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Irving Friedman George I. Smith Kenneth G. Hardcastle 《Geochimica et cosmochimica acta》1976,40(5):501-511
Owens Lake is an alkaline salt lake in a closed basin in southeast California. It is normally nearly dry, but in early 1969, an abnormal runoff from the Sierra Nevada flooded it to a maximum depth of 2·4 m. By late summer of 1971, the lake was again nearly dry and the dissolved salts recrystallized. Changes in the chemistry, pH, and deuterium content were monitored during desiccation.During flooding, salts (mostly trona, halite, and burkeite) dissolved slowly from the lake floor. Their concentration in the lake waters increased as evaporation removed water and salts again crystallized, but winter temperatures caused precipitation of some salts and the following summer warming caused their solution, resulting in seasonal variations in the concentration patterns of some ions. The pH values (9·4–10·4) changed with time but showed no detectable diurnal pattern.The deuterium concentration increased during evaporation and appeared to be in equilibrium with vapor leaving the lake according to the Rayleigh equation. The effective α(D/H in liquid/D/H in vapor) decreased as salinity increased; the earliest measured value was 1·069 [as total dissolved solids (TDS) of lake waters changed from 136,200 to 250,400 mg/1]and the last value (calc.) was 1·025 (as TDS changed from 450,000 to 470,300 mg/1). Deuterium exchange with the atmosphere was apparently small except during late desiccation stages when the isotopic contrast became great. Eventually, atmospheric exchange, combined with decreasing α and lake size and increasing salinity, stopped further deuterium concentration in the lake. The maximum contrast between atmospheric vapor and lake deuterium contents was about 110%. 相似文献
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M. J. Hardcastle L. W. Looney 《Monthly notices of the Royal Astronomical Society》2008,388(1):176-186
We have observed a small sample of powerful double radio sources (radio galaxies and quasars) at frequencies around 90 GHz with the Berkeley Illinois Maryland Association (BIMA) millimetre array, with the intention of constraining the resolved high-frequency spectra of radio galaxies. When combined with other sources we have previously observed and with data from the BIMA archive, these observations allow us for the first time to make general statements about the high-frequency behaviour of compact components of radio galaxies – cores, jets and hotspots. We find that cores in our sample remain flat-spectrum up to 90 GHz; jets in some of our targets are detected at 90 GHz for the first time in our new observations and hotspots are found to be almost universal, but show a wide range of spectral properties. Emission from the extended lobes of radio galaxies is detected in a few cases and shows rough consistency with the expectations from standard spectral ageing models, though our ability to probe this in detail is limited by the sensitivity of BIMA. We briefly discuss the prospects for radio galaxy astrophysics with Atacama Large Millimeter Array. 相似文献