Sulfur cycling at the Mid-Atlantic Ridge: A multiple sulfur isotope approach     

Marc Peters  Harald Strauss  James Farquhar  Charlotte Ockert  Benjamin Eickmann  Cristiane L. Jost 《Chemical Geology》2010,269(3-4):180-196

The role of sulfur in two hydrothermal vent systems, the Logatchev hydrothermal field at 14°45′N/44°58′W and several different vent sites along the southern Mid-Atlantic Ridge (SMAR) between 4°48′S and 9°33′S and between 12°22′W and 13°12′W, is examined by utilizing multiple sulfur isotope and sulfur concentration data. Isotope compositions for sulfide minerals and vent H₂S from different SMAR sites range from + 1.5 to + 8.9‰ in δ³⁴S and from + 0.001 to + 0.051‰ in Δ³³S. These data indicate mixing of mantle sulfur with sulfur from seawater sulfate. Combined δ³⁴S and Δ³³S systematics reveal that vent sulfide from SMAR is characterized by a sulfur contribution from seawater sulfate between 25 and 33%. This higher contribution, compared with EPR sulfide, indicates increased seawater sulfate reduction at MAR, because of a deeper seated magma chamber and longer fluid upflow path length, and points to fundamental differences with respect to subsurface structures and fluid evolution at slow and fast spreading mid-ocean ridges.Additionally, isotope data uncover non-equilibrium isotopic exchange between dissolved sulfide and sulfate in an anhydrite bearing zone below the vent systems at fluid temperatures between 335 and 400 °C. δ³⁴S values between + 0.2 to + 8.8‰ for dissolved and precipitated sulfide from Logatchev point to the same mixing process between mantle sulfur and sulfur from seawater sulfate as at SMAR. δ³⁴S values between ? 24.5 and + 6.5‰ and Δ³³S values between + 0.001 and + 0.125‰ for sulfide-bearing sediments and mafic/ultramafic host rocks from drill cores taken in the region of Logatchev indicate a clear contribution of biogenic sulfides formed via bacterial sulfate reduction. Basalts and basaltic glass from SMAR sites with Δ³³S = ? 0.008‰ reveal lower Δ³³S lower values than suggested on the basis of previously published isotopic measurements of terrestrial materials.We conclude that the combined use of both δ³⁴S and Δ³³S provides a more detailed picture of the sulfur cycling in hydrothermal systems at the Mid-Atlantic Ridge and uncovers systematic differences to hydrothermal sites at different mid-ocean ridge sites. Multiple sulfur isotope measurements allow identification of incomplete isotope exchange in addition to isotope mixing as a second important factor influencing the isotopic composition of dissolved sulfide during fluid upflow. Furthermore, based on Δ³³S we are able to clearly distinguish biogenic from hydrothermal sulfides in sediments even when δ³⁴S were identical.  相似文献   

SHRIMP zircon dating and Nd isotopic systematics of Palaeoproterozoic migmatitic orthogneisses in the Epupa Metamorphic Complex of northwestern Namibia     

A. Kröner  Y. Rojas-Agramonte  E. Hegner  K.-H. Hoffmann  M.T.D. Wingate 《Precambrian Research》2010

The Epupa Metamorphic Complex constitutes the southwestern margin of the Congo Craton and is exposed in a hilly to mountainous terrain of northwestern Namibia, bordering the Kunene River and extending into southern Angola. It consists predominantly of granitoid gneisses which are migmatized over large areas. This migmatization locally led to anatexis and produced crustal-melt granites such as the Otjitanda Granite. We have undertaken reconnaissance geochemical studies and single zircon U–Pb SHRIMP and Pb–Pb evaporation dating of rocks of the Epupa Complex. The granitoid gneisses, migmatites and anatectic melts are similar in composition and constitute a suite of metaluminous to peraluminous, calc-alkaline granitoids, predominantly with volcanic arc geochemical signatures. The zircon protolith ages for the orthogneisses range from 1861 ± 3 to 1758 ± 3 Ma. Anatexis in the migmatitic Epupa gneisses was dated from a melt patch at 1762 ± 4 Ma, and the anatectic Otjitanda Granite has a zircon age of 1757 ± 4 Ma. Migmatization and anatexis therefore occurred almost immediately after granitoid emplacement and date a widespread high-temperature Palaeoproterozoic event at ∼1760 Ma which has not been recorded elswhere in northern Namibia. The Nd isotopic systematics of all dated samples are surprisingly similar and suggest formation of the protolith from a source region that probably separated from the depleted mantle about 2.4–2.0 Ga ago. A major Archaean component in the source area is unlikely.  相似文献   

A parallel global-implicit 2-D solver for reactive transport problems in porous media based on a reduction scheme and its application to the MoMaS benchmark problem     

Joachim Hoffmann  Serge Kr?utle  Peter Knabner 《Computational Geosciences》2010,14(3):421-433

In this article, an approach for the efficient numerical solution of multi-species reactive transport problems in porous media is described. The objective of this approach is to reformulate the given system of partial and ordinary differential equations (PDEs, ODEs) and algebraic equations (AEs), describing local equilibrium, in such a way that the couplings and nonlinearities are concentrated in a rather small number of equations, leading to the decoupling of some linear partial differential equations from the nonlinear system. Thus, the system is handled in the spirit of a global implicit approach (one step method) avoiding operator splitting techniques, solved by Newton’s method as the basic algorithmic ingredient. The reduction of the problem size helps to limit the large computational costs of numerical simulations of such problems. If the model contains equilibrium precipitation-dissolution reactions of minerals, then these are considered as complementarity conditions and rewritten as semismooth equations, and the whole nonlinear system is solved by the semismooth Newton method.  相似文献   

The Pleistocene evolution of the East Antarctic Ice Sheet in the Prydz bay region: stable isotopic evidence from ODP Site 1167     

Kevin M. Theissen  Robert B. Dunbar  Alan K. Cooper  David A. Mucciarone  Dirk Hoffmann 《Global and Planetary Change》2003,39(3-4):227-256

Ocean Drilling Program Leg 188, Prydz Bay, East Antarctica is part of a larger initiative to explore the Cenozoic history of the Antarctic Ice Sheet through direct drilling and sampling of the continental margins. In this paper, we present stable isotopic results from Ocean Drilling Program (ODP) Site 1167 located on the Prydz Channel Trough Mouth Fan (TMF), the first Antarctic TMF to be drilled. The foraminifer-based δ¹⁸O record is interpreted along with sedimentary and downhole logging evidence to reconstruct the Quaternary glacial history of Prydz Bay and the adjacent Lambert Glacier Amery Ice Shelf System (LGAISS). We report an electron spin resonance age date of 36.9±3.3 ka at 0.45 m below sea floor and correlate suspected glacial–interglacial cycles with the global isotopic stratigraphy to improve the chronology for Site 1167. The δ¹⁸O record based on planktonic (Neogloboquadrina pachyderma (s.)) and limited benthic results (Globocassidulina crassa), indicates a trend of ice sheet expansion that was interrupted by a period of reduced ice volume and possibly warmer conditions during the early–mid-Pleistocene (0.9–1.38 Ma). An increase in δ¹⁸O values after 900 ka appears to coincide with the mid-Pleistocene climate transition and the expansion of the northern hemisphere ice sheet. The δ¹⁸O record in the upper 50 m of the stratigraphic section indicates as few as three glacial–interglacial cycles, tentatively assigned as marine isotopic stages (MIS) 16–21, are preserved since the Brunhes/Matuyama paleomagnetic reversal (780 ka). This suggests that there is a large unconformity near the top of the section and/or that there may have been few extreme advances of the ice sheet since the mid-Pleistocene climate transition resulting in lowered sedimentation rates on the Prydz Channel TMF. The stable isotopic record from Site 1167 is one of the few available from the area south of the Antarctic Polar Front that has been linked with the global isotopic stratigraphy. Our results suggest the potential for the recovery of useful stable isotopic records in other TMFs.  相似文献   

Efficient block preconditioners for the coupled equations of pressure and deformation in highly discontinuous media     

Joachim Berdal Haga  Harald Osnes  Hans Petter Langtangen 《国际地质力学数值与分析法杂志》2011,35(13):1466-1482

Large‐scale simulations of flow in deformable porous media require efficient iterative methods for solving the involved systems of linear algebraic equations. Construction of efficient iterative methods is particularly challenging in problems with large jumps in material properties, which is often the case in geological applications, such as basin evolution at regional scales. The success of iterative methods for this type of problems depends strongly on finding effective preconditioners. This paper investigates how the block‐structured matrix system arising from single‐phase flow in elastic porous media should be preconditioned, in particular for highly discontinuous permeability and significant jumps in elastic properties. The most promising preconditioner combines algebraic multigrid with a Schur complement‐based exact block decomposition. The paper compares numerous block preconditioners with the aim of providing guidelines on how to formulate efficient preconditioners. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Quaternary volcanic ash zones on the Iceland Plateau,southern Norwegian Sea     

Jorunn Sjwholm  Hans Petter Sejrup  Harald Furnes 《第四纪科学杂志》1991,6(2):159-173

Four Quaternary volcanic ash zones in the southern Norwegian Sea have been investigated in core P57-7 from the Iceland Plateau. Both the geochemical composition and morphological variation of each ash layer have been studied. The four volcanic ash zones appear in the light oxygen isotope stages 1, 5, 7 and 11. The ash zones are composed of transparent platy grains, light brown transparent grains, brown blocky and black blocky grains and white/transparent pumice, and each zone shows a distinct stratigraphic evolution. The geochemical results show a mixture of basaltic and silicic grains in each ash zone, and that each zone contains grains from more than one eruption. The geochemical investigations strongly suggest that all the ashes are derived from Iceland. The youngest ash zone includes two layers, which based on their geochemical composition and stratigraphic position are correlated with the ¹⁴C-dated Vedde Ash (10 600 yr BP) and Saksunarvatn Ash (9 100 yr BP). Possible sources on Iceland for these layers are discussed.  相似文献   

Three-frequency BDS precise point positioning ambiguity resolution based on raw observables   总被引：1，自引：0，他引：1  

Pan Li  Xiaohong Zhang  Maorong Ge  Harald Schuh 《Journal of Geodesy》2018,92(12):1357-1369

All BeiDou navigation satellite system (BDS) satellites are transmitting signals on three frequencies, which brings new opportunity and challenges for high-accuracy precise point positioning (PPP) with ambiguity resolution (AR). This paper proposes an effective uncalibrated phase delay (UPD) estimation and AR strategy which is based on a raw PPP model. First, triple-frequency raw PPP models are developed. The observation model and stochastic model are designed and extended to accommodate the third frequency. Then, the UPD is parameterized in raw frequency form while estimating with the high-precision and low-noise integer linear combination of float ambiguity which are derived by ambiguity decorrelation. Third, with UPD corrected, the LAMBDA method is used for resolving full or partial ambiguities which can be fixed. This method can be easily and flexibly extended for dual-, triple- or even more frequency. To verify the effectiveness and performance of triple-frequency PPP AR, tests with real BDS data from 90 stations lasting for 21 days were performed in static mode. Data were processed with three strategies: BDS triple-frequency ambiguity-float PPP, BDS triple-frequency PPP with dual-frequency (B1/B2) and three-frequency AR, respectively. Numerous experiment results showed that compared with the ambiguity-float solution, the performance in terms of convergence time and positioning biases can be significantly improved by AR. Among three groups of solutions, the triple-frequency PPP AR achieved the best performance. Compared with dual-frequency AR, additional the third frequency could apparently improve the position estimations during the initialization phase and under constraint environments when the dual-frequency PPP AR is limited by few satellite numbers.  相似文献   

Effects of melt composition on Fe3+/Fe2+ in silicate melts: a step to model ferric/ferrous ratio in multicomponent systems     

Alexander Borisov  Harald Behrens  Francois Holtz 《Contributions to Mineralogy and Petrology》2015,169(2):1-12

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Ductile to brittle fault zone evolution in Austroalpine units to the southeast of the Tauern Window (Eastern Alps)     

Andreas Wölfler  Wolfgang Frisch  Harald Fritz  Martin Danišik  Anke Wölfler 《Swiss Journal of Geoscience》2015,108(2-3):239-251

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High resolution regional climate model simulations for Germany: Part II—projected climate changes   总被引：1，自引：1，他引：0  

Sven Wagner  Peter Berg  Gerd Schädler  Harald Kunstmann 《Climate Dynamics》2013,40(1-2):415-427

The projected climate change signals of a five-member high resolution ensemble, based on two global climate models (GCMs: ECHAM5 and CCCma3) and two regional climate models (RCMs: CLM and WRF) are analysed in this paper (Part II of a two part paper). In Part I the performance of the models for the control period are presented. The RCMs use a two nest procedure over Europe and Germany with a final spatial resolution of 7 km to downscale the GCM simulations for the present (1971–2000) and future A1B scenario (2021–2050) time periods. The ensemble was extended by earlier simulations with the RCM REMO (driven by ECHAM5, two realisations) at a slightly coarser resolution. The climate change signals are evaluated and tested for significance for mean values and the seasonal cycles of temperature and precipitation, as well as for the intensity distribution of precipitation and the numbers of dry days and dry periods. All GCMs project a significant warming over Europe on seasonal and annual scales and the projected warming of the GCMs is retained in both nests of the RCMs, however, with added small variations. The mean warming over Germany of all ensemble members for the fine nest is in the range of 0.8 and 1.3 K with an average of 1.1 K. For mean annual precipitation the climate change signal varies in the range of ?2 to 9 % over Germany within the ensemble. Changes in the number of wet days are projected in the range of ±4 % on the annual scale for the future time period. For the probability distribution of precipitation intensity, a decrease of lower intensities and an increase of moderate and higher intensities is projected by most ensemble members. For the mean values, the results indicate that the projected temperature change signal is caused mainly by the GCM and its initial condition (realisation), with little impact from the RCM. For precipitation, in addition, the RCM affects the climate change signal significantly.  相似文献