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91.
We investigate the dissociative recombination contribution to I(5577) and I(6300) of [OI] as a function of low energy cutoff for two measured solar proton spectra. The volume ionization rate profiles used in the calculation are obtained using a detailed atomic cross section approach in the continuous slowing down approximation. The ratio of the dissociative recombination contribution to the direct impact contribution for both the 5577 Å and 6300 Å [OI] emissions is found to be dependent upon the low energy cutoff. This ratio has a nominal value of ~2.0 for the 5577 Å [OI] emission and ~0.25 for the 6300 Å [OI] emission. The I(5577)/I(3914) and I(6300)/I(3914) ratios including the direct and dissociative recombination contributions are strongly dependent upon the low energy cutoff of the spectrum. We have also investigated F-layer enhancements resulting from the low energy spectrum component. For the Mizera et al. (1972) spectrum with a low energy cutoff of 12.4 keV, we find an NmF2 of ~4.5 × 103 electrons/cm3 or about 10 per cent of the ionization required to maintain the dip pole at a value of 5 × 104 electrons/cm3. Extension of the cutoff to 1 keV results in ~1 × 104 electrons/cm3, or about 20 per cent of the required maintenance ionization.  相似文献   
92.
Testing the theoretical notion that differences in entrepreneurial skill can enhance the viability of a poor location or detract from the qualities of a good location, this study reviews the historical experience of a number of retailing establishments operated by different firms at the same sites. The ultimate success of stores that had done poorly under previous management tends to confirm that a location is “good'’only so long as the retailer employs effective merchandising and operating policies.  相似文献   
93.
94.
Summary. The average geomagnetic pole position consistent with the magnetization of the Newer Volcanics of Victoria, which are for the most part of Pleistocene age, coincides with the present geographic pole just as do all pole determinations from Miocene and later rock formations from the Northern Hemisphere. During this time it appears that the Earth's magnetic field has approximated, on average, to that of a geocentric axial dipole and that the land masses concerned have maintained their present positions. In contrast, the pole determined from Lower Tertiary Volcanics of Victoria does not agree with the geographic pole nor with equivalent determinations from the Northern Hemisphere, suggesting that the relative positions of the continents may have been different in the past.  相似文献   
95.
96.
Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.  相似文献   
97.
Lake Vanda is a closed-basin, permanently ice-covered lake located in the Wright Valley of Antarctica. The lakes more important geochemical features include the fact that it is fed by a single glacial melt water stream for only 6–8weeks out of the year; that it has remained stratified for more than a millennium; and that, like other lakes in the region, it is remote from anthropogenic influence. These, together with the fact that it is among the least biologically productive lakes in the world, make it an ideal system for examining the transport, cycling and fate of trace metals in the aquatic environment. Like others before us, we view this lake as a natural geochemical laboratory, a flask in the desert. This paper presents the first set of closely spaced, vertical, profiles for dissolved and particulate Mn, Fe, Ni, Cu, Zn and Cd in the water column. Despite the absence of an outflow, metals in the fresh upper waters of the lake have extremely low concentrations, in the pico-molar to nano-molar range, and are partitioned largely into dissolved rather than particulate phases. Efficient metal scavenging by particles from these oxygen-rich waters is indicated. Significant increases in metal concentrations begin to appear at depth, between 57 and 60m, and these increases coincide with the onset of manganese oxide dissolution in oxic, but lower pH waters. Vertical profiles suggest that the entire suite of trace metals (Ni, Cu, Zn, and Cd) is being released from manganese oxide carrier phases. Thermodynamic analysis indicates that Mn3O4 (i.e., the mineral hausmannite) may be important in metal sequestration and recycling in the deeper waters of Lake Vanda. Manganese-reducing organisms reported by Bratina etal. (1998) are active in the zone of metal release and these could also contribute to the observed cycling.  相似文献   
98.
Isolated patches ofSpartina anglica (cordgrass) at two sites on a wave-exposed mid-intertidal flat of the 340 km2 Manukau Harbor (Auckland, New Zealand) have developed very differently since being planted in the mid-1970s. Although the two sites are only 0.5 km apart and at the same intertidal elevation,Spartina patches at the easternmost site (site 1) have as much as an order of magnitude higher biomass and accumulated sediment volume thanSpartina patches at site 2. A field experiment was conducted to characterize waves and associated sediment dynamics at each site, which might explain whySpartina patches at the two sites have developed so differently over the past 25 yr or so. Suspended sediments were measured and wave characteristics were inferred from subsurface pressure data measured for 5 wk at bothSpartina sites and at an intermediate location. Bed-orbital speeds and frictional wave-energy dissipation were consistently lower at the easternmost site with the largerSpartina patches. The west-to-east reduction in wave energy is due to the spatial arrangement of theSpartina sites relative to the predominant wind fetches. The wave-energy gradient is maintained by tidal-cycle variations in fetch and bed friction and results in a west-to-east reduction in sand suspension. Silt, which is largely resuspended under southwest winds, is redeposited in the low wave-energy conditions in and around the larger site 1Spartina patches. Shell accumulation bySpartina patches at site 1 occurs infrequently, during southwest winds >10 m s−1 and water depths >0.7 m, when waves are least attenuated by bed friction. Large between-site differences in the growth of and sediment accumulation by theSpartina patch are consistent with the observed wave-energy gradient. The resulting spatial patterns of silt, sand, and shell resuspension and deposition directly influence the rate of sediment accumulation bySpartina patches and the composition of accumulated sediment on this wave-exposed intertidal flat.  相似文献   
99.
The Sørfjord (Western Norway) has a long history of industry and pollution, and has been monitored for several decades. The environmental monitoring has comprised analyses of different contaminants in sea water, mussel, fish, seaweed and sediments. Measurements of polychlorinated biphenyls (PCBs) in blue mussels (Mytilus edulis) some 17 years ago indicated a local source. In 2001 severe concentrations were measured in blue mussels and further investigations disclosed the primary source of PCBs in the Sørfjord. In 2002, extreme PCB-concentrations were found in cod (Gadus morhua) from the same area. However, no induction of EROD activity was detected, indicating the limitations of this assay as marker for PCB contamination. A future scientific challenge will be to understand the specific mechanisms and effects of such PCB accumulation in fish.  相似文献   
100.
Indigenous Australians’ knowledge of weather and climate   总被引:1,自引:1,他引:0  
Although the last 200 years of colonisation has brought radical changes in economic and governance structures for thousands of Aboriginal and Torres Strait Islanders living in remote areas of northern Australia, many of these Indigenous people still rely upon, and live closely connected to, their natural environment. Over millennia, living ‘on country’, many of these communities have developed a sophisticated appreciation of their local ecosystems and the climatic patterns associated with the changes in them. Some of this knowledge is recorded in their oral history passed down through generations, documented in seasonal weather calendars in local languages and, to a limited degree, transcribed and translated into English. This knowledge is still highly valued by these communities today, as it is used to direct hunting, fishing and planting as well as to inform many seasonally dependant cultural events. In recent years, local observations have been recognised by non-Indigenous scientists as a vital source of environmental data where few historic records exist. Similar to the way that phenological observations in the UK and US provide baseline information on past climates, this paper suggests that Indigenous observations of seasonal change have the potential to fill gaps in climate data for tropical northern Australia, and could also serve to inform culturally appropriate adaptation strategies. One method of recording recent direct and indirect climate and weather observations for the Torres Strait Islands is documented in this paper to demonstrate the currency of local observations of climate and its variability. The paper concludes that a comprehensive, participatory programme to record Aboriginal and Torres Strait Islander knowledge of past climate patterns, and recent observations of change, would be timely and valuable for the communities themselves, as well as contributing to a greater understanding of regional climate change that would be useful for the wider Australian population.  相似文献   
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