A surface complexation model for cadmium and lead adsorption onto diatom surface     

A. Glabert  O.S. Pokrovsky  C. Reguant  J. Schott  A. Boudou 《Journal of Geochemical Exploration》2006,88(1-3):110

This work is devoted to the physico-chemical study of cadmium and lead interaction with diatom–water interfaces for two marine planktonic (Thalassiosira weissflogii = TW, Skeletonema costatum = SC) and two freshwater periphytic species (Achnanthidium minutissimum = AMIN, Navicula minima = NMIN) by combining adsorption measurements with surface complexation modeling. Reversible adsorption experiments were performed at 20 °C after 3 h of exposure as a function of pH, metal concentration in solution, and ionic strength. While the shape of pH-dependent adsorption edge is similar among all four diatom species, the constant-pH adsorption isotherm and maximal binding capacities differ. These observations allowed us to construct a surface complexation model for cadmium and lead binding by diatom surfaces that postulates the constant capacitance of the electric double layer and considers Cd and Pb complexation with mainly carboxylic and, partially, silanol groups. Parameters of this model are in agreement with previous acid–base titration results and allow quantitative reproduction of all adsorption experiments.  相似文献   

Holocene record of productivity in the NW Iberian continental shelf     

V. Alves Martins  C. Patinha  E. Ferreira da Silva  J.-M. Jouanneau  O. Weber  F. Rocha   《Journal of Geochemical Exploration》2006,88(1-3):408

A multiproxy approach (textural characteristics, heavy metal concentrations and benthic foraminifera data) was adopted to study the OMEX core KSGX 40, collected at the Galicia Mud Deposit (NW Iberian outer continental shelf) and recording the last ca. 4.8 ka cal BP. Geochemical profiles of Fe, Mn, Zn, Co, Cr, Cu, Ni, Pb, Al and Ca show significant temporal variations. Benthic foraminifera productivity proxy suggests that the recorded muddy events were contemporaneous of a higher C_org flux to the marine benthic environment. The higher flux of organic matter, following a long-term intensification of the upwelling and coinciding with a finer sedimentation, led to depressed levels of oxygen beneath the water-sediments interface and to early diagenetic processes of several redox-sensitive elements.  相似文献   

Developments in the characterisation of waste materials for environmental impact assessment purposes     

H.A. van der Sloot  J.C.L. Meeussen  A. van Zomeren  D.S. Kosson 《Journal of Geochemical Exploration》2006,88(1-3):72

The characterisation of waste is entering a new phase with the latest developments of characterisation leaching tests and associated modelling capabilities. The currently applied too simple testing approaches lead to poor choices in waste management. With the increased insight in release controlling processes chemical speciation aspects can be addressed even in the most complex and heterogeneous waste materials. From a composition perspective materials may be highly variable, but often materials are far more consistent in their leaching behaviour. This aspect should be exploited more extensively as it holds the key to treat waste materials in such a way that long term solutions are achieved rather than reaching temporary gains.  相似文献   

Metamafic rocks of the Tana Belt, Kola Peninsula: Isotopic age and PT conditions     

L. L. Perchuk  J. D. Kramers  V. O. Yapaskurt  A. V. Krotov 《Doklady Earth Sciences》2006,408(1):623-626

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The bimodal rift-related Juscelândia volcanosedimentary sequence in central Brazil: Mesoproterozoic extension and Neoproterozoic metamorphism     

Renato Moraes  Reinhardt A. Fuck  Mrcio Martins Pimentel  Simone M.C.L. Gioia  Maria H.B.M. de Hollanda  Richard Armstrong 《Journal of South American Earth Sciences》2006,20(4):287-301

The Barro Alto Complex and Juscelândia volcanosedimentary sequence are exposed in the central part of the Neoproterozoic Brasília belt of central Brazil. The former is a large (approximately 150 km long), boomerang-shaped, mafic-ultramafic, layered complex formed by two different intrusions metamorphosed under granulite facies. These rocks are tectonically overlain by rocks of the Juscelândia volcanosedimentary sequence, represented mainly by biotite-gneiss and amphibolite, or amphibolite facies metamorphic equivalents of rhyolite and basalt, respectively. New SIMS U–Pb zircon data and Sm–Nd isochron data presented herein help clarify the igneous and metamorphic evolution of the Juscelândia volcanosedimentary sequence, as well as its relationship with the Barro Alto Complex. Zircon grains from two biotite gneisses were analyzed by SIMS (SHRIMP) and indicate Mesoproterozoic dates, approximately 1.28 Ga, interpreted as the time of bimodal volcanism in a tectonic setting transitional between a continental rift and an ocean basin. Metamorphism is constrained by Sm–Nd garnet-whole-rock isochrons for garnet amphibolite and pelitic schists of the Juscelândia sequence, as well as for clinopyroxene-garnet amphibolite and garnet granulite of the Barro Alto Complex, which give ages between 0.74 and 0.76 Ga, in agreement with SIMS dates for metamorphic zircon rims. These new data are significant, because they establish that a single metamorphic event affected both the Barro Alto Complex and the Juscelândia sequence. Based on these new data, we present a modified tectonic model for the Brasília belt.  相似文献   

The seismic hazard assessment of the Dead Sea rift, Jordan   总被引：1，自引：0，他引：1  

Abdallah S. Al-Zoubi  Z.S.H. Abu-Hamatteh  Amrat Abdealkaderer 《Journal of African Earth Sciences》2006,45(4-5):489-501

The Dead Sea fault system and its branching faults represent one of the most tectonically active regions in the Middle East. The aim of this study is to highlight the degree of hazards related to the earthquake activities associated with the Dead Sea rift, in terms of speculating the possible future earthquakes. The present investigation mainly is based on available data and vertical crustal modeling of Jordan and the Dead Sea model for the Dead Sea basin with particular emphasis of the recent earthquake activities, which occurred on December 31st, 2003 (Mc = 3.7), February 11th, 2004 (strongest Mc = 4.9 R), and March 15th, 2004 (Mc = 4). The present research examines the location of the strong events and correlates them with the various tectonic elements in the area. The source mechanism of the main shock and the aftershock events is also examined. The analyses were based on the available short period seismogram data, which was recorded at the Natural Resources Authority of Jordan, Seismological Observatory. The seismic energy appears to have migrated from the south to the north during the period from December 31st up to March 12th, where the released seismic energy showed a migration character to the southern block of the eastern side of the Dead Sea, which led the seismic event to occur on March 15th.  相似文献   

Simulation of the Holocene climate evolution in Northern Africa: The termination of the African Humid Period   总被引：2，自引：0，他引：2  

H. Renssen  V. Brovkin  T. Fichefet  H. Goosse 《Quaternary International》2006,150(1):95

The Holocene climate evolution in Northern Africa is studied in a 9000-yr-long transient simulation with a coupled atmosphere–ocean–vegetation model forced by changes in insolation and atmospheric greenhouse gas concentrations. The model simulates in the monsoonal domains a significant decrease in precipitation under influence of the orbitally forced reduction in summer insolation. In the Western Sahara region, the simulated mid-Holocene transition from humid to arid conditions (the termination of the African Humid Period) is highly non-linear with the occurrence of centennial-scale climate fluctuations due to the biogeophysical feedback between precipitation and vegetation cover. This result is in agreement with proxy data from the Western Sahara region. The other monsoonal regions experience a more gradual climate evolution that linearly follows the insolation forcing, which appears in disagreement with available lake level records.  相似文献   

Petrofacies, provenance and diagenesis of the dhosa sandstone member (Chari Formation) at Ler, Kachchh sub-basin, Western India     

A.H.M. Ahmad  G.M. Bhat   《Journal of Asian Earth Sciences》2006,27(6):857-872

The sandstones of the Dhosa Sandstone Member of Late Callovian and Early Oxfordian age exposed at Ler have been analyzed for their petrofacies, provenance, tectonic setting and diagenetic history. These sandstones are fine to medium grained and poorly- to well sorted. The constituent mineral grains are subangular to subrounded. These sandstones were derived from a mixed provenance including granites, granite–gneisses, low- and high-grade metamorphic and some basic rocks of the Aravalli Range and Nagarparkar Massif. The petrofacies analysis reveals that these sandstones belong to the continental block-, recycled orogen- and rifted continental margin tectonic regime.The imprints of early and deep burial diagenesis of these sandstones include different stages of compaction, cementation, change in crystal boundaries, cement–cement boundaries, chertification and neomorphism. The sequence of cementation includes precipitation of calcite and its subsequent replacement by Fe calcite and silica cements. The typical intermediate burial (2–3 km depth) diagenetic signatures of these sandstones are reflected in the formation of suture and straight-line boundaries, and triple junctions with straight-line boundaries. The depositional environment, relatively low-energy environment that was below storm wave base but subjected to gentle currents, of the Dhosa Sandstone Member controlled the early diagenesis, which in turn influenced the burial diagenesis of these sandstones.  相似文献   

First record of a Cretaceous cheilostome bryozoan from Hokkaido, Japan     

Andrew N. Ostrovsky  Reishi Takashima  Matthew H. Dick  Andrei V. Grischenko  Hiroshi Nishi  Shunsuke F. Mawatari 《Cretaceous Research》2006,27(6):859-862

A small collection of recrystallised, encrusting colonies of a single species from the Mikasa Formation (lower Middle Cenomanian), represents the first record of cheilostome (malacostegan or anascan) bryozoans from Hokkaido, Japan.  相似文献   

Variability in drift macroalgal abundance in relation to biotic and abiotic factors in two seagrass dominated estuaries in the Western Gulf of Mexico     

Andrea L. Kopecky  Kenneth H. Dunton 《Estuaries and Coasts》2006,29(4):617-629

We examined the spatial and temporal variability in drift macroalgal abundance in two seagrass dominated estuarine systems on the Texas coast: Redfish Bay (in the Copano-Aransas Estuary) and Lower Laguna Madre. Measurements of benthic macroalgal variability were made in conjunction with a suite of biotic (seagrass biomass, percent cover, blade width and length, shoot density, epiphyte biomass, seagrass blade C:N ratios, and drift macroalgal abundance and composition) and abiotic (inorganic nitrogen and phosphorus concentrations, chlorophylla, total suspended solids, light attenuation, salinity, temperature, total organic carbon and porewater NH₄ ⁺) indicators. All parameters were measured at 30 sites within each estuary semiannually from July 2002 to February 2004. Principal components analysis (PCA) was used to examine relationships between drift macroalgal abundance and biotic and abiotic parameters. In both Redfish Bay and Lower Laguna Madre, drift macroalgal distribution was widespread, and during three of four sampling periods, abundance was equal to abovegro und biomass ofThalassia testudinum, the dominant seagrass. Drift macro algal abundance was highly variable within sites, between sites, and between seasons in both estuaries. No significant differences in drift macroalgal abundance were found between Redfish Bay and Lower Laguna Madre. In Redfish Bay, drift macroalgae (90.1±10.2 gm⁻²) tended to accumulate in bare patches within seagrass beds. In Lower Laguna Madre, drift macroalgae (72.7±10.7 gm⁻²) tended to accumulate in areas of dense seagrass cover rather than in bare areas. We found no relationship between drift macroalgal abundance and low (<2μM) water column nutrient concentrations, and although several of our measured parameters were related to drift macroalgal abundance, none alone sufficiently explained the variability in abundance noted between the two estuarine systems. The contrasting patterns of macroalgal accumulation between Redrish Bay and Lower Laguna Madre likely reflect differences in water circulation characteristics between the two regions as dictated by local physiography, in cluding the shape and orientation of the lagoons, with seasonal variations in macroalgal abundance related to changes in freshwater inflow and nutrient loading.  相似文献