Structural features of humic acids from a sedimentary sequence in the Guadiana estuary (Portugal–Spain border)     

O. Polvillo  J.A. González-Pérez  T. Boski  F.J. González-Vila 《Organic Geochemistry》2009,40(1):20-28

The structural characteristics of humic acids (HAs) from two different depths of a sedimentary sequence representing the last 13 kyr in the valley of Guadiana river estuary (SW Portugal/Spain border) have been approached using a combination of spectroscopic techniques, wet chemical degradation methods (sequential oxidation with sodium persulfate followed by KMnO₄, and oxidation with RuO₄) and analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) in the presence and absence of tetramethylammonium hydroxyde (TMAH). The aim was to obtain complementary information on the sources and alteration of the organic matter (OM) provided by a previous study on the vertical distribution of terrestrial and phytoplankton biogeochemical markers in the sequence. Both the FT-IR (Fourier transformed infrared) and ¹³C NMR (nuclear magnetic resonance) spectra showed a close similarity with the structural characteristics of the HA samples. NMR signals in the alkyl region (0–45 ppm) as well as FT-IR band patterns typical for methoxyl-substituted aromatic rings pointed to the presence of an important aliphatic domain, as well as to lignin-derived compounds. This finding was confirmed using analytical pyrolysis. In addition, the main TMAH thermochemolysis products were typical lignin-derived methoxyphenols with both guaicyl and syringyl nuclei. The detection of methoxyphenol units with three to six carbon atom (C₃–C₆) side chains suggests that lignin and possibly suberin were only partially degraded. Compounds arising from proteins and polysaccharides were also detected, although in lesser and varying amount. The major products from persulfate oxidation were series of n-alkanes (C₁₆–C₃₃ with clear odd/even predominance) and n-fatty acids, both saturated (C₁₀–C₂₆ with strong even/odd predominance) and unsaturated, which may arise from the above aliphatic biomacromolecules. The major products from permanganate oxidation of the persulfate residue were α,ω-diacids (C₆–C₁₁) originating from oxidation of the ether bonds linking the building blocks constituting the core of the HA structure. Aromatic compounds (phenols, methoxy-dimethoxybenzene carboxylic acid and benzene di-, tri-, tetra- and pentacarboxylic acids), most probably derived from the aromatic backbone of the HAs, that may also include lignin moieties as well as other polyphenols (flavonoids and tannins) were also detected. The RuO₄ oxidation also released series of n-alkanes (C₁₆–C₃₃), linear saturated fatty acids (C₁₀–C₂₈) and α,ω-diacids (C₇–C₂₅), as well as traces of benzene polycarboxylic acids. Regarding the usefulness of the various techniques used, they provide complementary information. Indeed, spectroscopic techniques and analytical pyrolysis provide information on the backbone of the HAs, and on their origin, whereas the oxidative degradations provide different information on the structural features of the HA, particularly the nature of the linking between the building blocks. In general, the data support the idea that the HAs still contain information about the signature of aliphatic and aromatic biomacromolecules contributing to the OM deposited. The presence of lignin-derived residues suggests a large input from terrestrial carbon throughout the core.  相似文献   

Regional stratigraphy and distribution of epigenetic stratabound celestine, fluorite, barite and Pb–Zn deposits in the MVT province of northeastern Mexico     

Francisco González-Sánchez  Antoni Camprubí  Eduardo González-Partida  Rafael Puente-Solís  Carles Canet  Elena Centeno-García  Viorel Atudorei 《Mineralium Deposita》2009,44(3):343-361

Northeastern Mexico hosts numerous epigenetic stratabound carbonate-hosted low-temperature hydrothermal deposits of celestine, fluorite, barite and zinc-lead, which formed by replacement of Mesozoic evaporites or carbonate rocks. Such deposits can be permissively catalogued as Mississippi Valley-type (MVT) deposits. The deposits studied in the state of Coahuila are associated with granitic and metasedimentary basement highs (horsts) marginal or central to the Mesozoic Sabinas Basin. These horsts controlled the stratigraphy of the Mesozoic basins and subsequently influenced the Laramide structural pattern. The Sabinas Basin consists of ~6,000-m-thick Jurassic to Cretaceous siliciclastic, carbonate and evaporitic series. The MVT deposits are mostly in Barremian and in Aptian-Albian to Cenomanian formations and likely formed from basinal brines that were mobilized during the Laramide orogeny, although earlier diagenetic replacement of evaporite layers (barite and celestine deposits) and lining of paleokarstic cavities in reef carbonates (Zn–Pb deposits) is observed. Fluid inclusion microthermometry and isotopic studies suggest ore formation due to mixing of basinal brines and meteoric water. Homogenization temperatures of fluid inclusions range from 45°C to 210°C; salinities range from 0 to 26 wt.% NaCl equiv., and some inclusions contain hydrocarbons or bitumen. Sulfur isotope data suggest that most of the sulfur in barite and celestine is derived from Barremian to Cenomanian evaporites. Regional geology and a compilation of metallogenic features define the new MVT province of northeastern Mexico, which comprises most of the state of Coahuila and portions of the neighboring states of Nuevo León, Durango and, perhaps extends into Zacatecas and southern Texas. This province exhibits a regional metal zonation, with celestine deposits to the south, fluorite deposits to the north and barite and Zn–Pb deposits mostly in the central part.  相似文献   

A potentially new type of nonchondritic interplanetary dust particle with hematite,organic carbon,amorphous Na,Ca‐aluminosilicate,and FeO‐spheres     

Guillermo M. MUÑOZ CARO  Frans J. M. RIETMEIJER  Virginia SOUZA‐EGIPSY  Maria Pilar VALLES‐GONZÁLEZ 《Meteoritics & planetary science》2012,47(2):248-261

Abstract– We used a combination of different analytical techniques to study particle W7190‐D12 using microinfrared spectroscopy, micro‐Raman spectroscopy, and field emission scanning electron microscopy (FESEM) energy dispersive X‐ray spectroscopy (EDS). The particle consists mainly of hematite (α‐Fe₂O₃) with considerable variations in structural disorder. It further contains amorphous (Na,K)‐bearing Ca,Al‐silicate and organic carbon. Iron‐bearing spherules (<150 nm in diameter) cover the surface of this particle. At local sites of structural disorder at the hematite surface, the hematite spheres were reduced to FeO in the presence of organic carbons forming FeO‐spheres. However, metallic Fe spheres cannot be excluded based on the available data. To the best of our knowledge, this particle is the first detection of such spherules at the surface of a stratospheric dust particle. Although there is no definitive evidence for an extraterrestrial origin of particle W7190‐D12, we suggest that it could be an IDP that had moved away from the asteroid‐forming region of the early solar system into the outer solar system of the accreting Kuiper Belt objects. After it was released from a Jupiter family comet, this particle became part of the zodiacal cloud. Atmospheric entry flash‐heating caused (1) the formation of microenvironments of reduced iron oxide when indigenous carbon materials reacted with hematite covering its surface resulting in the formation of FeO‐spheres and (2) Na‐loss from Na,Al‐plagioclase. The particle of this study, and other similar particles on this collector, may represent a potentially new type of nonchondritic IDPs associated with Jupiter family comets, although an origin in the asteroid belt cannot be ignored.  相似文献   

GPS differential code biases determination: methodology and analysis   总被引：1，自引：1，他引：0  

Jaume Sanz  J. Miguel Juan  Adrià Rovira-Garcia  Guillermo González-Casado 《GPS Solutions》2017,21(4):1549-1561

  相似文献   

Mhd Leaky Waves in a Layered Plasma: II Mechanisms of Leakage     

A.G. González  J. Gratton  S. Farina 《Astrophysics and Space Science》1997,256(1-2):297-301

The application of Fourier analysis to study leaky waves has the advantage of simplicity, but it is not clear why the complex roots of the dispersion relations represent leaky waves, nor how the leakage occurs. We investigate the different kinds of leakage that can occur in a three layer plasma, and to which Fourier pseudomodes they are associated. We find four basic mechanisms, called surface mode ..., single interface ..., trapped wave ... and lost insulation leakage. These mechanisms appear in pure form only near certain limiting cases, in which the parameters of the problem take some special values. As soon as the parameters depart significantly from the limiting values, the behavior of the leaky wave complicates and mixtures of the mechanisms occur, in varying amounts. In consequence different points of the same complex branch of the spectrum may correspond to different mechanisms. All the complex branches of the spectrum correspond to leaky waves, but in general it is not possible to classify them according to type of leakage, except close to a limiting case. Since in a three layer configuration there are many of these, the spectrum of leaky waves is very complicated.  相似文献   

Impacts of climate change on building energy demands in the intra-Americas region     

Moises?E.?AngelesEmail authorView author&#;s OrcID profile  Jorge?E.?González  Nazario?Ramírez 《Theoretical and Applied Climatology》2018,133(1-2):59-72

It was recently reported a regional warming in the intra-Americas region where sea surface temperature exhibited increases exceeding 0.15 °C/decade and an accelerated air temperature rise that could impact building energy demands per capita (EDC). Reanalysis data is used herein to quantify the impacts of these warming trends on EDC. Results of the analysis depict a Southern Greater Antilles and inland South America with a positive annual EDC rate of 1–5 kWh per year. The Intergovernmental Panel on Climate Change (IPCC) Representative Concentration Pathways (RCP) 2.6 and 4.5 scenarios were selected to analyze energy demand changes in the twenty-first century. A multi-model ensemble forecasts an EDC increase of 9.6 and 23 kWh/month in the RCP2.6 and RCP4.5 at the end of the twenty-first century, which may increase average building cooling loads in the region by 7.57 GW (RCP2.6) and 8.15 GW (RCP4.5), respectively. Furthermore, 4 of 9 (RCP2.6) and 7 of 9 (RCP4.5) of the major countries in this region have EDCs ranging between 1887 and 2252 kWh/year at the end of this century. Therefore, increased energy production and improved energy infrastructure will be required to maintain ideal indoor building conditions at the end of the twenty-first century in these tropical coastal regions as consequence of a warmer climate.  相似文献   

Recent Vertical Deformation in Mexicali Valley and its Relationship with Tectonics, Seismicity, and the Exploitation of the Cerro Prieto Geothermal Field, Mexico   总被引：1，自引：0，他引：1  

E. Glowacka  J. González  H. Fabriol 《Pure and Applied Geophysics》1999,156(4):591-614

—The interpretation of the results of regional and local leveling which began in 1977 in the Mexicali Valley and the local short profile precision leveling which started in 1994 are discussed. The relation of vertical deformations around the Cerro Prieto Geothermal Field (CPGF) and along the Imperial fault, with local tectonics and seismicity in the Mexicali Valley, is reviewed. Also the relation between vertical deformation and fluid operation in the CPGF is analyzed. The subsidence observed in the field seems to be induced by fluid extraction. The way in which fluid production influences surface changes along the Imperial fault is not clear. The possibility that seismicity is triggering subsidence in the area and vertical movement on the Imperial fault is discussed.  相似文献   

Structural and kinematic analysis of the Corredoiras detachment: evidence for early Variscan synconvergent extension in the Ordenes Complex, NW Spain   总被引：1，自引：1，他引：0  

F. Díaz García  J. R. Martínez Catalán  R. Arenas  P. González Cuadra 《International Journal of Earth Sciences》1999,88(2):337-351

 An important detachment is described in the allochthonous Ordenes Complex, in the NW Iberian Massif, and its meaning is related to the kinematics of contemporaneous convergent structures. The Corredoiras Detachment (CD) separates a hangingwall unit, characterised by a medium-pressure metamorphic gradient, from a footwall high-pressure and high-temperature unit and an underlying ophiolitic unit. An associated ductile shear zone, nearly 2000 m thick, developed in the lower part of the hangingwall unit, where the Corredoiras Orthogneiss, a Lower Ordovician metagranite, was progressively transformed into augengneisses, mylonitic and ultramylonitic gneisses. The attitude of the stretching and mineral lineation in the mylonites varies due to late refolding at map scale, but the sense of movement can be estimated, being roughly top to the SE. According to crosscutting relationships, the CD developed subsequent to the thrusting of the high-pressure/high-temperature unit onto the ophiolitic unit, and prior to younger extensional detachments, upright folding and strike-slip tectonics. The geometric relationships of the CD with the previous structures in the footwall unit, the subtractive character of the metamorphic gap between its hangingwall and footwall, and the available isotopic data suggest that the CD is an early Variscan, ductile extensional detachment, the movement of which was roughly simultaneous with the onset of thrusting of the allochthonous complexes over their relative autochthon. Received: 17 November 1998 / Accepted: 4 April 1999  相似文献   

Origin of peraluminous granites and granodiorites, Iberian massif, Spain: an experimental test of granite petrogenesis   总被引：27，自引：0，他引：27  

Antonio Castro  Alberto E. Patiño Douce  L. Guillermo Corretgé  Jesús D. de la Rosa  Mohammed El-Biad  Hassan El-Hmidi 《Contributions to Mineralogy and Petrology》1999,135(2-3):255-276

The discrimination between potential source materials involved in the genesis of Iberian granites and granodiorites, as well as the role of mantle-crust interactions, are examined using constraints imposed by melting experiments, melting-assimilation experiments and Sr-Nd isotope systematics. The Sr-Nd isotope relationships indicate the existence of different genetic trends in which juvenile mantle materials are involved by different mechanisms: (1) a source trend, traced by a particular evolution of the pre-Hercynian basement and indicating mantle participation at the time of sedimentation; (2) a set of magmatic trends traced by gabbro-tonalite-enclave-granodiorite associations, implying the incorporation of new mantle material at the time of granite generation. These relationships strongly support a pure crustal origin for the peraluminous leucogranites, derived from partial melting of crustal protoliths, and a hybrid origin for the peraluminous granodiorites. These granodiorites are the most abundant granitic rocks of the Central Iberian zone (CIZ) of the Iberian massif, implying that processes of hybridisation by assimilation and/or magma mixing played an important role in granitoid production during the Hercynian orogeny. These hypotheses have been tested by means of melting and assimilation experiments. Melting experiments in the range 800–900 °C and at pressures of 3, 6, 10 and 15 kbar indicate that: (1) several potential source materials such as Bt-Ms gneisses and metagreywackes are suitable for the production of peraluminous leucogranite melts; (2) the melt compositions are always leucogranitic, regardless of pressure; (3) pressure exerts a strong influence on the fertility of the source: experiments at 3 kbar produce more than 20 vol% of melt, compared with less than 5 vol% of melt produced at 10 and 15 kbar and at the same temperature. The melting-assimilation experiments carried out at 1000 °C and 4, 7 and 10 kbar and using a proportion of 50% gabbro and 50% gneiss give high melt proportions (more than 50 vol.%) and noritic residues. These melts have the composition of leucogranodiorites, and overlap with part of the compositional range of peraluminous granodiorites of the Iberian massif. The generation of more mafic granodiorites may be explained by the incorporation of some residual orthopyroxene to the granodiorite magmas. The low solubility of Fe + Mg prevents the generation of granodiorite melts with more than 3 wt% of MgO + FeO at all crustal pressures. The large volumes of peraluminous, hybrid granodiorites, produced by assimilation of crustal rocks by mantle magmas, imply that an important episode of crustal growth took place during the Late-Palaeozoic Hercynian orogeny in the Iberian massif. Received: 30 June 1998 / Accepted: 27 November 1998  相似文献   

SlugIn 1.0: A Free Tool for Automated Slug Test Analysis          下载免费PDF全文

Sergio Martos‐Rosillo  Carolina Guardiola‐Albert  Alberto Padilla Benítez  Joaquín Delgado Pastor  Antonio Azcón González  Juan José Durán Valsero 《Ground water》2018,56(3):362-365

The correct characterization of aquifer parameters is essential for water‐supply and water‐quality investigations. Slug tests are widely used for these purposes. While free software is available to interpret slug tests, some codes are not user‐friendly, or do not include a wide range of methods to interpret the results, or do not include automatic, inverse solutions to the test data. The private sector has also generated several good programs to interpret slug test data, but they are not free of charge. The computer program SlugIn 1.0 is available online for free download, and is demonstrated to aid in the analysis of slug tests to estimate hydraulic parameters. The program provides an easy‐to‐use Graphical User Interface. SlugIn 1.0 incorporates automated parameter estimation and facilitates the visualization of several interpretations of the same test. It incorporates solutions for confined and unconfined aquifers, partially penetrating wells, skin effects, shape factor, anisotropy, high hydraulic conductivity formations and the Mace test for large‐diameter wells. It is available in English and Spanish and can be downloaded from the web site of the Geological Survey of Spain. Two field examples are presented to illustrate how the software operates.  相似文献