Oxygen and carbon isotopic study on the genesis of the Steirischer Erzberg siderite deposit (Austria)     

N. Laube  H. E. Frimmel  S. Hoernes 《Mineralium Deposita》1995,30(3-4):285-293

The carbon and oxygen isotopic composition of Fe-carbonate ore and its calcitic to dolomitic Devonian host rocks at the Steirischer Erzberg siderite deposit (Greywacke zone, Upper Austroalpine Unit) were determined in order to constrain the source and nature of the Fe-rich mineralizing fluid. The ¹⁸O-values obtained for various Fe-carbonate generations and the carbonate host lie within a similar range between + 14.6 and + 21.6 (V-SMOW). No good correlation exists between the relative ages of the carbonate phases and their O isotopic composition. The variation in ¹⁸O-values is due to metamorphic recrystallization with locally variable fluid/rock ratios. The average ¹³C-value of the carbonate host is +0.5 ± 1.2 (PDB) which corresponds well to worldwide Phanerozoic marine carbonate values. The first Fecarbonate generation has slightly lower ¹³C-values, on average -1.4 ± 0.8 (PDB). Recrystallization of both the carbonate host minerals and the ankerite/siderite led to significantly lower ¹³C-values of -4.2 ± 0.6 and-4.7 ± 0.7, respectively. Within the basal breccia of the post-Hercynian transgression series matrix calcite/ dolomite shows an average ¹³C-value of -2.9 ± 0.7, and matrix siderite/ankerite an average value of-4.1 ± 0.4. These data, together with Sr isotope data published previously, strongly support a late-diagenetic or epigenetic first Fe-mineralization from convecting formation waters. They ascended along extension faults and were driven by an increased heat flow caused by crustal thinning during a Devonian rifting phase that initiated the separation of the Noric terrane from Africa. A potential source of the Fe could have been the underlying Ordovician acid volcanics. Regional metamorphism related to collision tectonics in the Late Carboniferous (Hercynian) and later during the Alpine orogeny, caused intensive recrystallization and partial mobilization of the various carbonate phases.  相似文献   

Radiometric constraints on hydrothermal circulation in cooling granite plutons     

A. M. R. Neiva  M. H. Dodson  D. C. Rex  P. G. Guise 《Mineralium Deposita》1995,30(6):460-468

Improved precision of radiometric dating of ore deposits can provide information about the thermal history of hydrothermal circulation in cooling plutons. In Jales a Hercynian porphyritic two-mica granite and pre-Ordovician mica schists are cut and intensely altered by the Campo gold-quartz vein. The unaltered granite must be younger than 320 ± 6 Ma, and gives mica Rb-Sr ages of 308.5 ± 2.4 (1) Ma (muscovite) and 294.5 ± 1.1 Ma (biotite). Alteration muscovites from the granite give a weighted mean Rb-Sr age of 308.1 ± 1.5 Ma, and a mean ³⁹Ar-⁴⁰Ar age of 300.7 ± 2.8 Ma. Alteration muscovites from the mica schists give similar ³⁹Ar-⁴⁰Ar ages, averaging 303.0 ± 2.8 Ma. The results suggest that circulation of the Campo mineralising fluids took place no more than 2–4 Ma after the granite cooled through the muscovite Rb-Sr closure temperature, about 500 °C, and that subsequent cooling to biotite closure at about 300 °C took place at less than 14°C/Ma. The mean cooling rate following emplacement was 15 to 25 °C/Ma. The most detailed comparable published data, for the Cornubian ore field, imply much faster cooling rates.  相似文献   

Powder- and single crystal Mössbauer spectroscopy on synthetic fayalite     

W. Lottermoser  K. Forcher  G. Amthauer  H. Fuess 《Physics and Chemistry of Minerals》1995,22(4):259-267

Mössbauer measurements on synthetic iron orthosilicate Fe₂SiO₄ (fayalite) were carried out in the antiferromagnetic spin state below T _N 65 K. The Mössbauer parameters isomer shift , inner magnetic field H(0), angle between H(0) and the z-component of the electric field gradient (efg), quadrupole splitting QS and asymmetry parameter were determined as a function of temperature. These parameters could be attributed to the two crystallographic sites M1 and M2.The smaller isomer shift on M1 with respect to M2 displays the more covalent character of the Fe-O bond on M1, which is supported by previous neutron diffraction experiments. H(0) shows a Brillouin-type behaviour with different fields on the two crystallographic sites (stronger on M1) and a small discontinuity at T = 23 K which corresponds with previous magnetic measurements. The quadrupole splitting is equal on both sites within error bars, in agreement with previous theoretical results and in contradiction to previous Mössbauer refinements published elsewhere.  相似文献   

Mineralogical and geochemical compositions of modern bivalve shells from the Mediterranean coast of Egypt     

H. Holail  R. Tony 《GeoJournal》1995,35(4):481-486

The stable isotopic composition (¹³C and ¹⁸O) and elemental (Sr and Mg) of marine molluscs are presented for Carditacea and Solenacea shells collected off the Mediterranean coast of Egypt. Based on shell microstructures and mineralogy, the bivalve shells are preserved in their original mineralogy and chemistry.The Sr and Mg concentrations of the bivalve shells have mean values of 1960 ppm and 226 ppm respectively. The stable isotopic composition generally show high values of ¹⁸O and ¹³C. The ¹⁸O values range from +0.1 to –1.8 PDB and most shells are highly enriched in¹³C; averaging +2.5 PDB. These elemental and isotopic signatures are analogous to modern marine bivalves from other localities.The oxygen and carbon isotopes, together with the calculated temperatures, suggest that the aragonitic bivalve shells were precipitated in isotopic equilibrium from warm marine waters.  相似文献   

A climate change simulation starting from 1935     

U Cubasch  G C Hegerl  A Hellbach  H Höck  U Mikolajewicz  B D Santer  R Voss 《Climate Dynamics》1995,11(2):71-84

Due to restrictions in the available computing resources and a lack of suitable observational data, transient climate change experiments with global coupled ocean-atmosphere models have been started from an initial state at equilibrium with the present day forcing. The historical development of greenhouse gas forcing from the onset of industrialization until the present has therefore been neglected. Studies with simplified models have shown that this cold start error leads to a serious underestimation of the anthropogenic global warming. In the present study, a 150-year integration has been carried out with a global coupled ocean-atmosphere model starting from the greenhouse gas concentration observed in 1935, i.e., at an early time of industrialization. The model was forced with observed greenhouse gas concentrations up to 1985, and with the equivalent C0₂ concentrations stipulated in Scenario A (Business as Usual) of the Intergovernmental Panel on Climate Change from 1985 to 2085. The early starting date alleviates some of the cold start problems. The global mean near surface temperature change in 2085 is about 0.3 K (ca. 10%) higher in the early industrialization experiment than in an integration with the same model and identical Scenario A greenhouse gas forcing, but with a start date in 1985. Comparisons between the experiments with early and late start dates show considerable differences in the amplitude of the regional climate change patterns, particularly for sea level. The early industrialization experiment can be used to obtain a first estimate of the detection time for a greenhouse-gas-induced near-surface temperature signal. Detection time estimates are obtained using globally and zonally averaged data from the experiment and a long control run, as well as principal component time series describing the evolution of the dominant signal and noise modes. The latter approach yields the earliest detection time (in the decade 1990–2000) for the time-evolving near-surface temperature signal. For global-mean temperatures or for temperatures averaged between 45°N and 45°S, the signal detection times are in the decades 2015–2025 and 2005–2015, respectively. The reduction of the cold start error in the early industrialization experiment makes it possible to separate the near-surface temperature signal from the noise about one decade earlier than in the experiment starting in 1985. We stress that these detection times are only valid in the context of the coupled model's internally-generated natural variability, which possibly underestimates low frequency fluctuations and does not incorporate the variance associated with changes in external forcing factors, such as anthropogenic sulfate aerosols, solar variability or volcanic dust.  相似文献   

The age of the Kagenfels granite (northern Vosges) and its bearing on the intrusion scheme of late Variscan granitoids     

J. C. Hess  H. J. Lippolt  B. Kober 《International Journal of Earth Sciences》1995,84(3):568-577

In the Saxothuringian part of the Vosges (France), a first series of Variscan plutonic rocks (diorites to granites) has been intruded by several younger granites. Rocks of both the older generations have been cross-cut by the late orogenic Kagenfels granite. The averages of the hitherto published mineral ages of the earlier rock generations are 331 and 334 Ma, respectively, whereas Rb-Sr and K-Ar dates around 290 Ma have been reported for the Kagenfels granite. Because of the unlikely large age hiatus, a redetermination of the intrusion age of the Kagenfels granite formation appeared to be irrevocable. The newly obtained mineral ages on the Kagenfels granite (K-Ar and ⁴⁰Ar/³⁹Ar biotite ages as well as single zircon radiogenic ²⁰⁷Pb/²⁰⁶Pb data: 331 ± 5 Ma) are about 40 Ma older than the previous results. They are interpreted as giving the time of emplacement of the Kagenfels granite during the latest Visan. The mineral ages of the earlier plutonic rocks in this part of the Variscan Orogeny in all probability are not significantly different from their ages of intrusion. Therefore the age concordance of all three granitoid generations constrains a rather narrow time interval of orogenic magmatism close to the Lower-Upper Carboniferous boundary.  相似文献   

Solar structure in terms of Gauss' hypergeometric function     

H. J. Haubold  A. M. Mathai 《Astrophysics and Space Science》1995,228(1-2):77-86

Hydrostatic equilibrium and energy conservation determine the conditions in the gravitationally stabilized solar fusion reactor. We assume a matter density distribution varying non-linearly through the central region of the Sun. The analytic solutions of the differential equations of mass conservation, hydrostatic equilibrium, and energy conservation, together with the equation of state of the perfect gas and a nuclear energy generation rate = ₀ ⁿ T ⁿT ^m ,are given in terms of Gauss' hypergeometric function. This model for the structure of the Sun gives the run of density, mass, pressure, temperature, and nuclear energy generation through the central region of the Sun. Because of the assumption of a matter density distribution, the conditions of hydrostatic equilibrium and energy conservation are separated from the mode of energy transport in the Sun.  相似文献   

TheROSAT survey of extreme UV sources: a new window on the universe     

David A. H. Buckley 《Astrophysics and Space Science》1995,228(1-2):349-365

This paper discusses the first all-sky suvey of cosmic extreme ultra-violet sources, discovered by theROSAT Wide Field Camera. Details of the instrument and the survey are presented, with comparisons made to previous selected surveys in the X-ray regime. The subsequent optical identification program is described, and the major results summarized. I then discuss the main classes of EUV emitters: active chromosphere stars and hot white dwarfs, and describe the importance of EUV obserevations in understanding the astrophysics of these objects. Many bright, and relatively nearby, sources have been identified with hitherto unrecognized active stars, representing the extremes in chromospheric and coronal activity, be it binary or age related. Many new hot DA white dwarfs have also been indentified, and the most exciting result in this area is the discovery that significant traces of heavier elements (e.g. C, N, O, Si, Fe & Al) exist in their atmospheres, substantially increasing their EUV opacities. The importance of hot white dwarfs as standard candles in probing the local interstellar medium is also discussed. Miscellaneous counterparts (AGN, PNN, O-B stars and CVs) that make up the rest of the sample of EUV sources are also briefly mentioned. I conclude the paper with a discussion of the new magnetic cataclysmic variables discovered at SAAO, which have been the subject of intensive follow-up observations.  相似文献   

Interferometric observations of HCN and CN towards carbon stars     

M. Lindqvist  R. Lucas  H. Olofsson  A. Omont  K. Eriksson  B. Gustafsson 《Astrophysics and Space Science》1995,224(1-2):501-502

Using the IRAM interferometer we have observed four carbon stars (U Cam, CIT6, Y CVn, IRC+40540) in the HCN(J=1 0) and CN(N=1 0) lines. Here we present some results for CIT6 and U Cam.  相似文献   

The Mauritius Radiotelescope     

K. Golap  N. H. Issur  R. Somanah  R. Dodson  M. Modgekar  S. Sachdev  N. Udaya Shankar  Ch. V. Sastry 《Astrophysics and Space Science》1995,228(1-2):373-377

The Mauritius Radiotelescope (MRT) is a T-shaped array of helical antennas with a 2048 m EW arm and a 890 m South arm. The primary objective of the telescope is to produce a sky survey in the declination zone -15° to -65° with a point source sensitivity of 200 mJy and an angular resolution of 4'×4.6'cosec(z) at 151.6 MHz, z being the zenith angle . This paper describes the telescope and the present status  相似文献