Small angle neutron scattering by opals     

H. Graetsch  K. Ibel 《Physics and Chemistry of Minerals》1997,24(2):102-108

Micro- and non-crystalline opals, chalcedony and flint show diffuse small angle neutron scattering (SANS). Precious opals give rise to two additional intensity maxima at very small scattering angles which are due to Bragg reflections from the closest packed non-crystalline silica spheres. A small angle texture diagram reveals that the closest packing is faulty. Synthetic non-crystalline opals yield much less intense small angle scattering due to lower contrast between silica spheres and interstitial cement or particles; in this case intensity maxima were not observed. The outer part of the scattering curves of opal-CT and microcrystalline quartz deviates from Porod's law. The specific surface of natural non-crystalline opals ranges from 0.006 to 0.018 nm^–1. In microcrystalline opals, the specific surface is about 10 times larger than in non-crystalline opals.  相似文献   

Examples of clustering around high redshift radio-galaxies     

J. M. Deltorn  O. Le Fèvre 《Astrophysics》1995,38(4):379-381

Published in Astrofizika, Vol. 38, No. 4, pp. 677–680, October–December, 1995.  相似文献   

Comparison of results from several AOGCMs for global and regional sea-level change 1900–2100     

J. M. Gregory  J. A. Church  G. J. Boer  K. W. Dixon  G. M. Flato  D. R. Jackett  J. A. Lowe  S. P. O'Farrell  E. Roeckner  G. L. Russell  R. J. Stouffer  M. Winton 《Climate Dynamics》2001,18(3-4):225-240

 Sea-level rise is an important aspect of climate change because of its impact on society and ecosystems. Here we present an intercomparison of results from ten coupled atmosphere-ocean general circulation models (AOGCMs) for sea-level changes simulated for the twentieth century and projected to occur during the twenty first century in experiments following scenario IS92a for greenhouse gases and sulphate aerosols. The model results suggest that the rate of sea-level rise due to thermal expansion of sea water has increased during the twentieth century, but the small set of tide gauges with long records might not be adequate to detect this acceleration. The rate of sea-level rise due to thermal expansion continues to increase throughout the twenty first century, and the projected total is consequently larger than in the twentieth century; for 1990–2090 it amounts to 0.20–0.37 m. This wide range results from systematic uncertainty in modelling of climate change and of heat uptake by the ocean. The AOGCMs agree that sea-level rise is expected to be geographically non-uniform, with some regions experiencing as much as twice the global average, and others practically zero, but they do not agree about the geographical pattern. The lack of agreement indicates that we cannot currently have confidence in projections of local sea-level changes, and reveals a need for detailed analysis and intercomparison in order to understand and reduce the disagreements. Received: 1 September 2000 / Accepted: 20 April 2001  相似文献   

The re-analysis of the ROSAT data of Nova Mus 1983 using white dwarf atmosphere emission models     

&#;. Balman  J. Krautter 《Monthly notices of the Royal Astronomical Society》2001,326(4):1441-1447

The analyses of X-ray emission from classical novae during the outburst stage have shown that the soft X-ray emission below 1 keV, which is thought to originate from the photosphere of the white dwarf, is inconsistent with the simple blackbody model of emission. Thus, ROSAT Position Sensitive Proportional Counter (PSPC) archival data of the classical Nova Mus 1983 (GQ Mus) have been re-analysed in order to understand the spectral development in the X-ray wavelengths during the outburst stage. The X-ray spectra are fitted with the hot white dwarf (WD) atmosphere emission models developed for the remnants of classical novae near the Eddington luminosity. The post-outburst X-ray spectra of the remnant white dwarf are examined in the context of evolution on the Hertzsprung–Russell diagram using C–O enhanced atmosphere models. The data obtained in 1991 August (during the ROSAT All Sky Survey) indicate that the effective temperature is         . The 1992 February data show that the white dwarf had reached an effective temperature in the range         with an unabsorbed X-ray flux (i.e. ∼ bolometric flux) between     and     . We show that the H burning at the surface of the WD had most likely ceased at the time of the X-ray observations. Only the 1991 August data show evidence for ongoing H burning.  相似文献   

The build-up of haloes within Press–Schechter theory     

Will J. Percival 《Monthly notices of the Royal Astronomical Society》2001,327(4):1313-1322

Modelling the build-up of haloes is important for linking the formation of galaxies with cosmological models. A simple model of halo growth is provided by Press–Schechter (PS) theory, where the initial field of density fluctuations is smoothed using spherically symmetric filters centred on a given position to obtain information about the likelihood of later collapse on varying scales. In this paper the predicted halo mass growth is compared for three filter shapes: Gaussian, top-hat and sharp k -space. Preliminary work is also presented analysing the build-up of haloes within numerical simulations using a friends-of-friends group finder. The best-fit to the simulation mass function was obtained using PS theory with a top-hat filter. By comparing both the backwards conditional mass function, which gives the distribution of halo progenitors, and the distribution of halo mergers in time, the build-up of haloes in the simulations is shown to be better fitted by PS theory with a sharp k -space filter. This strengthens previous work, which also found the build-up of haloes in simulations to be well matched to PS theory with a sharp k -space filter by providing a direct comparison of different filters and by extending the statistical tools used to analyse halo mass growth. The usefulness of this work is illustrated by showing that the cosmological evolution in the proportion of haloes that have undergone recent merger is predicted to be independent of mass and power spectrum and to only depend upon cosmology. Recent results from observations of field galaxies are shown to match the evolution expected, but are not sufficiently accurate to distinguish usefully between cosmological parameters.  相似文献   

The importance of new rate coefficients for deuterium fractionation reactions in interstellar chemistry     

Helen Roberts  Eric Herbst  T. J. Millar 《Monthly notices of the Royal Astronomical Society》2002,336(1):283-290

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Grain boundary diffusion in enstatite     

D. K. Fisler  S. J. Mackwell  S. Petsch 《Physics and Chemistry of Minerals》1997,24(4):264-273

We have investigated grain boundary diffusion rates in enstatite by heating single crystals of quartz packed in powdered San Carlos olivine (Mg_0.90Fe_0.10)₂SiO₄ at controlled oxygen fugacities in the range 10^?5.7 to 10^?8.7?atm and temperatures from 1350° to 1450?°C for times from 5 to 100?h at 1?atm total pressure. Following the experiments, the thickness of the coherent polycrystalline reaction rim of pyroxene that had formed between the quartz and olivine was measured using backscatter scanning imaging in the electron microprobe. Quantitative microprobe analysis indicated that the composition of this reaction phase is (Mg_0.92Fe_0.08)₂Si₂O₆. The rate of growth of the pyroxene increases with increasing temperature, is independent of the oxygen fugacity, and is consistent with a parabolic rate law, indicating that the growth rate is controlled by ionic diffusion through the pyroxene rim. Microstructural observations and platinum marker experiments suggest that the reaction phase is formed at the olivine-pyroxene interface, and is therefore controlled by the diffusion of silicon and oxygen. The parabolic rate constants determined from the experiments were analyzed in terms of the oxide activity gradient across the rim to yield mean effective diffusivities for the rate-limiting ionic species, assuming bulk transport through the pyroxene layer. These effective diffusivities are faster than the lattice diffusivities for the slowest species (silicon) calculated from creep experiments, but slower than measured lattice diffusivities for oxygen in enstatite. Thus, silicon grain boundary diffusion is most likely to be the rate-limiting process in the growth of the pyroxene rims. Also, as oxygen transport through the pyroxene rims must be faster than silicon transport, diffusion of oxygen along the grain boundaries must be faster than through the lattice. The grain boundary diffusivity for silicon in orthopyroxenite is then given by D¯gbSiδ=(3.3±3.0)×10^?9f0.0O₂e^?400±65/RT?m³s^?1, where the activation energy for diffusion is in kJ/mol, and δ is the grain boundary width in m. Calculated growth rates for enstatite under these conditions are significantly slower than predicted by an extrapolation from similar experiments performed at 1000?°C under high pressure (hydrous) conditions by Yund and Tullis (1992), perhaps due to water-enhancement of diffusion in their experiments.  相似文献   

Solid bitumens: an assessment of their characteristics, genesis, and role in geological processes     

David J. Mossman  Bartholomew Nagy † 《地学学报》1996,8(2):114-128

Familiar since antiquity, and subject in contemporary times to various characterization schemes, the exact nature of solid bitumen is not yet fully known. Bitumens have ‘random polymer-like’ molecular structures, are mobile as highly viscous fluids or were once fluids but have since turned into solids. Solid bitumens consist mainly of large moieties, of polyclyclic aromatic hydrocarbons, occasionally with finely admixed, fine-grained cryptocrystalline graphite. Solid bitumens are distinguished from kerogen, which is the syngenetic and generally finely dispersed particulate organic matter in sedimentary rock that virtually does not migrate following its deposition. Occurrences of solid bitumens are relevant to petroleum exploration as well as the search for, and evaluation of, a variety of metallic mineral deposits. Genesis of bitumen is in many cases linked to the thermal and hydrothermal history of organic matter in sedimentary rock. Apparently bitumen, or more specifically organic acids generated along with bitumen during diagenesis, may alter porosity of reservoir rocks or otherwise prepare the ground for ore deposition. Bitumen is also relatively sensitive to alteration processes, some of which, such as oxidative weathering, water leaching, biodegradation (contact) metamorphism and ionizing radiation may likewise affect its nature. Elemental composition of bitumen commonly reflects the nature of mineral deposits. Is is possible that in petroleum exploration, trace metal abundances of bitumen may eventually allow prediction of crude oil types and volumes anticipated from a given source rock? Beside transition elements, notably Ni and V, highly anomalous concentrations of U, Pt and Au occur in some solid bitumens. During the generation of petroleum from kerogen, the trend in δ¹³C is toward lighter values. The opposite seems to occur when liquid petroleum is subjected to thermal cracking (and /or related processes) yielding solid bitumen enriched in ¹³C, and isotopically light methane. In fact, except for deasphalting and possibly some irradiation processes, the result of thermal cracking, oxidation, water leaching, inspissation (drying) and bacterial degradation of crude oil is that lower molecular weight hydrocarbons are removed leaving bitumen residues enriched in aromatic hydrocarbons, heteroatomic compounds (NSO) and ¹³C. Such phenomena are relevant to bitumen paragenesis in petroleum reservoir rocks, to certain Phanerozoic occurrences of multiple generations of bitumens, and to bitumens in mineral deposits.  相似文献   

Historical Changes in the Flood Hazard at Khartoum, Sudan: Lessons and Warnings for the Future   总被引：1，自引：0，他引：1  

H.R.J. Davies  & R.P.D. Walsh 《Singapore journal of tropical geography》1997,18(2):123-140

The 1988 floods at Khartoum were frequently described as "unprecedented". However, an examination of evidence for floods caused by the Nile and rain storms during the nineteenth and twentieth centuries leads to the conclusion that neither the Nile flood nor the rain storms nor their coincidence in one season were unprecedented and that similar situations will recur.We argue that most problems were created by complacency, lack of planning and mismanagement. We conclude with some simple suggestions for flood amelioration in the future and warn that complacency is the single most important phenomenon likely to recur to the detriment of Greater Khartoum in the future.  相似文献   

Rift-related Jurassic basaltic phreatomagmatic volcanism in the central Transantarctic Mountains: precursory stage to flood-basalt effusion     

Richard E. Hanson  David H. Elliot 《Bulletin of Volcanology》1996,58(5):327-347

 The Middle Jurassic Kirkpatrick flood basalts and comagmatic Ferrar intrusions in the Transantarctic Mountains represent a major pulse of tholeiitic magmatism related to early stages in the breakup of Gondwana. A record of the volcano-tectonic events leading to formation of this continental flood-basalt province is provided by strata underlying and only slightly predating the Kirkpatrick lavas. In the central Transantarctic Mountains, the lavas rest on widespread (≥7500 km²) tholeiitic pyroclastic deposits of the Prebble Formation. The Prebble Formation is dominated by lahar deposits and is an unusual example of a regionally developed basaltic lahar field. Related, partly fault-controlled pyroclastic intrusions cut underlying strata, and vents are represented by the preserved flanks of two small tephra cones associated with a volcanic neck. Lahar and air-fall deposits typically contain 50–60% accidental lithic fragments and sand grains derived from underlying Triassic – Lower Jurassic strata in the upper part of the Beacon Supergroup. Juvenile basaltic ash and fine lapilli consist of nonvesicular to scoriaceous tachylite, sideromelane, and palagonite, and have characteristics indicating derivation from hydrovolcanic eruptions. The abundance of accidental debris from underlying Beacon strata points to explosive phreatomagmatic interaction of basaltic magma with wet sediment and groundwater, which appears to have occurred in particular where rising magma intersected upper Beacon sand aquifers. Composite clasts in the lahar deposits exhibit complex peperitic textures formed during fine-scale intermixing of basaltic magma with wet sand and record steps in subsurface fuel-coolant interactions leading to explosive eruption. The widespread, sustained phreatomagmatic activity is inferred to have occurred in a groundwater-rich topographic basin linked to an evolving Jurassic rift zone in the Transantarctic Mountains. Coeval basaltic phreatomagmatic deposits of the Mawson and Exposure Hill Formations, which underlie exposures of the Kirkpatrick Basalt up to 1500 km to the north along strike in Victoria Land, appear to represent other parts of a regional, extension-related Middle Jurassic phreatomagmatic province which developed immediately prior to rapid outpouring of the flood basalts. This is consistent with models which assign an important role to lithospheric stretching in the generation of flood-basalt provinces. Received: 28 August 1995 / Accepted: 18 April 1996  相似文献