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281.
Kristine Krogh Jensen Joel Baker Tod Waight Robert Frei David W. Peate 《Geostandards and Geoanalytical Research》2003,27(1):59-66
We present high precision Ir, Ru, Pt, Pd, Re and rare earth element (REE) determinations by isotope dilution multiple collector-ICP-MS on the Cretaceous-Tertiary boundary sedimentary reference material FC-1. Samples for platinum-group element measurements were digested in Carius tubes followed by acid digestion. The platinum-group elements were subsequently separated by anion exchange chemistry and determined by multiple collector-ICP-MS. The accuracy of the platinum-group element analyses have been verified by comparative analyses of the reference materials WITS-1 and GP13 (sample size 0.5-1 g). Replicate analyses of FC-1 (sample size 0.2 g) exhibit good reproducibility (RSD < 5%) for all the analysed platinum-group elements. REE data also exhibit excellent reproducibility (RSD < 0.5%), which indicates that this sample is homogeneous for the determination of the platinum-group elements and REE at the 0.2 g level. 相似文献
282.
A large data set, collected under the national Danish monitoring program, was used to evaluate the importance of photon flux density (PFD), relative wave exposure (REI), littoral slope, and salinity in regulating eelgrass cover at different depth intervals in Danish coastal waters. Average eelgrass cover exhibited a bell-shaped pattern with depth, reflecting that different factors regulate eelgrass cover at shallow- and deep-water sites. The multiple logistic regression analysis was used to identify regulating factors and determine their role in relation to eelgrass cover at different depth intervals. PFD, REI, and salinity were main factors affecting eelgrass cover while littoral slope had no significant effect. Eelgrass cover increased with increasing PFD at water depths of more than 2 m, while cover was in versely related to REI in shallow water. This pattern favored eelgrass cover at intermediate depths where levels of PFD and REI were moderate. Salinity had a minor, but significant, effect on eelgrass cover that is most likely related to the varying costs of osmoregulation with changing salinity. The analysis provided a useful conceptual framework for understanding the factors that regulate eelgrass abundance with depth. Although the regression model was statistically significant and included the factors generally considered most important in regulating eelgrass cover, its explanatory power was low, especially in shallow water. The largest discrepancies between predicted and observed values of cover appeared in cases where no eelgrass occurred despite sufficient light and moderate levels of exposure (almost 50% of all observations). These discrepancies suggest that population losses due to stochastic phenomena, such as extreme wind events, played an important regulating role that is not adequately described by average exposure levels. A more thorough knowledge of the importance of such loss processes and the time scales involved in recovery of seagrass populations after a severe disturbance are necessary if we are to understand the regulation of seagrass distribution in shallow coastal areas more fully. 相似文献
283.
The Moho topography is strongly undulating in southern Scandinavia and northeastern Europe. A map of the depth to Moho shows similarities between the areas of the Teisseyre–Tornquist Zone (TTZ) in Poland and the Fennoscandian Border Zone (FBZ), which is partly coinciding with the Sorgenfrei–Tornquist Zone (STZ) in Denmark. The Moho is steeply dipping at these zones from a crustal thickness of approximately 32 km in the young Palaeozoic Platform and basin areas to approximately 45 km in the old Precambrian Platform and Baltic Shield. The Moho reflectivity (PMP waveform) in the POLONAISE'97 refraction/wide-angle seismic data from Poland and Lithuania is variable, ranging from ‘sharp’ to strongly reverberating signals of up to 2 s duration. There is little or no lower crustal wide-angle reflectivity in the thick Precambrian Platform, whereas lower crustal reflectivity in the thin Palaeozoic Platform is strongly reverberating, suggesting that the reflective lower crust and upper mantle is a young phenomena. From stochastic reflectivity modelling, we conclude that alternating high- and low-velocity layers with average thicknesses of 50–300 m and P-wave velocity variations of ±3–4% of the background velocity can explain the lower crustal reflectivity. Sedimentary layering affects the reflectivity of deeper layers significantly and must be considered in reflectivity studies, although the reverberations from the deeper crust cannot be explained by the sedimentary layering only. The reflective lower crust and upper mantle may correspond to a zone that has been intruded by mafic melts from the mantle during crustal extension and volcanism. 相似文献
284.
We derive the bias and sampling variation of the harmonic average. These expressions, based on the lognormal distribution,
are validated using Monte Carlo and jackknife analysis of field data. The average has a positive bias. The sampling variation
results suggest that, for moderate to large sample sizes, the harmonic average is no more variable than the arithmetic average
if the medium is appropriately sampled. 相似文献
285.
Governments are major investors in climate change mitigation, but aversion to public indebtedness has led to reliance on private finance to deliver public assets. Compounding this challenge, financing through Energy Service Contracts is ruled out by accounting rules. With public and traditional private funding avenues closed, government departments have sought contracts that do not disclose the full cost of borrowing, such as the Public–Private Partnership (PPP) described in this case study. We unpack the utility contract filed with the provincial regulator to show that circumventing budgetary constraints cost the Delta School Board (DSB) 8.75% per annum on borrowed private funds while public finance would have cost 4%pa. All levels of the public sector are keen to play their role in climate mitigation. Climate policy is about not passing our burden of unbridled fossil fuel use and greenhouse gas emissions to future generations. If we do not exempt public sector capital investments for decarbonization from deficit regulations, we risk passing an unnecessary economic burden to future generations.
Key policy insights
Transition to a low-carbon economy requires public sector investments that exceed budget deficit regulations and political aversion in many jurisdictions;
Private–Public Partnerships are currently viewed as the solution to this self-imposed fiscal constraint;
PPPs without clear performance targets or contractual templates will expose less experienced public sector investors to high costs and emissions above expectations.
286.
Gaia Fantechi Niels R. Jensen Ole Saastad Jens Hjorth Jozef Peeters 《Journal of Atmospheric Chemistry》1998,31(3):247-267
The reactions of isoprene, MBO (2-methyl-3-buten-2-ol) and toluene with chlorine atoms have been studied at 298 ± 5 K and 740 ± 5 Torr with the use of FTIR spectroscopy. Major products of the isoprene-Cl reaction and of the MBO-Cl reaction have been identified and quantified, and reaction mechanisms have been tentatively proposed in order to explain the products formed. The reaction between isoprene and Cl atoms yields mainly HCl, formyl chloride, formic acid, methylglyoxal (pyruvic aldehyde), CO and CO2, while the MBO-Cl reaction forms acetone, HCl, formyl chloride, formic acid, CO, CO2. As products from the reaction between toluene and Cl we identified and quantified HCl and benzaldehyde. The rate constants for the reactions of isoprene and toluene with Cl atoms have also been determined using a relative rate method. The measured values are: kisoprene = (5.5 ± 1.0) × 10–10 cm3 molecule–1 s–1 and ktoluene = (5.6 ± 1.3) × 10–11 cm3 molecule–1 s–1. Atmospheric lifetimes have been estimated from these values. 相似文献
287.
288.
Claus-Dieter Hillenbrand Dieter K. Fütterer Hannes Grobe Thomas Frederichs 《Geo-Marine Letters》2002,22(2):51-59
Records of glaciomarine deposition recovered from the West Antarctic continental margin in the Amundsen Sea allow the reconstruction of the behaviour of the West Antarctic Ice Sheet (WAIS) in response to the natural climatic changes of the last 1.8 million years. Contents of gravel-sized and lithogenic components represent the input and redeposition of glaciogenic debris, whereas variations in the proportions of the calcareous sediment fraction reflect palaeoproductivity changes. All proxies, which are regarded as sensitive to a WAIS collapse, changed markedly during the global climatic cycles, but do not confirm a complete disintegration of the WAIS during the Pleistocene. 相似文献
289.
290.