of the water column and that strongly affect the trophic state of the basin. In general, oligotrophic conditions dominate, and were more pronounced offshore, but mesotrophy occurred episodically in May 2004 and July 2005, when phytoplankton blooms were observed concomitant with vertical stability of the water column. A marked interannual variability was also observed, supporting the importance of maintaining long‐term observations of the basin.  相似文献   

Spatial and temporal prokaryotic variability in the northern Adriatic Sea     

Paola Del Negro  Mauro Celussi  Erica Crevatin  Alessandro Paoli  Fabrizio Bernardi Aubry  Alessandra Pugnetti 《Marine Ecology》2008,29(3):375-386

The prokaryotic community, both in terms of abundance and activity (exoenzymatic hydrolysis of proteins, polysaccharides and phosphorylated molecules and leucine uptake), was investigated seasonally for a 3‐year period (2004–2006) in the Gulf of Venice (northern Adriatic Sea). By focusing on spatial and temporal variability, the prokaryote dynamics showed significant variations on a horizontal and seasonal scale, but no substantial differences were observed among years. The basin‐scale variability was mainly influenced by allochthonous inputs from the Po river and the Venice Lagoon, which were the main source of nutrients, acting as a ‘bottom up’ control on prokaryotes. On a seasonal scale, all the microbial parameters (except the polysaccharide degradation) showed significant variations following the temperature fluctuations. The annual rate of change was very low for all the chemical, physical and biological parameters and only the abundance and phosphatase activity of the prokaryotes differed significantly among years.  相似文献   

A modeling language to support the interoperability of global navigation satellite systems     

Daniele Gianni  Joachim Fuchs  Pierluigi De Simone  Marco Lisi 《GPS Solutions》2013,17(2):175-198

The availability of multiple Global Navigation Satellite Systems (GNSS) will offer the opportunity to provide seamless navigation services and improved positioning performance. However, before this opportunity can be exploited, a number of issues need to be solved to ensure the compatibility and interoperability of existing GNSS. In particular, the GNSS interoperability can be technically defined as the capability of receivers to compute their global position using two or more GNSS signals. This capability can be more effectively achieved if Signal-In-Space interface specifications are available in a consistent, unambiguous, and possibly standard format, which can support engineers to design interoperable receivers. We aim to support the design of interoperable receivers with the introduction of the Interface Communication Modeling Language (ICML), a graphical language for the formal specification of Signal-In-Space interfaces. The ICML language enables receiver engineers to specify these interfaces at different levels of abstraction, such as analog signal or binary data. In addition, the ICML language also supports the specification of conversion routines between adjacent levels, for the representation of the dynamic aspects—e.g., convolution and encryption processes—of the interface specification. As such, the ICML language proposes an alternative format to textual-based interface specifications and can possibly integrate with the ongoing trend of the Model-based Systems Engineering approaches. We present the structure of the framework implementing the language and an example ICML-based specification for a simplified and reduced version of the Galileo Freely Accessible Navigation (F/NAV) message. The language metamodel is also attached for technical reference. An important caveat: no endorsement is made for the use of the ICML language for the official Galileo Signal-In-Space interface specification.  相似文献   

Climate control on snowfall days in peninsular Italy     

Nazzareno Diodato  Gianni Bellocchi 《Theoretical and Applied Climatology》2020,140(3):951-961

The advent of instrumental and digital weather observatories has not eliminated the substantial gaps within surface meteorological time series. In particular, the lack of long-term homogeneous snowfall records may be a major impediment for hydrologic studies. We tested the hypothesis that reliable estimates of snowy days per year (SDY) can be produced for peninsular Italy, based on weather and site measurements from a limited set of stations centrally located in the Central Mediterranean Area. The core weather data are those from three observatories: Naples (40° 51′ N, 14° 15′ E, 150 m a.s.l.), Rome (41° 53′ N, 12° 28′ E, 100 m a.s.l.) and Montevergine (40° 56′ N, 14° 43′ E, 1280 m a.s.l.). A linear multivariate regression model (LMRM) was developed with candidate predictors (elevation, snowfall days and winter temperatures) for SDY reconstructions in the Benevento Valley (calibration site), whose homogenised SDY time series covers the period 1869–2018 (the longest in Southern Italy, extending back to 1832 thanks to documentary proxies but with missing values from 1911 to 1949). Three validation sites across peninsular Italy were considered: Vesuvius (40° 49′ N, 14° 24′ E, 605 m a.s.l.), Perugia (43° 05′ N, 12° 30′ E, 205 m a.s.l.) and Padua (45° 23′ N, 11° 51′ E, 15 m a.s.l.). The percent relative mean absolute error (%RMAE) for Benevento Valley was 20.2%, and though higher model errors were encountered at validation sites, they were in an acceptable range (32.6, 39.3 and 39.5% at Vesuvius, Perugia and Padua, respectively). Our SDY reconstruction in the Benevento Valley parallels, the pattern of water discharge occurred in the region during the same period, whose fluctuations result in changes of the pattern of snowfall days (i.e. decreasing snowfall days in recent times was accompanied by decreasing groundwater levels). This corroborates that the approach used to reconstruct SDY data takes dominant climate controlling factors of hydrological changes. We conclude that the LMRM, a statistically developed model, is physically meaningful and may be reasonably used for estimating SDY in peninsular Italy roughly down from the sub-Alpine range.  相似文献   

A polarized synchrotron template for cosmic microwave background polarization experiments based on WMAP data     

G. Bernardi  E. Carretti  R. Fabbri  C. Sbarra  S. Poppi  S. Cortiglioni  J. L. Jonas 《Monthly notices of the Royal Astronomical Society》2004,351(2):436-446

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Phylogeography of the bluespotted cornetfish,Fistularia commersonii: a predictor of bioinvasion success?          下载免费PDF全文

Alexis M. Jackson  Kimberly Tenggardjaja  Gerardo Perez  Ernesto Azzurro  Daniel Golani  Giacomo Bernardi 《Marine Ecology》2015,36(4):887-896

Biological invasions result in huge ecological and economic impacts; therefore, a great amount of effort is dedicated to predicting the potential success of newly established or candidate bioinvaders. Thus far, over 90 species of fish have entered the Mediterranean Sea via the Suez canal, the so‐called Lessepsian bioinvaders. The bluespotted cornetfish, Fistularia commersonii, is remarkable in its ability to disperse within the Mediterranean and has been dubbed ‘the Lessepsian sprinter’. In just a few years, starting in 2000, it expanded over the entire area, from the Suez Canal to Gibraltar. Theoretical predictions correlate the dispersal capabilities of an invader in its native range (using the population genetic metrics, F_st, as a proxy) with its dispersal capability in its invading area (continuous extent of spread, CES). Here, we estimated the population genetic characteristics of Indo‐Pacific native populations of F. commersonii in order to determine if this Lessepsian ‘sprinter’ fits the predictive model of dispersal. Indeed, we found that even in the case of such a very rapid range expansion, the predicted relationship between F_st and CES is fulfilled in F. commersonii.  相似文献