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981.
982.
Atomistic calculations of structural and elastic properties of serpentine minerals: the case of lizardite 总被引:1,自引:0,他引:1
A.-L. Auzende R. J.-M. Pellenq B. Devouard A. Baronnet O. Grauby 《Physics and Chemistry of Minerals》2006,33(4):266-275
The physical properties of the hydrous phyllosilicate lizardite have been investigated by atomistic simulation using the GULP code based on transferable semi-empirical interatomic potentials. Lizardite behavior was first investigated during structure relaxation at room temperature. The Helmholtz free energy is minimum for an equilibrium structure that is in agreement with experiment. The bulk, shear, and Young modulii for lizardite were calculated along with the Poisson ratio. From the shear and bulk modulii, we also calculated translational and longitudinal acoustic wave velocities that are important quantities for tectonophysics models. As expected, lizardite is stiffer in the a direction parallel to the layers than in the c perpendicular direction; the variation of the unit cell parameters with pressure is in good agreement with experiment. The cohesive energy between two successive layers along c direction was calculated at 0.33 eV (i.e., 0.11 eV per OH bond) in good agreement with recent ab initio calculations. Upon pressure and temperature variations, we evidenced that structural changes are mainly pressure induced; pressure being accommodated by a decrease of the c parameter up to 10 GPa. We also found that the change of slope in the derivative of the c cell parameter with respect to pressure occurring around 2 GPa originates from the bending of the interlayer hydroxyl groups with respect to the layer normal direction. 相似文献
983.
S. C. Choi Onyx W. H. Wai Thomas W. H. Choi X. D. Li C. W. Tsang 《Environmental Geology》2006,51(3):455-461
Partitioning of heavy metals (Cd, Cr, Cu, Pb, Zn) in marine sediments collected from various sites in Hong Kong waters were
determined using sequential extraction method. Sediments from Kellette Bank, located in Victoria Harbour, had higher metal
concentrations especially Cu and Zn than most other sites. Slightly over 20% of total Cu and Cr existed as readily available
forms in Peng Chau and Kellette Bank. At most sampling sites, over 15% of the Cu existed as the exchangeable form indicating
that Cu could be readily released into the aqueous phase from sediments. A significantly higher percentage of Pb and Zn was
associated with the three non-residual fractions. Hence, there is a greater environmental concern for remobilization of Pb
and Zn compared with Cr. The high amount of residual Cd (>50%) and the relatively lower Cd content indicate that little environmental
concern is warranted for the remobilization of Cd. Distribution of metals in sediments collected from different depth at Kellette
Bank shows that metal concentrations decreased with profile depth. The levels of Pb and Zn associated with the two readily
available fractions increased sharply in the surface sediment. These metals represented the pollutants, which were introduced
into the area in the mid-eighties through early nineties as a result of rapid economic and industrial development in the territory.
As significant portions of these metals were bound to the readily available phases in the surface sediments, metal remobilization
could be a concern.
An erratum to this article can be found at 相似文献
984.
Tenerife basically consists of three Miocene shield volcanoes, the Anaga, the Teno and Central shield, as well as the Pliocene Cañadas volcano. The temporal evolution and structural significance of each volcano with respect to the history of Tenerife is still a matter of debate. We present paleomagnetic results in order to enhance the view of the volcanic history of the Teno volcano by means of magnetostratigraphy. It is found that the initial subaerial phase shows reverse magnetizations throughout. After two major sector collapses, dominantly normally magnetized lavas extruded. Comparisons of observed magnetic polarities with the geomagnetic polarity timescale show that these volcanic activities occurred within 0.4 Myr between 6.3 and 5.9 Ma. Significantly younger flows, ~ 5.3 Myr old according to their radiometric age, revealed again normal polarity throughout. The absence of inversely magnetized lavas in-between the two normal periods indicates a volcanic hiatus or erosional phase. The evolutionary sequence and the estimated high production rates for the initial building phase are similar as would be expected for a hotspot volcano. The average geomagnetic field for 6.0 ± 0.2 Ma is close to an axial dipole field showing a slight far-sided/right-handed effect. The field strength, determined by Thellier-type intensity determinations, corresponds to a virtual axial dipole moment of 4.9 × 1022 A m2. This value is approximately half of the present day field strength, but similar to values obtained for the mid-Miocene. It also corresponds to the proposed tertiary low-field level of the geomagnetic dipole moment. 相似文献
985.
L. G. Medaris Jr. E. D. Ghent H. F. Wang J. H. Fournelle E. Jelínek 《Mineralogy and Petrology》2006,86(3-4):203-220
Summary In the Kutná Hora Complex, the Běstvina Formation, which is similar to Gf?hl granulite, contains eclogite that has escaped
widespread retrograde recrystallization. The eclogite assemblage, garnet + omphacite + quartz + rutile ± plagioclase, yields
an estimate for peak metamorphic conditions of 18–20 kbar and 835–935 °C, which is comparable to that determined from felsic
granulite, 14–20 kbar and 900–1000 °C. Garnet in eclogite exhibits both prograde and retrograde compositional zoning, from
which constraints on thermal history of the Gf?hl terrane can be derived by diffusion modelling. At 900 °C, a garnet grain
of 800–1000 μm radius would homogenize in 7.5–11.7 million years, but the existence of compositional gradients on a length
scale of 100–200 μm suggests that the duration of peak metamorphism may have been limited to ∼500,000 years. Diffusion modelling
of retrograde zoning in garnet yields a cooling rate of 150–100 °C/m.y. for a radius of 800–1000 μm and initial temperature
of 900 °C. The relatively brief duration of high-pressure/high-temperature metamorphism and rapid cooling and exhumation of
the Gf?hl terrane may be a consequence of lithospheric delamination during Early Carboniferous collision of Bohemia (Teplá-Barrandia)
and Moldanubia (Franke, 2000). 相似文献
986.
S. Tadisetty K. Matsui H. Shimada R. N. Gupta 《Rock Mechanics and Rock Engineering》2006,39(4):383-393
Summary. Discontinuous manual observations and irregular caving characteristics of roof rocks often lead to improper decisions resulting
in accidents and production loss. Hence, systematic monitoring of the hanging roof behind the chock shields is necessary for
safe and productive mining operations. A real-time application was successfully implemented in an Indian mine for forecasting
of hanging roof behaviour to enhance safety and productivity. This paper reports the functioning of real-time TWAP (time weighted
average pressure) analysis in the forecasting of hanging roof behaviour in real time. 相似文献
987.
In ground improvement projects with prefabricated vertical drains, the duration of the preloading period is set in advance
based on the predetermined time rate of consolidation of the compressible layer. If prediction is accurately done, the required
degree of consolidation is met at the pre-determined preloading time. As such, there is a requirement for in-situ tests to be carried out just prior to the removal of surcharge to assess the degree of consolidation of the improved ground.
In-situ tests were carried out after 23 months of surcharge loading at the In-Situ Test Site within the Changi East Reclamation Project in the Republic of Singapore. In-situ testing works in this research study comprises the use of field vane shear, piezocone, flat dilatometer and self-boring pressuremeter.
The in-situ tests were carried out to determine the shear strength and degree of consolidation of the Singapore marine clay at Changi
after 23 months of surcharge loading. The In-Situ Test Site consisted of a Vertical Drain Area as well as an untreated Control Area. Both areas were located adjacent to each
other and were surcharged simultaneously to the same level and surcharge left in place for a period of 23 months. Comparison
was made between the in-situ test results of the Vertical Drain Area and the untreated Control Area. 相似文献
988.
E. O. Groznova M. G. Dobrovol’skaya V. A. Kovalenker K. V. Davydov V. T. Bitarov M. V. Razin 《Geology of Ore Deposits》2006,48(2):108-133
The mineralogy and PT formation conditions of the Dzhimidon Pb-Zn deposit in the Sadon ore district are considered. The deposit is localized in metamorphic rocks of the Buron Formation, which pertain to the pre-Jurassic basement (lower structural stage) and are cut through by Upper Paleozoic granitoids, and in the Lower Jurassic terrigenous sequence (upper structural stage). Orebodies as quartz-sulfide veins are mainly hosted in the metamorphic rocks. Galena, sphalerite, chalcopyrite, pyrite, pyrrhotite, and arsenopyrite are the most abundant sulfides, while quartz, carbonates, chlorite, sericite, and feldspar are gangue minerals. The bismuth mineralization identified at this deposit for the first time is represented by diverse phases of the Ag-Pb-Bi-S system. Five stages of the ore deposit formation are recognized: a premineral stage (quartz-feldspar), three ore-bearing stages (pyrite-arsenopyrite, pyrrhotite-chalcopyrite-sphalerite, and arsenopyrite-sphalerite-galena), and a postmineral stage (quartz-calcite); each stage comprises one or several mineral assemblages. The study of fluid inclusions in quartz, calcite, and sphalerite of the premineral, ore-forming, and postmineral stages has shown that the ore was deposited mainly from Na chloride solution with a salinity varying from >22 to <1.0 wt % NaCl equiv at a temperature from 460 to ~120°C and 430–290 bars pressure. The third stage was characterized by an abrupt increase in temperature and by the appearance of Mg(Fe,Ca) chloride solutions equally with Na chloride fluids, presumably owing to the emplacement of granite porphyry. 相似文献
989.
990.